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公开(公告)号:US10995417B2
公开(公告)日:2021-05-04
申请号:US15739314
申请日:2016-06-30
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, Jr. , Eric Rouya , Kyle Whitten , Shaopeng Sun , Jianwen Han
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising submicron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US20210388519A1
公开(公告)日:2021-12-16
申请号:US17400633
申请日:2021-08-12
Applicant: MacDermid Enthone Inc.
Inventor: Thomas Richardson , Kyle Whitten , Vincent Paneccasio, JR. , John Commander , Richard Hurtubise
IPC: C25D3/38 , C08G65/24 , C08G65/333 , C08G73/06 , H01L23/00
Abstract: An electrodeposition composition comprising: (a) a source of copper ions; (b) an acid; (c) a suppressor; and (d) a leveler, wherein the leveler comprises a quaternized dipyridyl compound prepared by reacting a dipyridyl compound with a difunctional alkylating agent or a quaternized poly(epihalohydrin). The electrodeposition composition can be used in a process for forming a copper feature over a semiconductor substrate in wafer level packaging to electrodeposit a copper bump or pillar on an underbump structure of a semiconductor assembly.
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公开(公告)号:US11035048B2
公开(公告)日:2021-06-15
申请号:US15641756
申请日:2017-07-05
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Kyle Whitten , Vincent Paneccasio, Jr. , Shaopeng Sun , Eric Yakobson , Jianwen Han , Elie Najjar
IPC: C25D3/16 , H01L21/768 , C25D5/02 , C25D7/12 , H01L21/288 , C25D3/18 , C25D7/00
Abstract: Compositions and methods of using such compositions for electroplating cobalt onto semiconductor base structures comprising submicron-sized electrical interconnect features are provided herein. The interconnect features are metallized by contacting the semiconductor base structure with an electrolytic composition comprising a source of cobalt ions, a suppressor, a buffer, and one or more of a depolarizing compound and a uniformity enhancer. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The method presented herein is useful for superfilling interconnect features.
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公开(公告)号:US20210222314A1
公开(公告)日:2021-07-22
申请号:US17220540
申请日:2021-04-01
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, JR. , Eric Rouya , Kyle Whitten , Shaopeng Sun , Jianwen Han
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising sub-micron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US20190010624A1
公开(公告)日:2019-01-10
申请号:US15641756
申请日:2017-07-05
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Kyle Whitten , Vincent Paneccasio, JR. , Shaopeng Sun , Eric Yakobson
IPC: C25D3/16 , H01L21/768 , C25D5/02 , C25D7/12
Abstract: Compositions and methods of using such compositions for electroplating cobalt onto semiconductor base structures comprising submicron-sized electrical interconnect features are provided herein. The interconnect features are metallized by contacting the semiconductor base structure with an electrolytic composition comprising a source of cobalt ions, a suppressor, a buffer, and one or more of a depolarizing compound and a uniformity enhancer. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The method presented herein is useful for superfilling interconnect features.
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公开(公告)号:US11434578B2
公开(公告)日:2022-09-06
申请号:US17220540
申请日:2021-04-01
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, Jr. , Eric Rouya , Kyle Whitten , Shaopeng Sun , Jianwen Han
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising sub-micron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US20200040478A1
公开(公告)日:2020-02-06
申请号:US15739314
申请日:2016-06-30
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, Jr. , Eric Rouya , Kyle Whitten , Shaopeng Sun
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising submicron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US20240018678A1
公开(公告)日:2024-01-18
申请号:US18372236
申请日:2023-09-25
Applicant: MacDermid Enthone Inc.
Inventor: Vincent Paneccasio, JR. , Kyle Whitten , Richard Hurtubise , John Commander , Eric Rouya
CPC classification number: C25D3/38 , C25D7/123 , C25D17/001 , H01L21/2885
Abstract: An electrolytic plating composition for superfilling submicron features in a semiconductor integrated circuit device and a method of using the same. The composition comprises (a) a source of copper ions to electrolytically deposit copper onto the substrate and into the electrical interconnect features, and (b) a suppressor comprising at least three amine sites, said polyether comprising a block copolymer substituent comprising propylene oxide (PO) repeat units and ethylene oxide (EO) repeat units, wherein the number average molecular weight of the suppressor compound is between about 1,000 and about 20,000.
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公开(公告)号:US11697884B2
公开(公告)日:2023-07-11
申请号:US17400633
申请日:2021-08-12
Applicant: MacDermid Enthone Inc.
Inventor: Thomas Richardson , Kyle Whitten , Vincent Paneccasio, Jr. , John Commander , Richard Hurtubise
CPC classification number: C25D3/38 , C08G65/24 , C08G65/33317 , C08G73/0627 , H01L24/11 , C25D7/123 , H01L2224/11462 , H01L2924/01029 , H01L2924/3656
Abstract: An electrodeposition composition comprising: (a) a source of copper ions; (b) an acid; (c) a suppressor; and (d) a leveler, wherein the leveler comprises a quaternized dipyridyl compound prepared by reacting a dipyridyl compound with a difunctional alkylating agent or a quaternized poly(epihalohydrin). The electrodeposition composition can be used in a process for forming a copper feature over a semiconductor substrate in wafer level packaging to electrodeposit a copper bump or pillar on an underbump structure of a semiconductor assembly.
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公开(公告)号:US20210332491A1
公开(公告)日:2021-10-28
申请号:US17222058
申请日:2021-04-05
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Kyle Whitten , Vincent Paneccasio, JR. , Shaopeng Sun , Eric Yakobson , Jianwen Han , Elie Najjar
IPC: C25D3/16 , H01L21/768 , C25D5/02 , C25D7/12 , H01L21/288 , C25D3/18 , C25D7/00
Abstract: Compositions and methods of using such compositions for electroplating cobalt onto semiconductor base structures comprising submicron-sized electrical interconnect features are provided herein. The interconnect features are metallized by contacting the semiconductor base structure with an electrolytic composition comprising a source of cobalt ions, a suppressor, a buffer, and one or more of a depolarizing compound and a uniformity enhancer. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The method presented herein is useful for superfilling interconnect features.
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