公开(公告)号：US3666822A

公开(公告)日：1972-05-30

申请号：US3666822D

申请日：1970-03-05

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C5/48 ,  C22B41/00 ,  C07C5/18

CPC classification number: B01J23/002 ,  B01J21/08 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/8871 ,  B01J23/8876 ,  B01J37/0201 ,  B01J37/04 ,  B01J2523/00 ,  C07C5/48 ,  C07C253/26 ,  C22B41/00 ,  Y02P20/52 ,  B01J2523/39 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/41 ,  B01J2523/842 ,  B01J2523/31 ,  B01J2523/52 ,  B01J2523/55 ,  B01J2523/845 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and molybdenum and the combined oxides of uranium and molybdenum in combination with arsenic, bismuth, tin, vanadium, iron, nickel and cobalt.

Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括铀和钼的组合氧化物以及铀和钼与砷，铋，锡，钒，铁，镍和钴组合的组合氧化物。

公开(公告)号：US3929899A

公开(公告)日：1975-12-30

申请号：US42349473

申请日：1973-12-10

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/843 ,  C07C45/35 ,  C07C45/04

CPC classification number: C07C253/26 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/8432 ,  C07C45/35 ,  Y02P20/52 ,  C07C47/22 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and arsenic on a catalyst support and the combined oxides of uranium and arsenic promoted by molybdenum, boron, vanadium, tin, nickel, bismuth, chromium, iron, manganese, zinc, tungsten, antimony, cerium, cobalt or rhenium.

Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括催化剂载体上的铀和砷的组合氧化物，以及由钼，硼，钒，锡，镍，铋，铬，铁，锰，锌，钨，锑，铈， 钴或铼。

公开(公告)号：US3907713A

公开(公告)日：1975-09-23

申请号：US32903473

申请日：1973-02-02

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  FRIEDRICH MARIA

IPC: C07C27/00 ,  B01J21/02 ,  B01J23/28 ,  B01J23/31 ,  B01J23/34 ,  B01J23/76 ,  B01J23/84 ,  B01J23/88 ,  B01J27/057 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C27/14 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/10

CPC classification number: B01J23/8872 ,  B01J21/02 ,  B01J23/31 ,  B01J23/34 ,  B01J23/8871 ,  B01J23/8876 ,  B01J27/0576 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/64 ,  B01J2523/72 ,  C07C255/08

Abstract: Very desirable oxidation catalysts are prepared by impregnating a catalytic oxide matrix containing at least cobalt and molybdenum, magnesium and molybdenum, nickel and mulybdenum, manganese and molybdenum with iron, bismuth, tellurium or a mixture thereof.

Abstract translation: 通过将含有至少钴和钼，镁和钼，镍和钼，锰和钼的催化氧化物基质浸渍在铁，铋，碲或其混合物中来制备非常理想的氧化催化剂。

公开(公告)号：US3686295A

公开(公告)日：1972-08-22

申请号：US3686295D

申请日：1970-06-01

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  MILLER ROBERT C

IPC: C07C45/33 ,  C07C45/34 ,  C07C45/36 ,  C07C57/05 ,  C07C51/20 ,  C07C45/02

CPC classification number: C07C45/36 ,  C07C45/33 ,  C07C45/34 ,  C07C253/24 ,  C07C253/28 ,  C07C47/22 ,  C07C255/08 ,  C07C255/34

Abstract: The instant application is related to a process for the oxidation of saturated hydrocarbons and substituted saturated hydrocarbons in a vapor phase reaction over an antimonycontaining oxidation catalyst in which the hydrocarbon in the presence of a minor quantity of an inorganic or organic halide, hydrogen chloride, hydrogen bromide or hydrogen iodide or of a halogen other than fluorine, is reacted with (a) oxygen, to form unsaturated aldehydes and acids or (b) oxygen and ammonia, to form unsaturated nitriles.

Abstract translation: 本申请涉及在含锑氧化催化剂的气相反应中氧化饱和烃和取代饱和烃的方法，其中烃在少量无机或有机卤化物，氯化氢存在下 ，溴化氢或碘化氢或氟以外的卤素与（a）氧反应，形成不饱和醛和酸或（b）氧和氨，形成不饱和腈。

公开(公告)号：US3666823A

公开(公告)日：1972-05-30

申请号：US3666823D

申请日：1970-03-05

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/16 ,  B01J23/18 ,  B01J23/28 ,  B01J23/843 ,  B01J23/88 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C5/48 ,  C22B41/00 ,  C07C5/18

CPC classification number: B01J23/002 ,  B01J21/08 ,  B01J23/16 ,  B01J23/18 ,  B01J23/28 ,  B01J23/8432 ,  B01J23/88 ,  B01J23/8876 ,  B01J37/0201 ,  B01J37/04 ,  B01J2523/00 ,  C07C5/48 ,  C07C253/26 ,  C22B41/00 ,  Y02P20/52 ,  B01J2523/39 ,  B01J2523/52 ,  B01J2523/54 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/72 ,  B01J2523/30 ,  B01J2523/43 ,  B01J2523/68 ,  B01J2523/27 ,  B01J2523/847 ,  B01J2523/67 ,  B01J2523/55 ,  B01J2523/53 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and arsenic on a catalyst support and the combined oxides of uranium and arsenic promoted by molybdenum, boron, vanadium, tin, nickel, bismuth, chromium, iron, manganese, zinc, tungsten, antimony, cerium, cobalt or rhenium.

Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括催化剂载体上的铀和砷的组合氧化物，以及由钼，硼，钒，锡，镍，铋，铬，铁，锰，锌，钨，锑，铈， 钴或铼。

公开(公告)号：US3911039A

公开(公告)日：1975-10-07

申请号：US43584174

申请日：1974-01-23

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  HARDMAN HARLEY F

IPC: B01J23/887 ,  C07C5/48 ,  C07C5/18

CPC classification number: B01J23/8876 ,  C07C5/48 ,  C07C11/167

Abstract: Catalysts containing molybdenum, bismuth, iron and nickel, cobalt, magnesium, zinc, cadmium, manganese calcium or mixture thereof and an alkali metal or T1 are promoted by an element selected from antimony and tin to give highly desirable catalysts for the oxidative dehydrogenation of olefins of 4 to about 10 carbon atoms.

Abstract translation: 含有钼，铋，铁和镍，钴，镁，锌，镉，锰钙或其混合物和碱金属或T1的催化剂由选自锑和锡的元素促进，以产生用于烯烃氧化脱氢的非常理想的催化剂 4至约10个碳原子。

公开(公告)号：US3907859A

公开(公告)日：1975-09-23

申请号：US30065072

申请日：1972-10-25

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  MILLER ARTHUR F

IPC: B01J23/24 ,  B01J23/32 ,  B01J23/68 ,  B01J23/887 ,  B01J27/192 ,  C07C51/25 ,  C07C57/055 ,  C07C120/14 ,  C07C51/32 ,  C07C57/04

CPC classification number: C07C253/26 ,  B01J23/24 ,  B01J23/32 ,  B01J23/687 ,  B01J23/8876 ,  B01J27/192 ,  C07C51/252 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08

Abstract: High per pass conversions to acrylonitrile and acrylic acid or methacrylonitrile and methacrylic acid and desirable commercial flexibility are realized by reacting propylene or isobutylene with molecular oxygen and about 0.1 to about 0.9 moles of ammonia per mole of olefin in the presence of two catalysts. The first catalyst is an ammoxidation catalyst, and the second catalyst is an oxidation catalyst.

Abstract translation: 丙烯腈和丙烯酸或甲基丙烯腈和甲基丙烯酸的高通过转化率和所需的商业柔性通过在两种催化剂存在下使丙烯或异丁烯与分子氧和约0.1至约0.9摩尔氨/摩尔烯烃反应来实现。 第一催化剂是氨氧化催化剂，第二催化剂是氧化催化剂。

公开(公告)号：US3859358A

公开(公告)日：1975-01-07

申请号：US20570571

申请日：1971-12-07

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/16 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C22B41/00 ,  C07C45/02

CPC classification number: B01J23/002 ,  B01J21/08 ,  B01J23/16 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/8871 ,  B01J23/8876 ,  B01J37/0201 ,  B01J37/04 ,  B01J2523/00 ,  C07C45/35 ,  C07C51/252 ,  C07C253/26 ,  C22B41/00 ,  Y02P20/52 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/39 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/55 ,  B01J2523/54 ,  B01J2523/43 ,  B01J2523/52 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and molybdenum and the combined oxides of uranium and molybdenum in combination with arsenic, bismuth, tin, vanadium, iron, nickel and cobalt.

公开(公告)号：US3642930A

公开(公告)日：1972-02-15

申请号：US3642930D

申请日：1969-10-20

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  HARDMAN HARLEY F

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C5/48 ,  C07C11/12 ,  C07C67/00 ,  H01H3/40 ,  C07C5/18 ,  C07C1/24

CPC classification number: H01H3/40 ,  B01J23/8876 ,  B01J27/192 ,  C07C1/20 ,  C07C5/48 ,  C07C2523/887 ,  C07C2527/192 ,  Y10S585/906 ,  C07C11/18

Abstract: A VAPOR PHASE CATALYTIC OXYDEHYDROGENATION PROCESS FOR THE CONVERSION OF A STREAM OF MIXED ISOMERIC ISOAMYLENES, METHYL BUTANOLS OR MIXTURES THEREOF TO ISOPRENE WITH RELATIVELY SHORT CONTACT TIMES AT A REACTOR TEMPERATURE IN THE RANGE OF 500*F. TO 1100*F. AT FROM 0.5 TO ABOUT 10 ATMOSPHERES PRESSURE. THE CATALYSTS COMPRISE AN ALKALI METAL AS AN ESSENTIAL CATALYTIC INGREDIENT.