公开(公告)号：US11279854B2

公开(公告)日：2022-03-22

申请号：US15753467

申请日：2016-08-18

Applicant: TESA SE

Inventor： Sebastian Dietze ,  Uwe Schümann ,  Tanja Altenwegner ,  Eugenia Seibel

IPC: C09J5/00 ,  C09J5/02 ,  C03C17/30

Abstract: The invention relates to a solution in particular for the pre-treatment of a surface, containing, preferably consisting of: I) at least one first silane of formula (I) with R1, R2, R3 independently selected from the groups methyl, ethyl, 2 methoxyethyl, propyl, i-propyl, butyl, benzyl, wherein m=0 or 1, n=3 to 12, p=1 or 2, and for p=1, Y=a functional group selected from the groups (meth)acryl, (meth)acryloxy, mercapto, ureido, —NH—CH2—CH2—NR4R5, —NR4R5 (with R4 and R5 independently selected from the groups H, alkyl, phenyl, benzyl, cycloalkyl), or for p=2, Y=NH; II) at least one second silane of formula (II) with R1, R2, R3 independently selected from the groups methyl, ethyl, 2 methoxyethyl, propyl, i-propyl, butyl, benzyl, wherein m=0 or 1, R8=H, alkyl, phenyl, benzyl or cycloalkyl; III) at least one alcohol; and IV) water.

公开(公告)号：US20200270486A1

公开(公告)日：2020-08-27

申请号：US16646367

申请日：2018-08-16

Applicant: tesa SE

Inventor： Sebastian Dietze ,  Jasmin Flucke ,  Uwe Schümann ,  Anna Schubert

IPC: C09J7/35 ,  C09J175/14 ,  C09J5/06 ,  C08G18/75 ,  C08G18/32

Abstract: A method is provided for sealing discontinuities in vehicle bodywork, using an at least two-layer adhesive product which comprises at least one thermally activatable adhesive layer and a film layer of a polymeric material, where first the adhesive product is positioned with the adhesive layer onto the discontinuity for sealing, the adhesive layer sealingly wets the discontinuity, optionally after temperature increase, at elevated temperature the thermal activation of the adhesive ensues, characterized in that the adhesive layer used comprises a layer of a thermally activatable adhesive, specifically a layer based on a vulcanizable adhesive, and the thermal activation takes place with vulcanization of the adhesive.

公开(公告)号：US20140308452A1

公开(公告)日：2014-10-16

申请号：US13887936

申请日：2013-05-06

Applicant: tesa SE

Inventor： Uwe B Schümann ,  Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Thilo Dollase

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06 ,  C08L39/04 ,  C08L39/06

Abstract: The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, c) acrylic acid, one or more organofunctional silanes. Such primer provides reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass. The adhesion-promoting effect is retained even when the primer additionally contains functional fillers.

Abstract translation: 本发明涉及一种底漆，其包含溶解或分散在一种或多种溶剂中的混合物，所述混合物由通过共聚获得的共聚物，优选自由基共聚合得到的乙烯基己内酰胺和/或乙烯基吡咯烷酮以及一种或多种以下单体 a）在醇的烷基中含有2至10个碳原子的直链伯醇的丙烯酸酯，b）烷基中具有4至12个碳原子的支链非环状醇的丙烯酸酯 的醇，c）丙烯酸，一种或多种有机官能硅烷。 这种底漆在压敏粘合带和亲水表面之间，特别是玻璃上提供了可靠和优异的粘合性。 即使引物另外含有功能性填料也可以保持粘附促进效果。

公开(公告)号：US11111423B2

公开(公告)日：2021-09-07

申请号：US16353054

申请日：2019-03-14

Applicant: tesa SE

Inventor： Uwe Schümann ,  Sebastian Dietze ,  Christine Böhm ,  Marten Papenbroock

IPC: C09J187/00 ,  C09J7/38 ,  C09J11/04 ,  C08G18/75 ,  C09J175/14 ,  C08G18/32 ,  C08G18/69 ,  C08G18/12 ,  C08G18/22

Abstract: A thermally vulcanizable pressure-sensitive adhesive comprising a chemically precrosslinked, pressure-sensitively adhesive polybutadiene-polyurethane and ground sulfur, which during the heating phase remains pressure-sensitively adhesive, does not liquefy and hence in this phase, in which the vulcanization has not yet started and the curing has not yet commenced, has shear strength at least under load to moderate low, is able to transmit forces and hence to perform holding, a process for producing it, an adhesive tape comprising this pressure-sensitive adhesive, and a process for producing the adhesive tape.

公开(公告)号：US10907076B2

公开(公告)日：2021-02-02

申请号：US15780343

申请日：2016-11-24

Applicant: TESA SE

Inventor： Sebastian Dietze ,  Arne Koops ,  Gero Maatz ,  Uwe Schümann

IPC: C09J5/04 ,  C09J5/00 ,  B32B15/04 ,  B32B29/00 ,  B32B7/12 ,  B32B15/20 ,  B32B15/12 ,  C09J7/28 ,  C09J7/20 ,  C09J7/30

Abstract: Method of adhesively bonding two surfaces by means of a reactive adhesive film system comprising at least two adhesive films (F1 and F2), each comprising at least one reactive component (R1 and R2), adhesive bonding being effected by a reaction which requires the presence of both reactive components (R1 and R2),
wherein, prior to adhesive bonding, a separating layer (T) which is impermeable to the reactive components is provided between the adhesive films which are to be brought into contact with one another for the reaction,
and the separating layer (T) is removed at least in part by means of a laser in order to effect bonding,
so that the adhesive films (F1 and F2) come into direct contact with one another and the reaction begins in the presence of both reactive components (R1 and R2), and reactive adhesive film system for use in this method.

公开(公告)号：US20210002521A1

公开(公告)日：2021-01-07

申请号：US16919393

申请日：2020-07-02

Applicant: tesa SE

Inventor： Uwe Schümann ,  Nicholas Buggy ,  Sebastian Dietze ,  Kim Elsenbach

IPC: C09J109/02 ,  C09J7/35 ,  C09J7/29

Abstract: An adhesive, more particularly a thermally curable, meltable, preferably pressure-sensitive adhesive, which is curable thermally from a temperature of 110° C., is storage-stable for approximately one month at 60° C. and longer than one year at 23° C., and an adhesive tape produced therefrom, comprising an epoxide-functionalized acrylonitrile/butadiene copolymer having on average more than 1.5 epoxide groups per molecule, and the ground reaction product of phthalic anhydride and diethylenetriamine, for use in the automotive industry both in bodyshell construction on oiled metal sheets and in the coating line on cathodically electrocoated or otherwise-coated metal sheets, for bonding and/or sealing, for example for hem fold bonding, for hem fold sealing, for seam sealing, for underseal bonding, for hole stopping, and much more.

公开(公告)号：US11208581B2

公开(公告)日：2021-12-28

申请号：US16336376

申请日：2017-09-12

Applicant: TESA SE

Inventor： Sebastian Dietze ,  Kim Elsenbach ,  Frank Hannemann ,  Björn Zeysing ,  Uwe Schümann ,  Matthias Seibert ,  Katja Meyer ,  Bernd Dietz ,  Jasmin Flucke ,  Amy Kaus

IPC: C09J175/14 ,  C09J7/35 ,  C09J7/38 ,  B29C48/67 ,  B29C48/02 ,  B29C48/15 ,  B29C48/40 ,  B29B7/48 ,  B29B7/60 ,  B29B7/72 ,  B29B7/84 ,  B29B7/86 ,  B29B7/90 ,  C08G18/22 ,  C08G18/32 ,  C08G18/65 ,  C08G18/69 ,  C08G18/75 ,  C08G18/87 ,  C09J11/04 ,  C09J11/06 ,  B29C48/00 ,  C08K3/011 ,  C08K3/013 ,  C08K3/06 ,  C08K5/40 ,  C08K5/47 ,  C08L63/00

Abstract: Thermally vulcanisable, meltable adhesives and processes have a meltable polybutadiene-polyurethane, ground sulphur and optionally at least one vulcanisation accelerator, at least one filling material, at least one epoxide resin, at least one tackifier resin, bitumen, at least one softener and further auxiliary and additive materials, wherein said adhesives and processes can be thermally vulcanised within a temperature range of 130° C. to 230° C., such that same, as well as an adhesive strip produced from same, can be used for adhesion and/or sealing in the automotive industry, as well as in structural work on oiled sheet metal, and in the painting line on e-coated or otherwise painted sheet metal, for example, for crimp fold adhesion, for crimp fold sealing, for seam sealing, for lining adhesion, for hole closure and much more.

公开(公告)号：US10513634B2

公开(公告)日：2019-12-24

申请号：US15329300

申请日：2015-08-27

Applicant: TESA SE

Inventor： Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Duc Hung Nguyen ,  Uwe Schümann

IPC: C09J5/02 ,  C08K5/057 ,  C09J139/06 ,  C08L23/28 ,  C08L51/06 ,  B05D3/02

Abstract: Primer for adhesive tape with improved adhesion promoting properties, comprising a mixture G, which is dissolved or dispersed in one or more solvents, consisting of at least one copolymer obtained by copolymerization of a monomer mixture comprising an amount of at least 90 wt % of the following monomers: vinylcaprolactam and/or vinylpyrrolidone; one or more of the monomers a) and/or b): a) acrylic acid ester of a linear, primary alcohol having 2 to 10 carbon atoms in the alkyl group of the alcohol, b) acrylic acid ester of a branched, non-cyclic alcohol having 3 to 12 carbon atoms in the alkyl group, at least one chlorinated polyolefin, and at least one metal compound selected from the group consisting of metal acetylacetonates, metal alkoxides and alkoxy-metal acetylacetonates.

公开(公告)号：US09080083B2

公开(公告)日：2015-07-14

申请号：US13887936

申请日：2013-05-06

Applicant: tesa SE

Inventor： Uwe Schümann ,  Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Thilo Dollase

IPC: C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06

CPC classification number: C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06 ,  C08L39/04 ,  C08L39/06

Abstract: The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, c) acrylic acid, one or more organofunctional silanes. Such primer provides reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass. The adhesion-promoting effect is retained even when the primer additionally contains functional fillers.

Abstract translation: 本发明涉及一种底漆，其包含溶解或分散在一种或多种溶剂中的混合物，所述混合物由通过共聚获得的共聚物，优选自由基共聚合得到的乙烯基己内酰胺和/或乙烯基吡咯烷酮以及一种或多种以下单体 a）在醇的烷基中含有2至10个碳原子的直链伯醇的丙烯酸酯，b）烷基中具有4至12个碳原子的支链非环状醇的丙烯酸酯 的醇，c）丙烯酸，一种或多种有机官能硅烷。 这种底漆在压敏粘合带和亲水表面之间，特别是玻璃上提供了可靠和优异的粘合性。 即使引物另外含有功能性填料也可以保持粘附促进效果。

公开(公告)号：US20150175853A1

公开(公告)日：2015-06-25

申请号：US14640835

申请日：2015-03-06

Applicant: tesa SE

Inventor： Uwe Schümann ,  Sebastian Dietze ,  Kai Ellringmann ,  Marco Kupsky ,  Thilo Dollase

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08K5/54 ,  C09J139/04 ,  C09J139/06 ,  C08L39/04 ,  C08L39/06

Abstract: The invention relates to a primer, comprising a mixture dissolved or dispersed in one or more solvents, the mixture composed of a copolymer obtained through copolymerization, preferably free-radical copolymerization, of vinylcaprolactam and/or vinylpyrrolidone, and one or more of the following monomers: a) an acrylic acid ester of a linear primary alcohol containing 2 to 10 carbon atoms in the alkyl group of the alcohol, b) an acrylic acid ester of a branched, non-cyclic alcohol having 4 to 12 carbon atoms in the alkyl group of the alcohol, c) acrylic acid, one or more organofunctional silanes. Such primer provides reliable and excellent adhesion between pressure-sensitive adhesive tapes and hydrophilic surfaces, in particular glass. The adhesion-promoting effect is retained even when the primer additionally contains functional fillers.

Abstract translation: 本发明涉及一种底漆，其包含溶解或分散在一种或多种溶剂中的混合物，所述混合物由通过共聚获得的共聚物，优选自由基共聚合得到的乙烯基己内酰胺和/或乙烯基吡咯烷酮以及一种或多种以下单体 a）在醇的烷基中含有2至10个碳原子的直链伯醇的丙烯酸酯，b）烷基中具有4至12个碳原子的支链非环状醇的丙烯酸酯 的醇，c）丙烯酸，一种或多种有机官能硅烷。 这种底漆在压敏粘合带和亲水表面之间，特别是玻璃上提供了可靠和优异的粘合性。 即使引物另外含有功能性填料也可以保持粘附促进效果。