摘要:
An apparatus for recovering, refining, and storing hydrogen gas, includes: a recovery and refinement line for recovering and refining hydrogen gas used for a hydrogen furnace or used as a process gas; a storage tank for storing refined gas; and a resupply line for resupplying a stored gas to the hydrogen furnace or as a process gas. A palladium film is installed in the recovery and refinement line and lets hydrogen gas permeate the palladium film so as to be refined.
摘要:
A connected body including a gas separator 10 and metallic members 21 and 22, each of which has a partly oxidized surface to be reliably connected with the gas separator. The gas separator includes a ceramic substrate 11 and a gas separation membrane 12 to be coated onto substrate 11. The substrate 11 is porous so that a gas molecule can pass therethrough, and gas separation membrane 12 is connected with metallic members 21 and 22 by a glass 15 having a thermal expansion coefficient of 5.0-8.0.times.10.sup.-6 /.degree.C. Glass 15 contacts with metal supporters 21 and 22 with a contact angle of 90.degree. or less. The connected body of a gas separator and metallic supporters and an apparatus for separating hydrogen gas from a mixed gas display excellent durability and are free from leakage at the joints during the separation of hydrogen gas at high temperatures and under high pressure.
摘要:
A hydrogen preparing apparatus is disclosed which reforms a hydrocarbon and/or a hydrocarbon containing an oxygen atom to obtain a hydrogen-containing gas and separates hydrogen from this hydrogen-containing gas. The apparatus includes a porous substrate and a hydrogen separating film which is formed on a predetermined surface portion of the porous substrate and which selectively separates hydrogen, a reforming catalyst for reforming the hydrocarbon being supported in the pores of the porous substrate. A reforming catalyst for reforming the hydrocarbon is supported on a honeycomb carrier, and the hydrogen separating film is arranged on the downstream side of the honeycomb carrier. The surface area of the catalyst per unit volume of the apparatus can be increased, whereby the apparatus can be miniaturized. A hydrogen separating efficiency can also be improved. The hydrogen manufacturing apparatus can be prevented from being damaged by a difference of expansion between the porous substrate and the container.
摘要:
A hydrogen separator has a porous substrate having a through-hole, and a metal having a hydrogen separating ability coated on the inner surface of the through-hole of the porous substrate to close pores on the inner surface of the through-hole. A method for manufacturing a hydrogen separator by a chemical plating process, includes providing a porous substrate having a through-hole, and forcedly circulating a plating solution containing a metal having a hydrogen separating ability through the through-hole of the substrate. The inner surface of the through-hole is covered with the metal film having the hydrogen separating ability.
摘要:
A hydrogen preparing apparatus is disclosed which reforms a hydrocarbon and/or a hydrocarbon containing an oxygen atom to obtain a hydrogen-containing gas and separates hydrogen from this hydrogen-containing gas. The apparatus includes a porous substrate and a hydrogen separating film which is formed on a predetermined surface portion of the porous substrate and which selectively separates hydrogen, a reforming catalyst for reforming the hydrocarbon being supported in the pores of the porous substrate. A reforming catalyst for reforming the hydrocarbon is supported on a honeycomb carrier, and the hydrogen separating film is arranged on the downstream side of the honeycomb carrier. The surface area of the catalyst per unit volume of the apparatus can be increased, whereby the apparatus can be miniaturized. A hydrogen separating efficiency can also be improved. The hydrogen manufacturing apparatus can be prevented from being damaged by a difference of expansion between the porous substrate and the container.
摘要:
A method for separating p-xylene by separating and recovering only p-xylene from a p-xylene-containing raw material mixture under high-temperature and high-pressure conditions using a zeolite membrane as a separating membrane is provided. The p-xylene partial pressure at the raw material side of the separating membrane is kept at a sufficiently high pressure and the p-xylene partial pressure at the recovery side of the separating membrane is controlled at a pressure which is not higher than the inflection point of p-xylene adsorption curve. This method for separating p-xylene using a zeolite membrane as a separating membrane can secure a sufficient p-xylene permeation amount and has industrial applicability.
摘要:
A gas separator is here disclosed in which a metal for separating a gas is filled into pores opened on the surface of a porous substrate to close them. The thus constituted gas separator can prevent a material gas from leaking into a purified gas. A method for preparing the gas separator is also disclosed which comprises an activation step of immersing the porous substrate having a pair of surfaces in a solution containing an activated metal, while a pressure difference is set between the pair of surfaces, and a chemical plating step of filling the metal for separating the gas into the pores opened on the surface of the porous substrate to close these pores by chemical plating.
摘要:
There is a system for producing high-purity hydrogen by reforming a hydrocarbon and/or an oxygen atom-containing hydrocarbon to form a reformed gas containing hydrogen and separating the hydrogen from said gas. The system includes a hydrocarbon source, a water source, an oxygen source, a vaporization chamber connecting with the hydrocarbon source, the water source and the oxygen source, and a reforming chamber provided with a catalyst for steam reforming and partial oxidation and a hydrogen-separating membrane. The reforming chamber is thermally connected with the vaporization chamber. A process for producing high-purity hydrogen includes heating a reforming chamber provided with a hydrogen-separating membrane, feeding, into the reforming chamber, hydrocarbon, steam and oxygen or air to give rise to steam reforming and partial oxidation therein to produce a reaction gas, and passing the reaction gas through the hydrogen-separating membrane to recover high-purity hydrogen. The heat possessed by the portion of the reaction gas not permeable into the hydrogen-separating membrane and the heat generated by the partial oxidation are utilized for the heating and reforming of the hydrocarbon, water and oxygen or air.
摘要:
An NOx sensor has the sensor element made of an oxide, the resistance of which is varied in response to an NOx component in a gas to be measured, and a measuring portion for measuring a resistance variation of the sensor element and for detecting an NOx concentration in the gas to be measured. A catalyst is arranged at an upstream side of a flow of the gas to be measured with respect reach to the sensor element, which makes a partial pressure ratio of NO/NO.sub.2 reach to an equilibrium state and removes a CO component from the gas to be measured. A heater for adjusting a temperature is arranged at a position close to the sensor element, which maintains temperatures of the sensor element and the catalyst constant. An O.sub.2 sensor is arranged at a position close to the sensor element so that the measuring portion can detect accurately the concentration of Nox in the measurement gas by reference to the resistance of the sensor element.
摘要翻译:NOx传感器具有由氧化物制成的传感器元件,其电阻响应待测气体中的NOx成分而变化,测量部分用于测量传感器元件的电阻变化并用于检测NOx浓度 在要测量的气体中。 催化剂被布置在相对于传感器元件的被测量气体的流动的上游侧,这使得NO / NO 2的分压比达到平衡状态并从气体中除去CO成分 测量。 用于调节温度的加热器布置在接近传感器元件的位置,其保持传感器元件的温度和催化剂的恒定。 O2传感器布置在靠近传感器元件的位置,使得测量部分可以参考传感器元件的电阻精确地检测测量气体中的Nox的浓度。
摘要:
In one aspect of the invention, there is provided a molded article of crystalline thermoplastic resin with high gas barrier property of which the resin has crystalline and non-crystalline regions, the enhancing effect on gas barrier property of uniaxial-uniplanar orientation of the crystal axis direction of crystallites of said crystalline regions being used and the crystallites orientation being optimized by specific conditions. In another aspect of the invention, the molded article of the first aspect of the invention is further annealed to increase the crystallinity of the crystalline regions. The molded articles in accordance with the present invention have excellent gas barrier properties, and they are not only useful as chilled beef packaging materials, but also useful for retort food packaging, pouch packaging, coating and protecting materials for ham and sausages, processed fish, processed seafood products such as boiled fish paste, dried food for sprinkling, soup powder, parched rice cake, curry powder, spices, vegetables, fruits and pharmaceuticals.