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公开(公告)号：US20070202309A1
公开(公告)日：2007-08-30
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
IPC分类号： B32B7/02
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译： 树脂被覆金属片由金属片构成， 在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分， 下层树脂层。 存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。 由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。
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公开(公告)号：US07691483B2
公开(公告)日：2010-04-06
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译： 树脂被覆金属片由金属片构成， 在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分， 下层树脂层。 存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。 由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。
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公开(公告)号：US20080261063A1
公开(公告)日：2008-10-23
申请号：US11579795
申请日：2005-05-18
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
IPC分类号： B32B27/36
CPC分类号： B32B15/09 , B32B1/02 , B32B15/08 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2309/105 , B32B2439/66 , B65D65/42 , Y10T428/31797
摘要： The resin-coated metal sheet has: a metal sheet; a lower polyester resin layer having 0.03 or smaller plane orientation factor and 5 to 20 μm of thickness, being formed on at least one side of the metal sheet; and an upper polyester resin layer containing 0.1 to 5% by mass of olefin wax, having larger than 0.06 and not larger than 0.15 of plane orientation factor and 0.5 to 10 μm of thickness, being formed on the lower polyester resin layer. The metal sheet assures excellent taking-out performance of the contents also those of low fat and high protein foods, and provides formability and adhesion requested for the container working.
摘要翻译： 树脂涂覆的金属片具有：金属片; 在金属片的至少一面上形成具有0.03或更小的平面取向因子和5至20μm的厚度的下聚酯树脂层; 并且在下聚酯树脂层上形成含有0.1〜5质量％以上的具有大于0.06且不大于0.15的面取向因子和0.5至10微米厚度的烯烃蜡的上聚酯树脂层。 金属片材确保了低脂肪和高蛋白食品的内容物的良好的取出性能，并提供了容器加工所需的成形性和粘合性。
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公开(公告)号：US20090068481A1
公开(公告)日：2009-03-12
申请号：US11919682
申请日：2006-07-26
申请人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
发明人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
CPC分类号： B32B15/08 , B32B27/36 , Y10T428/1359 , Y10T428/24942 , Y10T428/31678 , Y10T428/31681
摘要： A resin-coated metal sheet includes resin layers formed on both surfaces thereof and composed of a polyester as a main component, wherein the resin layer covering the inner surface of a container after the formation thereof has an interfacial free energy with water of 30 mN/m or more. The container formed from the resin-coated metal sheet exhibits an excellent content release property for contents with a high protein content.
摘要翻译： 树脂涂覆的金属板包括在其两面上形成并由聚酯作为主要成分的树脂层，其中覆盖容器的形成后的容器内表面的树脂层具有与水的界面自由能为30mN / m以上。 由树脂涂覆的金属片形成的容器对于具有高蛋白质含量的内容物具有优异的含量释放性能。
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公开(公告)号：US08905256B2
公开(公告)日：2014-12-09
申请号：US11919682
申请日：2006-07-26
申请人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
发明人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
CPC分类号： B32B15/08 , B32B27/36 , Y10T428/1359 , Y10T428/24942 , Y10T428/31678 , Y10T428/31681
摘要： A resin-coated metal sheet includes resin layers formed on both surfaces thereof and composed of a polyester as a main component, wherein the resin layer covering the inner surface of a container after the formation thereof has an interfacial free energy with water of 30 mN/m or more. The container formed from the resin-coated metal sheet exhibits an excellent content release property for contents with a high protein content.
摘要翻译： 树脂涂覆的金属板包括在其两面上形成并由聚酯作为主要成分的树脂层，其中覆盖容器的形成后的容器内表面的树脂层具有与水的界面自由能为30mN / m以上。 由树脂涂覆的金属片形成的容器对于具有高蛋白质含量的内容物具有优异的含量释放性能。
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公开(公告)号：US20110274922A1
公开(公告)日：2011-11-10
申请号：US13127368
申请日：2009-11-12
IPC分类号： B32B7/12
CPC分类号： B32B15/09 , B32B7/12 , B32B15/18 , B32B27/06 , B32B27/36 , B32B2255/06 , B32B2255/205 , B32B2307/4026 , B32B2307/714 , B32B2307/738 , B32B2439/66 , C08K3/013 , C08K5/0041 , C08K5/42 , C08L61/28 , C08L61/32 , C08L63/00 , C08L79/04 , C08L2666/14 , C09J7/29 , C09J167/02 , C09J2205/102 , C09J2400/163 , C09J2463/00 , C09J2467/00 , C09J2467/006 , C09J2479/02 , Y10T428/2848
摘要： A colored laminated metal plate for containers includes a metal plate having one or both surfaces coated with a film for lamination in which a colored adhesive layer is coated to a polyester resin film. The colored adhesive layer contains a polyester resin as a main component and further contains an etherified amino resin, an epoxy resin, a strong acid compound, and a coloring agent. The colored laminated steel sheet is excellent in deep drawability, adhesion after forming, rust resistance of a damaged portion, and so on. When the steel sheet is applied to manufacturing of a container such as a can, retort whitening of the laminate film hardly occurs, and the design properties of appearance can be maintained.
摘要翻译： 用于容器的彩色层压金属板包括具有一个或两个表面的金属板，该金属板涂覆有用于层压的膜，其中着色粘合剂层涂覆到聚酯树脂膜上。 着色粘合剂层含有聚酯树脂作为主要成分，还含有醚化氨基树脂，环氧树脂，强酸化合物和着色剂。 着色层压钢板的深冲性，成型后的粘合性，损伤部的耐锈性等优异。 当将钢板应用于罐等容器的制造时，难以发生层压膜的蒸馏白化，可以保持外观的设计性。
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公开(公告)号：US5391290A
公开(公告)日：1995-02-21
申请号：US38529
申请日：1993-03-29
摘要： A method for continuously tin-electroplating a metal strip, which comprises the steps of: causing a DC electric current to flow between a metal strip and an anode arranged adjacent to the metal strip while passing the metal strip at a travelling speed of at least 1 m/minute through an acidic tin-electroplating solution containing tin ions and an organic acid within a range of from 4.8 to 98 g/l as converted into sulfuric acid, to form a tin-electroplating layer on at least one surface of the metal strip; and applying an ultrasonic vibration, emitted from at least one ultrasonic vibrator and having an intensity within a range of from 0.01 to 1,000 W/100 cm.sup.2 and a frequency within a range of from 25 to 55 kHz, to the acidic tin-electroplating solution between the metal strip and the anode, thereby removing a diffusion layer of tin ions existing in the acidic tin-electroplating solution adjacent to the surface of the metal strip.
摘要翻译： 一种用于连续锡电镀金属带的方法，其特征在于包括以下步骤：使金属带与邻近金属带布置的阳极之间的直流电流流动，同时使金属带以至少1的行进速度通过 m /分钟，通过含有锡离子和有机酸的酸性锡 - 电镀溶液，其转化为硫酸在4.8至98g / l的范围内，以在金属带的至少一个表面上形成锡 - 电镀层 ; 将从至少一个超声波振子发射的强度为0.01〜1000W / 100cm 2，频率范围为25〜55kHz的超声波振动施加到酸性锡 - 电镀液 金属带和阳极，从而除去存在于与金属带的表面相邻的酸性锡 - 电镀溶液中的锡离子的扩散层。
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公开(公告)号：US5275716A
公开(公告)日：1994-01-04
申请号：US029781
申请日：1993-03-11
CPC分类号： C25D5/48
摘要： A method for manufacturing a tin-electroplated cold-rolled steel strip, which comprises the steps of: continuously annealing a degreased cold-rolled steel strip; then, subjecting, following the continuous annealing treatment, the continuously annealed cold-rolled steel strip to a continuous tin-electroplating treatment in a tin-electroplating bath to form, on at least one surface of the cold-rolled steel strip, a tin-electroplating layer having a plating weight within a range of from 0.1 to 2.8 g/m.sup.2 per surface of the cold-rolled steel strip; and then, temper-rolling, following the continuous tin-electroplating treatment, the cold-rolled steel strip having the tin-electroplating layer on at least one surface thereof, at a reduction ratio within a range of from 1 to 5%.
摘要翻译： 一种用于制造镀锡冷轧钢带的方法，包括以下步骤：连续退火脱脂冷轧钢带; 然后，在连续退火处理之后，使连续退火的冷轧钢带在锡 - 电镀浴中进行连续锡电镀处理，以在冷轧钢带的至少一个表面上形成锡 - 电镀层，其镀层重量在冷轧钢带表面0.1〜2.8g / m2的范围内; 然后在连续锡电镀处理之后，在其至少一个表面上具有锡 - 电镀层的冷轧钢带以1％至5％的范围内的压缩比进行回火。
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公开(公告)号：US4875984A
公开(公告)日：1989-10-24
申请号：US309683
申请日：1989-02-10
申请人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
发明人： Hiroki Iwasa , Toyofumi Watanabe , Hirohide Furuya
IPC分类号： C25D11/38
CPC分类号： C25D11/38
摘要： A method for manufacturing an electrolytically chromated steel sheet, comprising the steps of: subjecting a steel sheet to an anodic electrolytic treatment with a quantity of electricity of from 0.3 to 30 coulomb/dm.sup.2 in an acidic electrolyte containing at least one of chromic anhydride, chromate and bichromate, to form a hydrated chromium oxide film having numerous holes and numerous thin portions over the entire area of at least one surface of the steel sheet; and then subjecting the anodically treated steel sheet to a cathodic electrolytic chromate treatment in an acidic electrolytic chromating solution to form on the at least one surface of the steel sheet a chromate film comprising a metallic chromium layer as a lower layer having thereon numerous granular projections, and a hydrated chromium oxide layer as an upper layer. The electrolytically chromated steel sheet manufactured in accordance with the method of the present invention has excellent secondary paint adhesion and weldability, and has a satisfactory surface hue.
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公开(公告)号：US07198856B2
公开(公告)日：2007-04-03
申请号：US10658220
申请日：2003-09-08
CPC分类号： B32B15/09 , B32B15/08 , B32B15/18 , B32B27/36 , B32B2439/66 , Y10T428/1359 , Y10T428/31605 , Y10T428/31681 , Y10T428/31786 , Y10T428/31935
摘要： A film-laminated metal sheet for container comprises resin films each containing polyester as a main component in two surfaces. A polarity force component γsh of an surface free energy of a surface where the resin film to be positioned on an inner surface side of the container after formation of the container is to be in contact with a content is 4×10−3 N/m or less.
摘要翻译： 用于容器的薄膜层叠金属片包括在两个表面中各自含有聚酯作为主要成分的树脂膜。 在形成容器后，位于容器的内表面侧的树脂膜与内容物接触的表面的表面自由能的极性力分量曲线<！ - SIPO
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