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公开(公告)号：US20070202309A1
公开(公告)日：2007-08-30
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinuke Watanabe , Mitsunori Ota
IPC分类号： B32B7/02
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译： 树脂被覆金属片由金属片构成， 在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分， 下层树脂层。 存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。 由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。
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公开(公告)号：US07691483B2
公开(公告)日：2010-04-06
申请号：US10594533
申请日：2005-03-30
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Shinsuke Watanabe , Mitsunori Ota
CPC分类号： C23C28/00 , B32B15/08 , B32B27/08 , B32B27/36 , B32B2307/4026 , B32B2307/518 , B32B2307/704 , B32B2307/728 , B32B2439/66 , B32B2439/70 , C09D167/02 , Y10T428/24942 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681
摘要： The resin-coated metal sheet is composed of: a metal sheet; a lower resin layer containing a hydrophilic copolyester, formed on at least one side of the metal sheet; and an upper resin layer containing a polyester containing a diol component composed of a diol derivative of 1 to 10% by mole of alicyclic compound and 99 to 90% by mole of ethylene glycol, and a dicarboxylic acid component consisting of terephthalic acid, formed on the lower resin layer. The sum of cyclic trimer of alkylene terephthalate existing in the upper resin layer and the lower resin layer is 0.9% or less by mass. Since the manufacture of food cans using the resin-coated metal sheet does not induce white haze phenomenon and retort blushing phenomenon on outer surface of the can even after retorting, the decorative appearance on outer surface of the can is not deteriorated.
摘要翻译： 树脂被覆金属片由金属片构成， 在所述金属板的至少一侧形成含有亲水性共聚酯的下层树脂层; 和含有由二醇衍生物构成的二醇成分的聚酯的上层树脂层，所述二醇成分由脂环族化合物为1〜10摩尔％的二醇衍生物和99〜90摩尔％的乙二醇构成，以及由对苯二甲酸组成的二羧酸成分， 下层树脂层。 存在于上树脂层和下树脂层中的对苯二甲酸亚烷基酯的环状三聚体的总和为0.9质量％以下。 由于使用树脂涂覆金属片的食品罐的制造即使在蒸煮后也不会引起罐外表面的白霾现象和蒸煮发白现象，所以罐外表面的装饰外观不会变差。
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公开(公告)号：US20080261063A1
公开(公告)日：2008-10-23
申请号：US11579795
申请日：2005-05-18
申请人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
发明人： Yoichiro Yamanaka , Takeshi Suzuki , Hiroki Iwasa , Junichi Kitagawa , Toyofumi Watanabe , Katsunori Nakai , Mitsunori Ota
IPC分类号： B32B27/36
CPC分类号： B32B15/09 , B32B1/02 , B32B15/08 , B32B27/08 , B32B27/18 , B32B27/36 , B32B2309/105 , B32B2439/66 , B65D65/42 , Y10T428/31797
摘要： The resin-coated metal sheet has: a metal sheet; a lower polyester resin layer having 0.03 or smaller plane orientation factor and 5 to 20 μm of thickness, being formed on at least one side of the metal sheet; and an upper polyester resin layer containing 0.1 to 5% by mass of olefin wax, having larger than 0.06 and not larger than 0.15 of plane orientation factor and 0.5 to 10 μm of thickness, being formed on the lower polyester resin layer. The metal sheet assures excellent taking-out performance of the contents also those of low fat and high protein foods, and provides formability and adhesion requested for the container working.
摘要翻译： 树脂涂覆的金属片具有：金属片; 在金属片的至少一面上形成具有0.03或更小的平面取向因子和5至20μm的厚度的下聚酯树脂层; 并且在下聚酯树脂层上形成含有0.1〜5质量％以上的具有大于0.06且不大于0.15的面取向因子和0.5至10微米厚度的烯烃蜡的上聚酯树脂层。 金属片材确保了低脂肪和高蛋白食品的内容物的良好的取出性能，并提供了容器加工所需的成形性和粘合性。
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公开(公告)号：US20090068481A1
公开(公告)日：2009-03-12
申请号：US11919682
申请日：2006-07-26
申请人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
发明人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
CPC分类号： B32B15/08 , B32B27/36 , Y10T428/1359 , Y10T428/24942 , Y10T428/31678 , Y10T428/31681
摘要： A resin-coated metal sheet includes resin layers formed on both surfaces thereof and composed of a polyester as a main component, wherein the resin layer covering the inner surface of a container after the formation thereof has an interfacial free energy with water of 30 mN/m or more. The container formed from the resin-coated metal sheet exhibits an excellent content release property for contents with a high protein content.
摘要翻译： 树脂涂覆的金属板包括在其两面上形成并由聚酯作为主要成分的树脂层，其中覆盖容器的形成后的容器内表面的树脂层具有与水的界面自由能为30mN / m以上。 由树脂涂覆的金属片形成的容器对于具有高蛋白质含量的内容物具有优异的含量释放性能。
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公开(公告)号：US08905256B2
公开(公告)日：2014-12-09
申请号：US11919682
申请日：2006-07-26
申请人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
发明人： Yoichiro Yamanaka , Junichi Kitagawa , Yoshihiko Yasue , Yasuhide Oshima , Hiroshi Kubo , Hiroki Iwasa , Shinsuke Watanabe , Katsunori Nakai
CPC分类号： B32B15/08 , B32B27/36 , Y10T428/1359 , Y10T428/24942 , Y10T428/31678 , Y10T428/31681
摘要： A resin-coated metal sheet includes resin layers formed on both surfaces thereof and composed of a polyester as a main component, wherein the resin layer covering the inner surface of a container after the formation thereof has an interfacial free energy with water of 30 mN/m or more. The container formed from the resin-coated metal sheet exhibits an excellent content release property for contents with a high protein content.
摘要翻译： 树脂涂覆的金属板包括在其两面上形成并由聚酯作为主要成分的树脂层，其中覆盖容器的形成后的容器内表面的树脂层具有与水的界面自由能为30mN / m以上。 由树脂涂覆的金属片形成的容器对于具有高蛋白质含量的内容物具有优异的含量释放性能。
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公开(公告)号：US20110274922A1
公开(公告)日：2011-11-10
申请号：US13127368
申请日：2009-11-12
IPC分类号： B32B7/12
CPC分类号： B32B15/09 , B32B7/12 , B32B15/18 , B32B27/06 , B32B27/36 , B32B2255/06 , B32B2255/205 , B32B2307/4026 , B32B2307/714 , B32B2307/738 , B32B2439/66 , C08K3/013 , C08K5/0041 , C08K5/42 , C08L61/28 , C08L61/32 , C08L63/00 , C08L79/04 , C08L2666/14 , C09J7/29 , C09J167/02 , C09J2205/102 , C09J2400/163 , C09J2463/00 , C09J2467/00 , C09J2467/006 , C09J2479/02 , Y10T428/2848
摘要： A colored laminated metal plate for containers includes a metal plate having one or both surfaces coated with a film for lamination in which a colored adhesive layer is coated to a polyester resin film. The colored adhesive layer contains a polyester resin as a main component and further contains an etherified amino resin, an epoxy resin, a strong acid compound, and a coloring agent. The colored laminated steel sheet is excellent in deep drawability, adhesion after forming, rust resistance of a damaged portion, and so on. When the steel sheet is applied to manufacturing of a container such as a can, retort whitening of the laminate film hardly occurs, and the design properties of appearance can be maintained.
摘要翻译： 用于容器的彩色层压金属板包括具有一个或两个表面的金属板，该金属板涂覆有用于层压的膜，其中着色粘合剂层涂覆到聚酯树脂膜上。 着色粘合剂层含有聚酯树脂作为主要成分，还含有醚化氨基树脂，环氧树脂，强酸化合物和着色剂。 着色层压钢板的深冲性，成型后的粘合性，损伤部的耐锈性等优异。 当将钢板应用于罐等容器的制造时，难以发生层压膜的蒸馏白化，可以保持外观的设计性。
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公开(公告)号：US20050260417A1
公开(公告)日：2005-11-24
申请号：US10658220
申请日：2003-09-08
CPC分类号： B32B15/09 , B32B15/08 , B32B15/18 , B32B27/36 , B32B2439/66 , Y10T428/1359 , Y10T428/31605 , Y10T428/31681 , Y10T428/31786 , Y10T428/31935
摘要： A film-laminated metal sheet for container comprises resin films each containing polyester as a main component in two surfaces. A polarity force component γsh of an surface free energy of a surface where the resin film to be positioned on an inner surface side of the container after formation of the container is to be in contact with a content is 4×10−3 N/m or less.
摘要翻译： 用于容器的薄膜层叠金属片包括在两个表面中各自含有聚酯作为主要成分的树脂膜。 在形成容器后，位于容器的内表面侧的树脂膜与内容物接触的表面的表面自由能的极性力分量曲线<！ - SIPO
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公开(公告)号：US07198856B2
公开(公告)日：2007-04-03
申请号：US10658220
申请日：2003-09-08
CPC分类号： B32B15/09 , B32B15/08 , B32B15/18 , B32B27/36 , B32B2439/66 , Y10T428/1359 , Y10T428/31605 , Y10T428/31681 , Y10T428/31786 , Y10T428/31935
摘要： A film-laminated metal sheet for container comprises resin films each containing polyester as a main component in two surfaces. A polarity force component γsh of an surface free energy of a surface where the resin film to be positioned on an inner surface side of the container after formation of the container is to be in contact with a content is 4×10−3 N/m or less.
摘要翻译： 用于容器的薄膜层叠金属片包括在两个表面中各自含有聚酯作为主要成分的树脂膜。 在形成容器后，位于容器的内表面侧的树脂膜与内容物接触的表面的表面自由能的极性力分量曲线<！ - SIPO
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9.发明申请公开(公告)号：US20060210817A1
公开(公告)日：2006-09-21
申请号：US11439469
申请日：2006-05-23
IPC分类号： B32B15/09
CPC分类号： B32B15/09 , B32B15/08 , B32B15/18 , B32B15/20 , B32B27/36 , B32B37/04 , B32B2250/03 , B32B2250/40 , B32B2274/00 , B32B2307/518 , B32B2307/746 , B32B2309/02 , B32B2309/04 , B32B2311/00 , B32B2311/30 , B32B2323/10 , B32B2367/00 , B32B2439/66 , B32B2439/70 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692 , Y10T428/31786 , Y10T428/31855
摘要： The present invention relates to a resin film laminated metal sheet for can, in which both faces of the metal sheet have resin film laminated layers, and a surface free energy γ s of a face of the resin film is 10 dyn/cm or more to less than 30 dyn/cm, the face becoming an inside of can after can-making and being contacted with stuffed food contents. As the resin film, applicable is a polypropylene film or a propylene ethylene based random copolymer film of polypropylene being a main component. Further, a resin film of polyester being a main component and containing a wax component of 0.1 to 2.0% is used in a resin film to be an inside of can after can-making. The resin film laminated metal sheet for can according to the invention has excellent formability and adhesion while can-making and superior taking-out property of stuffed food contents.
摘要翻译： 本发明涉及一种用于罐的树脂膜层叠金属片，其中金属片的两面具有树脂膜层压层，并且树脂膜的表面的表面自由能γs为10dyn / cm以上至 小于30达因/厘米，脸部在罐头制作后与内部食物接触。 作为树脂膜，可以使用作为主要成分的聚丙烯膜或丙烯乙烯系无规共聚物膜。 此外，作为主要成分的聚酯的树脂膜，其中含有蜡成分为0.1〜2.0％的树脂膜，可以在制罐后作为罐内使用。 本发明的罐用树脂膜层压金属板具有优良的成形性和附着力，同时可制造出具有优异的填充食品的取出性能。
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公开(公告)号：US20060147733A1
公开(公告)日：2006-07-06
申请号：US11360210
申请日：2006-02-23
CPC分类号： B32B15/09 , B32B15/08 , B32B15/18 , B32B27/36 , B32B2439/66 , Y10T428/1359 , Y10T428/31605 , Y10T428/31681 , Y10T428/31786 , Y10T428/31935
摘要： A film-laminated metal sheet for a container having laminated resin films, each resin film containing a polyester as a main component on an inner surface thereof and an outer surface thereof, wherein a polarity force component γsh of a surface free energy of a surface of the resin film that is to be positioned on an inner surface side of the container after formation of the container and that is to be in contact with a content of the container is 4×10−3 N/m or less, the resin film to be positioned on the inner surface side of the container after formation of the container and/or a resin film to be positioned on the outer surface side of the container after formation of the container contains a color pigment or a color dye.
摘要翻译： 一种用于容器的薄膜层压金属片，其具有层压树脂膜，每个树脂膜在其内表面上包含聚酯作为主要成分，并且其外表面，其中极性力分量相对于 在形成容器之后要被定位在容器的内表面侧并且与容器的内容物接触的树脂膜的表面的表面自由能为4×10 -3〜 N / m以下的树脂膜，在形成容器后形成容器和/或树脂膜的位于容器的内表面侧的树脂膜，形成容器后形成容器的外表面侧 含有着色颜料或着色剂。
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