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公开(公告)号：US20240360056A1
公开(公告)日：2024-10-31
申请号：US18756640
申请日：2024-06-27
发明人： Andrew P. SHARRATT
CPC分类号： C07C17/087 , B01J23/26 , B01J37/03 , B01J37/26 , C07C17/10 , C07C17/206 , B01J35/613 , B01J35/615
摘要： A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity and from 0.1 to 8.0% by weight of the chromium in the catalyst based on the total weight of the chromium is present as chromium (VI). The use of the zinc-promoted, chromium-containing catalyst in a fluorination process in which a hydrocarbon or halogenated hydrocarbon is reacted with hydrogen fluoride in the vapour-phase at elevated temperatures is also described.
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公开(公告)号：US12037312B2
公开(公告)日：2024-07-16
申请号：US17050139
申请日：2019-04-25
申请人： SOLVAY SA
发明人： Sebastian Hasenstab-Riedel , Jan Hendrick Nissen , Helmut Beckers , Simon Steinhauer , Thomas Drews , Holger Pernice
IPC分类号： C07C407/00 , B01J27/12 , B01J37/26
CPC分类号： C07C407/00 , B01J27/12 , B01J37/26
摘要： The present invention relates to the preparation of perfluorinated or partially fluorinated peroxides which avoids the use of carbonyl fluoride (COF2).
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3.发明公开公开(公告)号：US20240199510A1
公开(公告)日：2024-06-20
申请号：US18536405
申请日：2023-12-12
CPC分类号： C07C2/10 , B01J21/04 , B01J21/08 , B01J21/16 , B01J37/0215 , B01J37/20 , B01J37/26 , C07C2521/12
摘要： Oligomer products are produced by reacting an alpha olefin and a vinylidene compound in the presence of a solid catalyst, such as a solid oxide or a chemically-treated solid oxide. Metallocene compounds, organoaluminum compounds, and BF3 are not needed to perform the reaction. Oligomer products formed by processes disclosed herein have a trimer:tetramer weight ratio of at least 2:1.
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公开(公告)号：US11878290B2
公开(公告)日：2024-01-23
申请号：US17427554
申请日：2020-02-24
申请人： Zhejiang Research Institute of Chemical Industry Co., Ltd. , Zhejiang Lantian Environmental Protection Hi-Tech Co., Ltd. , Sinochem Lantian Co., Ltd.
发明人： Jianjun Zhang , Wenfeng Han , Shucheng Wang , Wucan Liu , Feixiang Zhou
IPC分类号： B01J27/13 , B01J27/132 , B01J37/26 , C07C17/20
CPC分类号： B01J27/132 , B01J27/13 , B01J37/26 , C07C17/202 , C07C17/204 , C07C17/206
摘要： Disclosed is a method for reducing carbon deposits on a catalyst in recycling HFC-23. The recycling is realized by means of a fluorine-chlorine exchange reaction with HFC-23 and a halogenated hydrocarbon. The catalyst for the fluorine-chlorine exchange reaction comprises a main body catalyst and a precious metal. The precious metal is selected from at least one of Pt, Pd, Ru, Au or Rh, and has an addition amount of 0.01-2 wt %. During the fluorine-chlorine exchange reaction, hydrogen gas is introduced. The invention has advantages of good catalyst stability, long life, etc.
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公开(公告)号：US11547990B2
公开(公告)日：2023-01-10
申请号：US17455974
申请日：2021-11-22
发明人： Mario Joseph Nappa
摘要： A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.
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公开(公告)号：US11311863B2
公开(公告)日：2022-04-26
申请号：US16923324
申请日：2020-07-08
IPC分类号： B01J29/08 , B01J27/13 , B01J29/60 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/24 , B01J37/26 , C10G55/00 , B01J29/62 , B01J29/63 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/10 , B01J37/22
摘要： A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.
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公开(公告)号：US11141718B2
公开(公告)日：2021-10-12
申请号：US16251196
申请日：2019-01-18
发明人： Ryan W. Snell , Xianghong Hao
IPC分类号： B01J29/74 , B01J37/06 , B01J37/02 , B01J35/10 , B01J23/42 , B01J29/62 , C10G35/095 , C10G45/70 , B01J27/138 , B01J27/10 , B01J27/12 , B01J37/08 , B01J37/22 , B01J37/24 , B01J37/26 , B01J37/30 , B01J37/00 , B01J23/58
摘要： Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of washing the bound zeolite base in the presence of an alkali metal, prior to impregnating the bound zeolitic support with the transition metal. Alkali metals such as potassium and cesium may be used.
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公开(公告)号：US11103856B2
公开(公告)日：2021-08-31
申请号：US15972757
申请日：2018-05-07
IPC分类号： B01J29/62 , B01J27/13 , B01J29/60 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/24 , B01J37/26 , C10G55/00 , B01J29/08 , B01J29/63 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/10 , B01J37/22
摘要： A process of making an aromatization catalyst comprising: (a) mixing a zeolite, a binder, and water to form a mixture; (b) extruding the mixture to form a green extrudate; (c) drying the green extrudate to form a dried green extrudate; (d) calcining the dried green extrudate to form a support, wherein calcining the dried green extrudate is the only calcination step in the process; (e) washing the support to form a washed support; (f) drying the washed support to form a dried washed support; (g) impregnating the dried washed support with a Group 8-10 transition metal compound and at least one halide-containing compound to form a metalized-halided material; and (h) vacuum drying the metalized-halided material to form a dried metalized-halided material which is the aromatization catalyst.
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公开(公告)号：US20210094911A1
公开(公告)日：2021-04-01
申请号：US17050139
申请日：2019-04-25
申请人： SOLVAY SA
发明人： Sebastian HASENSTAB-RIEDEL , Jan Hendrick NISSEN , Helmut BECKERS , Simon STEINHAUER , Thomas DREWS , Holger PERNICE
IPC分类号： C07C407/00 , B01J27/12 , B01J37/26
摘要： The present invention relates to the preparation of perfluorinated or partially fluorinated peroxides which avoids the use of carbonyl fluoride (COF2).
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10.发明授权公开(公告)号：US10604417B2
公开(公告)日：2020-03-31
申请号：US16457892
申请日：2019-06-28
发明人： Yuzhong Zhang , Leitao Zhang , Hong Li
IPC分类号： C01F17/00 , B01D53/02 , B01J20/02 , B01J20/28 , B01J20/30 , B01J27/12 , B01J35/00 , B01J35/10 , B01J37/04 , B01J37/26 , H01M4/58 , B82Y30/00 , B82Y40/00
摘要： The present application provides a method for preparing lanthanide fluoride two-dimensional porous nanosheets and belongs to the field of novel materials. In the present application, mixing a water-soluble lanthanide metal salt and an aqueous solution of sodium acetate in a nitrogen atmosphere to obtain a mixed solution, and adding an aqueous solution of fluorine-containing salt to the mixed solution obtained for precipitation reaction to produce lanthanide fluoride two-dimensional porous nanosheets. In the preparation process provided by the present application, no additional surfactant or template agent needs to be added, the pollution of the surfactant to the surface of the prepared material is avoided and the tedious after-treatment steps to template agent are reduced. Accordingly, the large-scale production can be realized, and the lanthanide fluoride two-dimensional porous nanosheets constructed by nanoparticles are prepared in large scale by one step. Moreover, no other organic solvents are required, and the pollution to the environment during the preparation process is avoided.
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