公开(公告)号：US20220356290A1

公开(公告)日：2022-11-10

申请号：US17635192

申请日：2021-08-06

Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.

Inventor： Mika NAKASHIMA ,  Daisuke SUNAGA

IPC: C08G2/30 ,  C08K5/3492 ,  C08K5/13 ,  C08K5/17 ,  B29C48/00

Abstract: The present invention provides a method for producing an oxymethylene copolymer resin composition, comprising: adding to an oxymethylene copolymer (A), an Mn micromole of an amine-substituted triazine compound (B) per gram of the oxymethylene copolymer (A), an Mc micromole of a choline hydroxide (C) per gram of the oxymethylene copolymer (A), and 0.05 to 1.1 parts by weight of an antioxidant (D) with respect to 100 parts by weight of the oxymethylene copolymer (A), and melt kneading a mixture of the oxymethylene copolymer (A), amine-substituted triazine compound (B), the choline hydroxide (C), and the antioxidant (D), wherein Mn (μmol/g-POM) and Mc (μmol/g-POM) satisfy: 6.5

公开(公告)号：US09534090B2

公开(公告)日：2017-01-03

申请号：US14654640

申请日：2013-12-16

Applicant: Covestro Deutschland AG

Inventor： Thomas Ernst Müller ,  Christoph Gürtler ,  Walter Leitner ,  Henning Vogt ,  Gabor Barath

IPC: C08G18/56 ,  C08G81/00 ,  C08G18/71 ,  C08G2/30 ,  C08G65/333 ,  C08G65/00 ,  C08G65/331

CPC classification number: C08G81/00 ,  C08G2/30 ,  C08G18/56 ,  C08G18/71 ,  C08G65/002 ,  C08G65/331 ,  C08G65/33348

Abstract: The invention relates to a method for producing NCO-modified polyoxymethylene block copolymers comprising the step of polymerizing formaldehyde in a reaction vessel in the presence of a catalyst, the polymerization of formaldehyde in addition taking place in the presence of a starter compound comprising at least 2 Zerewitinoff active H atoms to obtain an intermediate product. The intermediate product obtained is reacted further with an isocyanate to obtain an NCO-modified polyoxymethylene block copolymer. The invention also relates to NCO-modified polyoxymethylene block copolymers obtained by a method of this type and to the use of said copolymers for producing polyurethane polymers.

Abstract translation: 本发明涉及一种生产NCO-改性聚甲醛嵌段共聚物的方法，其包括在催化剂存在下在反应容器中聚合甲醛的步骤，另外在存在起始化合物的情况下进行甲醛的聚合，所述起始化合物包含至少2 Zerewitinoff活性H原子获得中间产物。 所获得的中间产物进一步与异氰酸酯反应，得到NCO-改性的聚甲醛嵌段共聚物。 本发明还涉及通过这种方法获得的NCO改性的聚甲醛嵌段共聚物和所述共聚物用于生产聚氨酯聚合物的用途。

公开(公告)号：US20110303876A1

公开(公告)日：2011-12-15

申请号：US13203506

申请日：2010-02-01

Applicant: Aurélie Ludemann ,  Rémi Manouk Anémian ,  Alice Julliart

Inventor： Aurélie Ludemann ,  Rémi Manouk Anémian ,  Alice Julliart

IPC: H01B1/12 ,  C09K11/06 ,  C08G2/30 ,  C08G2/18

CPC classification number: H01L51/0035 ,  C08G61/12 ,  C08G73/026 ,  C08G73/0672 ,  C08J3/24 ,  C08J2379/02 ,  C08J2379/04 ,  C09D165/00 ,  C09K11/06 ,  C09K2211/1433 ,  C09K2211/1466 ,  H01B1/12 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H05B33/14 ,  Y02E10/549

Abstract: The present invention relates to a polymer which comprises at least one structural unit which contains at least one aldehyde group, and to a process for the preparation of a crosslinkable or crosslinked polymer including a polymer which contains aldehyde groups. The present invention thus also relates to a crosslinkable polymer and a crosslinked polymer which is prepared by the process according to the invention, and to the use of this crosslinked polymer in electronic devices, in particular in organic electroluminescent devices, so-called OLEDs (OLED=organic light emitting device).

Abstract translation: 本发明涉及包含至少一个含有至少一个醛基的结构单元的聚合物，以及一种制备包含含有醛基的聚合物的可交联或交联的聚合物的方法。 因此，本发明还涉及通过本发明的方法制备的可交联聚合物和交联聚合物，以及该交联聚合物在电子器件中的用途，特别是在有机电致发光器件中，所谓的OLED（OLED =有机发光装置）。

公开(公告)号：US5852135B1

公开(公告)日：2000-05-09

申请号：US75052396

申请日：1996-12-12

Applicant: POLYPLASTICS CO

Inventor： KANAI HIROYUKI ,  SERIZAWA HAJIME ,  MATSUSHIMA MITSUNORI

IPC: C08F283/06 ,  C08F290/06 ,  C08G2/30 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L25/04 ,  C08L51/06 ,  C08L51/08 ,  C08L53/00 ,  C08L55/02 ,  C08L59/00 ,  C08L67/00 ,  C08L69/00 ,  C08L75/04 ,  C08L77/00 ,  C08L101/00 ,  C08L61/02

CPC classification number: C08L59/00 ,  C08F283/06 ,  C08F290/062 ,  C08G2/30 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L25/04 ,  C08L51/06 ,  C08L51/08 ,  C08L53/00 ,  C08L55/02 ,  C08L67/00 ,  C08L69/00 ,  C08L75/04 ,  C08L77/00 ,  C08L101/00 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14 ,  C08L2666/18 ,  C08L2666/24 ,  C08L2666/16

公开(公告)号：US5608030A

公开(公告)日：1997-03-04

申请号：US290377

申请日：1994-08-15

Applicant: Michael Hoffmockel ,  Karl-Friedrich M uck ,  Helmut Schlaf ,  Karlheinz Burg

Inventor： Michael Hoffmockel ,  Karl-Friedrich M uck ,  Helmut Schlaf ,  Karlheinz Burg

IPC: B01J19/24 ,  C08G2/00 ,  C08G2/10 ,  C08G2/30 ,  C08G63/78

CPC classification number: B01J19/2415 ,  C08G2/10 ,  C08G2/30 ,  B01J2219/00162 ,  B01J2219/00166

Abstract: Process for continuous preparation of homo- and copolyoxymethylenes with stable end groups in a homogeneous phase, in which in a tubular reactor with static mixing elements cyclic formaldehyde oligomers are polymerized in the presence of protonic acids as initiators in amounts of 0.005 to 500 ppm in a polymerization zone, in which the residence time of the reaction components in this zone is 0.1 to 10 min and in which the initiator is deactivated immediately after polymerization, there being a fluid transition between the polymerization and deactivator zones which is determined solely by the addition of deactivator, and in which, besides deactivation, stabilization of the chain ends is carried out in the presence of residual monomers, with the volatile constituents being removed from the reaction mixture in a subsequent vent unit. Stabilization is carried out in the presence of alkaline substances, either at temperatures of 150.degree. C. to 250.degree. C., if necessary in the presence of water or primary alcohols, or at 175.degree. C. to 250.degree. C. in the absence of these additives.

Abstract translation: 在均相中连续制备具有稳定端基的均聚和共聚氧亚甲基的方法，其中在具有静态混合元件的管式反应器中，环状甲醛低聚物在质子酸作为引发剂存在下聚合，其量为0.005-500ppm 聚合区，其中反应组分在该区域中的停留时间为0.1至10分钟，其中引发剂在聚合后立即失活，在聚合和失活区之间存在流体转变，其仅通过加入 除去失活之外，在残留单体的存在下进行链端的稳定化，其中挥发性成分在随后的通风单元中从反应混合物中除去。 在碱性物质的存在下，如果需要，在水或伯醇的存在下，或在175℃至250℃下，在不存在碱的条件下，在碱性物质的存在下，在150℃至250℃的温度下进行稳定化 的这些添加剂。

公开(公告)号：US5557012A

公开(公告)日：1996-09-17

申请号：US461995

申请日：1995-06-05

Applicant: Thomas R. Bierschenk ,  Timothy J. Juhlke ,  Hajimu Kawa ,  Richard J. Lagow

Inventor： Thomas R. Bierschenk ,  Timothy J. Juhlke ,  Hajimu Kawa ,  Richard J. Lagow

IPC: C07C41/48 ,  C07C41/60 ,  C07C43/313 ,  C07C43/315 ,  C08G2/30 ,  C08G4/00 ,  C08G65/00 ,  C08G65/30 ,  C08G65/323 ,  C08G65/34 ,  C08G65/46 ,  C07C59/245 ,  C07C43/30 ,  C07C43/32

CPC classification number: C07C41/48 ,  C07C41/60 ,  C07C43/313 ,  C07C43/315 ,  C08G2/30 ,  C08G4/00 ,  C08G65/007 ,  C08G65/30 ,  C08G65/3236 ,  C08G65/34 ,  C08G65/46

Abstract: This invention pertains to perfluoropolyethers and perhalogenated chlorofluoroether polymers that can be prepared by fluorinating polymers made by the polymerization of acetals, ketals, polyacetals, polyketals and orthoesters with elemental fluorine.

公开(公告)号：US5202501A

公开(公告)日：1993-04-13

申请号：US754184

申请日：1991-08-27

Applicant: Richard J. Lagow ,  Thomas R. Bierschenk ,  Timothy J. Juhlke

Inventor： Richard J. Lagow ,  Thomas R. Bierschenk ,  Timothy J. Juhlke

IPC: C08G2/30 ,  C08G65/00 ,  C08G65/323 ,  C10M107/38 ,  C10M119/22

CPC classification number: C10M107/38 ,  C08G2/30 ,  C08G65/007 ,  C08G65/3236 ,  C10M119/22

Abstract: Perfluoropolyethers containing high concentrations of difluoromethylene oxide units in the polymer chain are disclosed.

Abstract translation: 公开了在聚合物链中含有高浓度的二氟亚甲基氧化物单元的全氟聚醚。

公开(公告)号：US4959404A

公开(公告)日：1990-09-25

申请号：US266800

申请日：1988-11-03

Applicant: Toshio Nakane ,  Yukihiko Kageyama ,  Kenji Hijikata

Inventor： Toshio Nakane ,  Yukihiko Kageyama ,  Kenji Hijikata

IPC: C08G2/22 ,  C08G2/18 ,  C08G2/30 ,  C08G2/38 ,  C08G59/00 ,  C08G77/46 ,  C08L27/12 ,  C08L59/00 ,  C08L63/00 ,  C08L67/00 ,  C08L67/02 ,  C08L83/04 ,  C08L101/00

CPC classification number: C08L59/00 ,  C08G2/38 ,  C08G77/46 ,  C08L101/00 ,  C08L67/02 ,  C08L27/12 ,  C08L83/04

Abstract: A thermoplastic resin composition comprises a resin dispersion which includes a thermoplastic resin component having a solubility parameter .delta. of at least 9.5 cal.sup.1/2 cm.sup.-3/2, a modifier component having a solubility parameter .delta. of not higher than 8.5 cal.sup.1/2 cm.sup.-3/2, and a dispersibility improver comprising a silicon-containing polyacetal copolymer having (i) a siloxane segment derived from 0.01 to 30 wt. % of a terminal-reactive silicone oil of the following general formula I: ##STR1## wherein R.sub.1 represents an alkyl or phenyl group, R.sub.2 represents a divalent organic group, X represents a group selected from the group consisting of --NH.sub.2, --OH, ##STR2## --R.sub.4 OH, --R.sub.5 COOH, --R.sub.6 COOR.sub.7, --R.sub.8 and --OR.sub.9, R.sub.3 represents a divalent organic group, R.sub.4 to R.sub.6 each represent an alkylene group having 1 to 10 carbon atoms, R.sub.7 to R.sub.9 each represent an alkyl group having 1 to 10 carbon atoms and n represents a number between 5 to 10.

公开(公告)号：US4772662A

公开(公告)日：1988-09-20

申请号：US900915

申请日：1986-08-26

Applicant: Andre Collart ,  Fredy Declerck

Inventor： Andre Collart ,  Fredy Declerck

IPC: C08G2/00 ,  C08G2/18 ,  C08G2/22 ,  C08G2/30 ,  C08G2/36 ,  C08L1/00 ,  C08L59/00 ,  C08L71/02

CPC classification number: C08G2/22 ,  C08G2/30 ,  C08G2/36 ,  C08L59/00 ,  C08L71/02 ,  C08L1/00

Abstract: Process for manufacturing oxymethylene copolymers stabilized against thermal degradation, comprising the heating of the copolymer in a medium containing water and a disubstituted cellulose ether.

Abstract translation: 制备耐热降解稳定的甲醛共聚物的方法，包括在含有水和二取代的纤维素醚的介质中加热共聚物。

公开(公告)号：US4731434A

公开(公告)日：1988-03-15

申请号：US628537

申请日：1984-07-06

Applicant: Jorg Dorffel

Inventor： Jorg Dorffel

IPC: C08G6/00 ,  C08G4/00 ,  C08G6/02 ,  C08G2/30

CPC classification number: C08G6/02

Abstract: Condensation resins obtained by the polycondensation of alkyl aryl ketones and formaldehyde, wherein the polycondensation mixture contains 0.05 to 5% by weight, based on the alkyl aryl ketone, of an activator having the formula (A) ##STR1## wherein X is a nitrogen or phosphorus atom; R.sub.1, R.sub.2 and R.sub.3 are each independently a C.sub.1-3 -alkyl group or a phenyl group; and Y.sup.- is the anion of an inorganic or organic acid, have higher softening points than resins prepared by analogous processes but without the activator.

Abstract translation: 通过烷基芳基酮和甲醛的缩聚获得的缩合树脂，其中所述缩聚混合物基于烷基芳基酮含有0.05至5重量％的具有式（A）的活化剂，其中X为 氮或磷原子; R1，R2和R3各自独立地为C1-3烷基或苯基; 和Y-是无机或有机酸的阴离子，具有比通过类似方法制备但不含活化剂制备的树脂更高的软化点。