METAL COMPLEX AND ELECTRON TRANSPORTING MATERIAL COMPRISING SAME

    公开(公告)号:US20220344599A1

    公开(公告)日:2022-10-27

    申请号:US17765978

    申请日:2020-10-02

    申请人: DYDEN CORPORATION

    摘要: Provided is a novel metal complex that can be used as an electron transporting material. A metal complex represented by the following Formula (1) to the following Formula (3). RA1 to RA9, RC1 to RC8, and RE1 to RE6 are each independently a single bond, an alkylene group, an arylene group, a heteroarylene group, or a group represented by —RP1—P(═O)RP2—RP3—, RB1 to RB9, RD1 to RD8, and RF1 to RF6 are each independently a hydrogen atom, an. alkyl group, an aryl group, a heteroaryl group, an alkoxy group, an aryloxy group, a heteroaryloxv group, an amino group, a cyano group, a halogen atom, or a hydroxy group, one or more selected from the group consisting of RB1 to RB9 are a phenanthrolinyl group, one or more selected from the group consisting of RD1 to RD8 are a phenanthrolinyl group, and one or more selected from the group consisting of RF1 to RF6 are a phenanthrolinyl group, M is an alkali metal or an alkaline earth metal, Z is 1 or 2, and X is O or S.

    Organolithium process under continuous flow conditions

    公开(公告)号:US11407769B2

    公开(公告)日:2022-08-09

    申请号:US16763775

    申请日:2018-11-13

    IPC分类号: C07F1/02 B01J19/00

    摘要: The invention relates to methods for CC bond formation using organolithium compounds under continuous flow conditions in a micro or mesoreactor system, wherein an organic substrate is reacted with an alkyl lithium compound in the presence of a donor solvent to form a Li intermediate, which can be reacted in situ or subsequently in a second reaction step with an electrophile to form an organic secondary product, the organolithium compound RLi being used as a solution in a hydrocarbon or hydrocarbon mixture and the RLi concentration being at least 3 M, preferably at least 4 M.