公开(公告)号：US20170275430A1

公开(公告)日：2017-09-28

申请号：US15509294

申请日：2015-09-01

Applicant: Michael KUBE ,  Zuhal TUNCAY ,  Sandra REEMERS ,  Friedrich Georg SCHMIDT ,  Emmanouil SPYROU

Inventor： Michael KUBE ,  Zuhal TUNCAY ,  Sandra REEMERS ,  Friedrich Georg SCHMIDT ,  Emmanouil SPYROU

IPC: C08J5/24 ,  B29C70/06

CPC classification number: C08J5/24 ,  B29C70/06 ,  C08J3/243

Abstract: The invention relates to a process for producing storage-stable polyurethane prepregs and mouldings produced therefrom (composite components). For production of the prepregs or components, for example, (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalized (meth)acrylate monomers and/or hydroxy-functionalized (meth)acrylate polymers are mixed with non-(meth)acrylic polyols and with uretdione materials. This mixture or solution is applied to fibre material, for example carbon fibres, glass fibres or polymer fibres, by known methods and polymerized thermally, via a redox initiation or with the aid of radiation or plasma applications.Polymerization, for example at room temperature or at up to 80° C., gives rise to thermoplastics or thermoplastic prepregs which can subsequently be subjected to a forming operation. The hydroxy-functionalized (meth)acrylate constituents and the polyols can subsequently be crosslinked with the uretdiones already present in the system by means of elevated temperature. In this way, dimensionally stable thermosets or crosslinked composite components can be produced.

公开(公告)号：US20160177123A1

公开(公告)日：2016-06-23

申请号：US14958962

申请日：2015-12-04

Applicant: Emmanouil SPYROU ,  Zuhal Tuncay ,  Andrea Diesveld ,  Marion Ewald ,  Holger Loesch

Inventor： Emmanouil SPYROU ,  Zuhal Tuncay ,  Andrea Diesveld ,  Marion Ewald ,  Holger Loesch

IPC: C09D133/08 ,  B05D3/06

CPC classification number: C09D133/08 ,  B05D3/06 ,  C08F2/50 ,  C08F220/20 ,  C08F2220/281 ,  C08F2220/343 ,  C09D133/10 ,  G03F7/027 ,  G03F7/029 ,  G03F7/031 ,  C08F2220/1875 ,  C08F2222/1013 ,  C09D4/06 ,  C08F265/06

Abstract: A thermally curable and radiation-curable formulation, contains A) 45% to 99.9% by weight of at least one radiation-curable component; and B) 0.1% to 5% by weight of at least one selected free-radically initiating photo-initiator; and optionally C) 0.01% to 50% by weight of at least one additive; wherein the sum total of A) and B) and any C) is 100% by weight. The formulation is curable with actinic radiation and/or thermally and is used, for example, for the production of pigmented and pigment-free coating materials, and for adhesives and sealants.

Abstract translation: 一种可热固化和可辐射固化的制剂，含有A）45重量％至99.9重量％的至少一种可辐射固化组分; 和B）0.1重量％至5重量％的至少一种选择的自由引发的光引发剂; 和任选的C）0.01重量％至50重量％的至少一种添加剂; 其中A）和B）和任何C）的总和为100重量％。 该制剂可用光化辐射和/或热固化，并用于例如生产着色和不含颜料的涂料，以及用于粘合剂和密封剂。

公开(公告)号：US20160023384A1

公开(公告)日：2016-01-28

申请号：US14774395

申请日：2014-02-26

Applicant: Emmanouil SPYROU ,  Günter SCHMITT ,  Friedrich Georg SCHMIDT ,  Sandra REEMERS ,  Birte OLLAND ,  Michael SPITTLER ,  Holger LOESCH

Inventor： Emmanouil SPYROU ,  Guenter SCHMITT ,  Friedrich Georg SCHMIDT ,  Sandra REEMERS ,  Birte OLLAND ,  Michael SPITTLER ,  Holger LOESCH

IPC: B29C43/00 ,  C08J3/24 ,  C08J3/28 ,  C08J5/24 ,  C08J5/04

CPC classification number: B29C43/003 ,  B29C70/50 ,  B29K2033/08 ,  B29K2033/12 ,  C08F220/18 ,  C08F220/28 ,  C08F290/067 ,  C08F297/06 ,  C08G18/672 ,  C08G18/798 ,  C08G18/8025 ,  C08J3/24 ,  C08J3/28 ,  C08J5/043 ,  C08J5/24 ,  C08J2375/04 ,  C08J2375/06

Abstract: The invention relates to a process for producing storage-stable polyurethane prepregs and to mouldings (composite components) produced therefrom. The prepregs and, respectively, components are produced by mixing (meth)acrylate monomers, (meth)acrylate polymers, hydroxy-functionalised (meth)acrylate monomers and/or hydroxy-functionalised (meth)acrylate polymers with uretdione materials. Photoinitiators can also optionally be added. This mixture or solution is applied by known processes to fibre material, e.g. carbon fibres, glass fibres or polymer fibres, and is polymerised with the aid of radiation or of plasma methods. Polymerisation, e.g. at room temperature or at up to 80° C., gives thermoplastics or thermoplastic prepregs, and these can subsequently also be subjected to forming processes. The hydroxy-functionalised (meth)acrylate constituents can then be crosslinked with the uretdiones already present within the system, by use of elevated temperature. It is thus possible to produce dimensionally stable thermosets or dimensionally stable crosslinked composite components.

Abstract translation: 本发明涉及一种用于制备储存稳定的聚氨酯预浸料的方法和由其制备的模制品（复合组分）。 通过将（甲基）丙烯酸酯单体，（甲基）丙烯酸酯聚合物，羟基官能化的（甲基）丙烯酸酯单体和/或羟基官能化的（甲基）丙烯酸酯）聚合物与脲二酮材料混合，分别制备预浸料。 也可以加入光引发剂。 该混合物或溶液通过已知方法施用于纤维材料，例如 碳纤维，玻璃纤维或聚合物纤维，并借助辐射或等离子体方法聚合。 聚合，例如 在室温或高达80℃下，得到热塑性塑料或热塑性预浸料，随后也可以进行成型工艺。 羟基官能化的（甲基）丙烯酸酯组分然后可以通过使用升高的温度与已经存在于体系内的脲化合物交联。 因此可以制备尺寸稳定的热固性材料或尺寸稳定的交联复合材料组件。

公开(公告)号：US20160017179A1

公开(公告)日：2016-01-21

申请号：US14796619

申请日：2015-07-10

Applicant: Emmanouil SPYROU ,  Andrea DIESVELD ,  Andrea THESING ,  Holger LOESCH

Inventor： Emmanouil SPYROU ,  Andrea DIESVELD ,  Andrea THESING ,  Holger LOESCH

IPC: C09D175/12 ,  C09J175/12

CPC classification number: C09D175/12 ,  C08G18/003 ,  C08G18/1875 ,  C08G18/4236 ,  C08G18/798 ,  C08K5/1515 ,  C09D175/06 ,  C09J175/12

Abstract: A high-reactivity polyurethane composition useful in coatings and adhesives, contains the following components A)-D): A) 5 to 98.7 wt %, based on the total mass of the components, of at least one compound containing an uretdione group, and a free NCO content of less than 5 wt %, and an uretdione content of 2 to 25 wt %, based on i) aliphatic and/or (cyclo)aliphatic and/or cycloaliphatic polyisocyanates and ii) compounds containing hydroxyl groups; B) 0.2 to 5 wt %, based on the total mass of the components, of at least one catalyst selected from the group consisting of a substituted carbonate salt having a quaternary ammonium counterion, a substituted carbonate salt having a quaternary phosphonium counterion and mixtures thereof; C) 0.1 to 10 wt %, based on the total mass of the components, of at least one cocatalyst having at least one epoxide group; D) 1 to 90 wt %, based on the total mass of the components, of at least one polymer containing a hydroxyl group and having an OH number of between 20 and 1000 mg KOH/gram; wherein a sum of all components A)-D) is 100 wt %.

Abstract translation: 用于涂料和粘合剂的高反应性聚氨酯组合物含有以下组分A）-D）：A）至少一种含有脲二酮基团的化合物为5〜98.7重量％，基于组分的总质量， 基于i）脂族和/或（环）脂族和/或脂环族多异氰酸酯和ii）含羟基的化合物，游离NCO含量小于5重量％，脲二酮含量为2至25重量％ B）0.2至5重量％，基于组分的总质量，至少一种催化剂选自具有季铵抗衡离子的取代碳酸盐，具有季鏻抗衡离子的取代碳酸盐及其混合物 ; C）0.1至10重量％，基于组分的总质量，至少一种具有至少一个环氧基团的助催化剂; D）1至90重量％，基于组分的总质量，至少一种含羟基并且OH值为20至1000mg KOH /克的聚合物; 其中所有组分A）-D）的总和为100重量％。

公开(公告)号：US20150274760A1

公开(公告)日：2015-10-01

申请号：US14433186

申请日：2013-09-25

Applicant: Emmanouil SPYROU ,  Manfred KRECZINSKI ,  Holger LOESCH ,  Andrea THESING ,  Lars HELLKUHL

Inventor： Emmanouil Spyrou ,  Manfred Kreczinski ,  Holger Loesch ,  Andrea Thesing ,  Lars Hellkuhl

IPC: C07F7/18 ,  C08G18/71 ,  C08G18/32 ,  C08G18/34 ,  C08G18/38

CPC classification number: C07F7/1804 ,  C07F7/1892 ,  C08G18/32 ,  C08G18/34 ,  C08G18/3819 ,  C08G18/3876 ,  C08G18/718

Abstract: The present invention relates to a composition comprising (A) an isocyanate of formula (I) OCN-A-SiR1R2R3 (I), wherein A is straight-chain, branched, substituted and/or unsubstituted aliphatic hydrocarbyl of 1 to 12 carbon atoms or substituted or unsubstituted cycloaliphatic hydrocarbyl of 4 to 18 carbon atoms, wherein R1 is selected from the group comprising —O—Ralk, wherein R2 and R3 are each independently selected from the group of substituents comprising —Ralk and —O—Ralk, and wherein —Ralk is hydrocarbyl of 1 to 6 carbon atoms, and B) a Bronstedt or Lewis acid or a compound which releases a Bronstedt or Lewis acid at room temperature; and also to a process for producing a stabilized alkoxysilane-containing isocyanate comprising the step of adding a Lewis or Bronstedt acid or a compound which releases a Bronstedt or Lewis acid at room temperature to an alkoxysilane-containing isocyanate.

Abstract translation: 本发明涉及包含（A）式（I）的异氰酸酯OCN-A-SiR 1 R 2 R 3（I）的组合物，其中A是具有1至12个碳原子的直链，支链，取代和/或未取代的脂族烃基或 取代或未取代的具有4至18个碳原子的脂环族烃基，其中R 1选自-O-Ralk，其中R 2和R 3各自独立地选自包括-Ralk和-O-Ralk的取代基，并且其中 - Ralk是1至6个碳原子的烃基，B）Bronstedt或Lewis酸或在室温下释放布朗斯台特或路易斯酸的化合物; 还涉及一种制备含稳定的含烷氧基硅烷的异氰酸酯的方法，包括在室温下将路易斯或布朗斯特酸或将布朗斯台德或路易斯酸释放到含烷氧基硅烷的异氰酸酯的化合物的步骤。

公开(公告)号：US20150252219A1

公开(公告)日：2015-09-10

申请号：US14430332

申请日：2013-08-23

Applicant: Emmanouil Spyrou ,  Evelyn Albrecht ,  Annegret Lilienthal ,  Iris Brueckner ,  Wiebke Stache ,  Stephen Parkyn

Inventor： Emmanouil Spyrou ,  Evelyn Albrecht ,  Annegret Lilienthal ,  Iris Brueckner ,  Wiebke Stache ,  Stephen Parkyn

IPC: C09D175/12 ,  C08K5/20 ,  C09J175/12

CPC classification number: C09D175/12 ,  C08G18/0823 ,  C08G18/3206 ,  C08G18/348 ,  C08G18/4236 ,  C08G18/4263 ,  C08G18/6625 ,  C08G18/755 ,  C08K5/20 ,  C09D7/63 ,  C09D175/04 ,  C09D201/08 ,  C09J175/04 ,  C09J175/12 ,  C09J201/08 ,  C08L101/08

Abstract: The invention relates to an aqueous composition, comprisingA a water-soluble or water-dispersible binder, or a water-soluble or water-dispersible component containing carboxyl groups, and B at least one cyclic hydroxyalkylamide.

Abstract translation: 本发明涉及一种含水组合物，其包含水溶性或水分散性粘合剂，或含有羧基的水溶性或水分散性组分，和B至少一种环状羟基烷基酰胺。

公开(公告)号：US08846979B2

公开(公告)日：2014-09-30

申请号：US13704465

申请日：2011-06-07

Applicant: Emmanouil Spyrou ,  Lars Hellkuhl ,  Marina Grammenos ,  Andrea Henschke

Inventor： Emmanouil Spyrou ,  Lars Hellkuhl ,  Marina Grammenos ,  Andrea Henschke

IPC: C07C49/603 ,  A01N47/10 ,  C09D7/00 ,  A01N25/02

CPC classification number: C07C49/603 ,  A01N25/02 ,  C09D7/20 ,  A01N37/22 ,  A01N47/22

Abstract: The invention relates to the use of β-isophorone as solvent.

Abstract translation: 本发明涉及使用 - 双异佛尔酮作为溶剂。

公开(公告)号：US08524837B2

公开(公告)日：2013-09-03

申请号：US13045141

申请日：2011-03-10

Applicant: Werner Grenda ,  Emmanouil Spyrou ,  Thomas Weihrauch ,  Christoph Lammers ,  Holger Loesch ,  Klaus Behrendt

Inventor： Werner Grenda ,  Emmanouil Spyrou ,  Thomas Weihrauch ,  Christoph Lammers ,  Holger Loesch ,  Klaus Behrendt

IPC: C08C19/22

CPC classification number: C09D167/00 ,  C08G59/4246 ,  C08G59/46 ,  C08K5/20 ,  C08L63/00 ,  C09D5/032 ,  C09D133/00 ,  C09D133/08 ,  C09D163/00 ,  Y10T428/3179

Abstract: The invention relates to heat-curing powder-lacquer compositions exhibiting a matte surface after curing of the coating, as well as to a simple method for production of the same.

公开(公告)号：US20130041103A1

公开(公告)日：2013-02-14

申请号：US13583252

申请日：2011-03-10

Applicant: Werner Grenda ,  Emmanouil Spyrou ,  Thomas Weihrauch ,  Christoph Lammers ,  Holger Loesch ,  Klaus Behrendt

Inventor： Werner Grenda ,  Emmanouil Spyrou ,  Thomas Weihrauch ,  Christoph Lammers ,  Holger Loesch ,  Klaus Behrendt

IPC: C09D167/00

CPC classification number: C09D167/00 ,  C08G59/4246 ,  C08G59/46 ,  C08K5/20 ,  C08L63/00 ,  C09D5/032 ,  C09D133/00 ,  C09D133/08 ,  C09D163/00 ,  Y10T428/3179

Abstract: The invention relates to heat-curable powder coating compositions, which after the coating has cured result in a matt surface and to a simple method for producing same

Abstract translation: 本发明涉及热固化粉末涂料组合物，其在涂层固化后产生无光泽表面，并且涉及一种简单的制造方法

公开(公告)号：US08283040B2

公开(公告)日：2012-10-09

申请号：US12520873

申请日：2007-12-04

Applicant: Emmanouil Spyrou ,  Holger Loesch ,  Pedro Cavaleiro

Inventor： Emmanouil Spyrou ,  Holger Loesch ,  Pedro Cavaleiro

IPC: C08J3/28 ,  C09D5/08 ,  C09D7/12 ,  C09D175/06 ,  B32B27/00

CPC classification number: C09D133/062 ,  C08G18/672 ,  C08G2150/90 ,  C08K3/38 ,  C09D133/08 ,  C09D133/14 ,  Y10T428/31551 ,  Y10T428/31605 ,  C08G18/42

Abstract: The invention relates to silica-containing radiation-curable formulations which in the cured state offer a particular degree of corrosion control for metallic substrates.

Abstract translation: 本发明涉及含二氧化硅的可辐射固化制剂，其在固化状态下为金属基材提供特定程度的腐蚀控制。