公开(公告)号：US20110243838A1

公开(公告)日：2011-10-06

申请号：US12750923

申请日：2010-03-31

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C01B39/02 ,  C01B39/00

CPC分类号： C01B39/48

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US08022262B1

公开(公告)日：2011-09-20

申请号：US12820079

申请日：2010-06-21

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C07C6/12 ,  C07C5/22 ,  C07C2/08 ,  C10G25/00

CPC分类号： C10G50/00 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/70 ,  C10G29/205 ,  C10G49/02

摘要： A new family of crystalline aluminosilicate zeolitic compositions, UZM-35 compositions, has been synthesized. These zeolitic compositions are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These compositions comprise a MSE zeolite, a MFI zeolite and an ERI zeolite. The compositions are similar to MCM-68 but are characterized by unique x-ray diffraction patterns and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石组合物UZM-35组合物。 这些沸石组合物由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些组合物包含MSE沸石，MFI沸石和ERI沸石。 组合物类似于MCM-68，但其特征在于独特的x射线衍射图，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US07985886B1

公开(公告)日：2011-07-26

申请号：US12751449

申请日：2010-03-31

申请人： Deng-Yang Jan ,  Jaime G. Moscoso

发明人： Deng-Yang Jan ,  Jaime G. Moscoso

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out alkylation processes.

公开(公告)号：US07982084B1

公开(公告)日：2011-07-19

申请号：US12750939

申请日：2010-03-31

申请人： Jaime G. Moscoso ,  Deng-Yang Jan

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C07C4/12 ,  C07C6/12 ,  C07C5/27 ,  C07C2/58 ,  C07C2/08 ,  C10G47/00 ,  C10G11/00 ,  C10G25/00

CPC分类号： C10G47/16 ,  C07C2/12 ,  C07C2/58 ,  C07C6/126 ,  C07C2529/70 ,  C10G11/05 ,  C10G29/205 ,  C10G47/04 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/1096 ,  C10G2300/70 ,  C10G2400/02 ,  C07C9/16

摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.

摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。

公开(公告)号：US07973206B1

公开(公告)日：2011-07-05

申请号：US12639971

申请日：2009-12-16

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn ,  Jaime G. Moscoso

IPC分类号： C07C2/66

CPC分类号： B01J29/80 ,  B01J29/087 ,  B01J29/088 ,  B01J29/18 ,  B01J29/70 ,  B01J2229/42 ,  C07C2/66 ,  C07C2529/08 ,  C07C2529/80 ,  C07C15/107

摘要： A process is presented for the production of linear alkylbenzenes. The process includes contacting an aromatic compound with an olefin in the presence of a selective zeolite catalyst. The catalyst includes two zeolites combined to improve the linearity, and to produce detergent grade LAB. The two zeolites are selected to limit skeletal isomerization while producing a desired 2-phenyl content for the LAB.

摘要翻译： 介绍了生产线性烷基苯的方法。 该方法包括在选择性沸石催化剂存在下使芳族化合物与烯烃接触。 催化剂包括两种结合以提高线性的沸石，并生产洗涤剂级LAB。 选择两种沸石以限制骨架异构化，同时为LAB产生所需的2-苯基含量。

公开(公告)号：US20100075833A1

公开(公告)日：2010-03-25

申请号：US12627531

申请日：2009-11-30

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn

IPC分类号： B01J29/08 ,  B01J29/40

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C15/107

摘要： The alkylation of aromatic compound with acyclic mono-olefin is effected at low aromatic compound to mono-olefin ratios with reduced co-production of heavies. In the processes a small crystal, acidic FAU molecular sieve is used as a catalyst under alkylation conditions. This invention also relates to catalysts containing small crystal, acidic FAU molecular sieve and at least one other acidic catalytic component.

摘要翻译： 芳族化合物与无环单烯烃的烷基化在低芳族化合物与单烯烃比率下进行，同时减少重质量的共同产生。 在该方法中，在烷基化条件下使用小结晶酸性FAU分子筛作为催化剂。 本发明还涉及含有小结晶，酸性FAU分子筛和至少一种其它酸性催化组分的催化剂。

公开(公告)号：US07626064B1

公开(公告)日：2009-12-01

申请号：US12146831

申请日：2008-06-26

申请人： Edwin P. Boldingh ,  Michael G. Gatter ,  Susan C. Koster ,  David S. Lafyatis ,  Terrence E. Deak ,  Eric J. Baker ,  Robert W. Broach ,  Deng-Yang Jan ,  Jaime G. Moscoso

发明人： Edwin P. Boldingh ,  Michael G. Gatter ,  Susan C. Koster ,  David S. Lafyatis ,  Terrence E. Deak ,  Eric J. Baker ,  Robert W. Broach ,  Deng-Yang Jan ,  Jaime G. Moscoso

IPC分类号： C07C6/12

CPC分类号： B01J29/80 ,  B01J29/26 ,  B01J29/48 ,  B01J29/70 ,  B01J29/72 ,  B01J29/78 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C07C2529/70 ,  C07C2529/78 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

摘要： This invention embodies a catalyst and a process for transalkylation of C7, C9, and C10 aromatics to obtain a high yield of xylenes. The catalyst comprises a novel UZM-14 catalytic material comprising globular aggregates of crystallites having a MOR framework type with a mean crystallite length parallel to the direction of the 12-ring channels of about 60 nm or less and a mesopore volume of at least about 0.10 cc/gram. The UZM-14 catalyst is particularly active and stable in a transalkylation process.

摘要翻译： 本发明体现了C7，C9和C10芳族化合物的烷基转移催化剂和方法，以获得高产率的二甲苯。 该催化剂包括新型的UZM-14催化材料，其包含具有MOR骨架类型的晶体的球状聚集体，其平均微晶长度与12-环通道的方向平行约60nm或更小，中孔体积至少约0.10 cc /克。 UZM-14催化剂在烷基转移过程中特别活跃和稳定。

公开(公告)号：US20090099399A1

公开(公告)日：2009-04-16

申请号：US11871600

申请日：2007-10-12

申请人： Deng-Yang Jan ,  Mark G. Riley

发明人： Deng-Yang Jan ,  Mark G. Riley

IPC分类号： C07C2/58

CPC分类号： C07C2/66 ,  C07C2529/18 ,  C07C2529/70 ,  C07C15/107

摘要： A process is disclosed wherein a layered catalyst is used for the alkylation of benzene with a substantially linear olefin. The layered catalyst allows for shifting the operating conditions to increase the alkylation of benzene, while reducing the amount of isomerization of the alkyl group. This is important for increasing the quality of the alkylbenzene by increasing the linearity of the alkylbenzene.

摘要翻译： 公开了一种方法，其中层状催化剂用于用基本上线性的烯烃烷基化苯。 层状催化剂允许转变操作条件以增加苯的烷基化，同时减少烷基的异构化量。 这对于通过增加烷基苯的线性来提高烷基苯的质量是重要的。

公开(公告)号：US20080161621A1

公开(公告)日：2008-07-03

申请号：US11872783

申请日：2007-10-16

申请人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn

发明人： Mark G. Riley ,  Deng-Yang Jan ,  Stephen W. Sohn

IPC分类号： C07C2/66 ,  B01J29/04

CPC分类号： C07C2/66 ,  C07C2529/08 ,  C07C15/107

摘要： The alkylation of aromatic compound with acyclic mono-olefin is effected at low aromatic compound to mono-olefin ratios with reduced co-production of heavies. In the processes a small crystal, acidic FAU molecular sieve is used as a catalyst under alkylation conditions. This invention also relates to catalysts containing small crystal, acidic FAU molecular sieve and at least one other acidic catalytic component.

摘要翻译： 芳族化合物与无环单烯烃的烷基化在低芳族化合物与单烯烃比率下进行，同时减少重质量的共同产生。 在该方法中，在烷基化条件下使用小结晶酸性FAU分子筛作为催化剂。 本发明还涉及含有小结晶，酸性FAU分子筛和至少一种其它酸性催化组分的催化剂。

公开(公告)号：US20060159615A1

公开(公告)日：2006-07-20

申请号：US11340914

申请日：2006-01-27

申请人： Deng-Yang Jan ,  Jaime Moscoso ,  Susan Koster ,  Lisa Knight ,  Gregory Lewis ,  Mark Miller ,  R. Patton ,  Stephen Wilson

发明人： Deng-Yang Jan ,  Jaime Moscoso ,  Susan Koster ,  Lisa Knight ,  Gregory Lewis ,  Mark Miller ,  R. Patton ,  Stephen Wilson

IPC分类号： C01B39/00

CPC分类号： C01B39/026 ,  C01B39/48 ,  C01P2002/72 ,  C10G11/05 ,  C10G35/095 ,  C10G45/12 ,  C10G47/16

摘要： A family of crystalline aluminosilicate zeolites designated UZM-8HS and derived from UZM-8 have been synthesized. The aluminum content of the UZM-8HS is lower than that of the starting UZM-8 thus changing its ion exchange capacity and acidity. These UZM-8HS are represented by the empirical formula: M1an+Al(1−x)ExSiy′Oz″and are prepared by treatments such as acid extraction and AFS treatments.

摘要翻译： 已经合成了一系列称为UZM-8HS并衍生自UZM-8的结晶硅铝酸盐沸石。 UZM-8HS的铝含量低于起始UZM-8的铝含量，从而改变其离子交换能力和酸度。 这些UZM-8HS由经验公式表示：<？in-line-formula description =“In-line Formulas”end =“lead”？> M 1 n + >（1-x） x 公式描述=“在线公式”end =“tail”？>并且通过诸如酸提取和AFS处理的处理来制备。