摘要:
The invention relates to novel compounds containing uretdione groups, to a process for preparing them by dimerizing aliphatic and/or cycloaliphatic isocyanates containing exclusively secondary and/or tertiary isocyanate groups and also to the use of uretdione polyisocyanates obtainable by this process from diisocyanates containing exclusively secondary and/or tertiary isocyanate groups as a starting component for polyurethane polymers, in particular as an isocyanate component in the preparation of uretdione powder coating crosslinkers.
摘要:
Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers, wherein blocked polyisocyanates are prepared by reacting polyisocyanates with secondary amines corresponding to the formula wherein R1—R4 can be identical or different and denote hydrogen, C1–C6-alkyl or cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, y denotes a number from 2 to 8, and B represents wherein R6–R8 can be identical or different and independently of one another denote C1–6-alkyl and/or C3–C6-cycloalkyl, R9 denotes hydrogen or C1–6-alkyl or C3–C6-cycloalkyl.
摘要:
The invention relates to a process for preparing polyisocyanates having a high uretdione group content by phosphine-catalysed isocyanate oligomerization in the presence of organic carbonates and/or nitriles.
摘要:
The invention relates to the use of cycloalkylphosphines as catalysts for isocyanate dimerization and to a process for preparing polyisocyanates containing uretdione groups.
摘要:
Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.
摘要:
The invention relates to particular mixtures of polyisocyanates which are blocked with 3,5-dimethylpyrazole, and to the use thereof as crosslinking component in single-component stoving lacquers, especially automotive clear lacquers.
摘要:
The invention relates to a method of preparing an aliphatic polyisocyanate by conversion of an aliphatic diisocyanate to a polyisocyanates in the presence of a catalyst, wherein the catalyst contains a saline compound having 5 to 97.1 wt. % of a 1,2,3- and/or a 1,2,4-triazolate (calculated as C2N3, molecular weight 66) in the anion, the isocyanates thus prepared and the polyurethane paints and coatings containing them.
摘要:
The present invention relates to water dispersible polyisocyanate mixtures prepared from aliphatic, cycloaliphatic, araliphatic and/or aromatic diisocyanates and having a) an average isocyanate functionality of at least 2.0, b) a content of 5.0 to 25.0 wt. %, based on resin solids, of isocyanate groups (calculated as NCO; molecular weight=42) and c) a content of 2 to 50 wt. %, based on resin solids, of ethylene oxide units calculated as C2H2O; molecular weight 44) incorporated within polyether chains containing an average of 5 to 35 ethylene oxide units, wherein at least 60 mole % of the polyether chains are connected via allophanate groups to two polyisocyanate molecules which are each prepared from at least two diisocyanate molecules. The present invention also relates to a process for the preparation of these water dispersible polyisocyanate.
摘要翻译:本发明涉及由脂族,脂环族,芳脂族和/或芳族二异氰酸酯制备的水分散性多异氰酸酯混合物,并且具有至少2.0的平均异氰酸酯官能度,b)5.0至25.0重量%的含量。 %,基于树脂固体的异氰酸酯基团(以NCO计算;分子量= 42),和c)2〜50重量%的含量。 %,基于树脂固体,以C 2 H 2 O计算的环氧乙烷单元; 分子量44),其包含平均5至35个环氧乙烷单元的聚醚链,其中至少60摩尔%的聚醚链通过脲基甲酸酯基团连接到两个由至少两个二异氰酸酯分子制备的多异氰酸酯分子。 本发明还涉及制备这些水分散性多异氰酸酯的方法。
摘要:
A process for the purification of organic isocyanates or isocyanate mixtures in which the amount of chlorine compound(s) present is reduced by mixing the isocyanate(s) or isocyanate mixtures with a gel-type or macroporous, anion-exchanging organic material having tertiary and/or quaternary amino groups. The process renders possible a purification of the isocyanates from chlorine-containing compounds which is milder than in conventional processes and is therefore particularly suitable for temperature-sensitive isocyanates.
摘要:
A process for the production of polyisocyanates containing isocyanurate groups by the catalytic trimerization of a mixture of low molecular weight isocyanate components having aliphatically and aromatically bound isocyanate groups in the presence of aminosilyl compounds, the resulting polyisocyanates and their use in coating compositions.