公开(公告)号：US09290586B2

公开(公告)日：2016-03-22

申请号：US13997967

申请日：2011-12-20

申请人： Anna Sommazzi ,  Francesco Masi ,  Guido Pampaloni ,  Filippo Renili ,  Fabio Marchetti ,  Anna Maria Raspolli Galletti

发明人： Anna Sommazzi ,  Francesco Masi ,  Guido Pampaloni ,  Filippo Renili ,  Fabio Marchetti ,  Anna Maria Raspolli Galletti

IPC分类号： C08F10/02 ,  C07F17/00 ,  C08F4/659 ,  C08F110/02 ,  C08F210/16

CPC分类号： C08F10/02 ,  C07F17/00 ,  C08F4/52 ,  C08F4/65912 ,  C08F4/76 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6557 ,  C08F4/65904 ,  C08F4/6552 ,  C08F2500/12 ,  C08F210/14

摘要： A solid catalyst component for the (co)polymerization of α-olefins having general formula (I): ZrnMAlxClMgp (I) wherein: M represents titanium (Ti), vanadium (V), or mixtures thereof; n is a number ranging from 0.01 to 2; x is a number ranging from 0.1 to 4; y is a number ranging from 5 to 53; p is a number ranging from 0 to 15; obtained by means of a process comprising putting at least one zirconium arene in contact with at least one metal compound and, optionally, with at least one compound of magnesium. Said solid catalyst component can be advantageously used as a solid component in a catalyst for the (co)polymerization of α-olefins. Said catalyst can be advantageously used in a process for the (co)polymerization of α-olefins.

摘要翻译： 用于（a）具有通式（I）的α-烯烃的（共）聚合的固体催化剂组分：ZrnMAlxClMgp（I）其中：M表示钛（Ti），钒（V）或其混合物; n为0.01〜2的数; x是从0.1到4的数字; y是从5到53的数字; p是从0到15的数字; 通过包括将至少一种锆芳烃与至少一种金属化合物和任选地与至少一种镁化合物接触的方法获得。 所述固体催化剂组分可有利地用作α-烯烃的（共）聚合催化剂中的固体组分。 所述催化剂可以有利地用于α-烯烃的（共）聚合方法中。

公开(公告)号：US09193643B2

公开(公告)日：2015-11-24

申请号：US13518550

申请日：2010-12-23

申请人： Maria Angela Mantegazza ,  Fabrizio Bordes ,  Roberto Buzzoni

发明人： Maria Angela Mantegazza ,  Fabrizio Bordes ,  Roberto Buzzoni

IPC分类号： C07C2/66 ,  C07C6/12 ,  C07C2/86

CPC分类号： C07C2/864 ,  Y02E50/17 ,  Y02P20/52 ,  C07C15/073

摘要： The invention relates to a process for the production of ethylbenzene which comprises: a reaction step in which benzene is reacted with ethanol, or a mixture of ethanol and ethylene, at a pressure higher than atmospheric pressure, preferably in gaseous phase or in mixed gas-liquid phase, in the presence of a catalytic system containing a zeolite belonging to the BEA family, and a separation step of the product obtained. According to a preferred aspect, ethanol deriving from biomasses is used, in particular ethanol obtained from the fermentation of sugars deriving from biomasses.

摘要翻译： 本发明涉及一种生产乙苯的方法，该方法包括：在高于大气压，优选气相或混合气体反应器中，苯与乙醇或乙醇和乙烯的混合物反应的反应步骤， 在含有属于BEA族的沸石的催化体系的存在下，所得的产物的分离步骤。 根据优选的方面，使用衍生自生物质的乙醇，特别是从衍生自生物质的糖的发酵得到的乙醇。

公开(公告)号：US20150259521A1

公开(公告)日：2015-09-17

申请号：US14432907

申请日：2013-10-17

申请人： VERSALIS S.P.A

发明人： Antonio Ponticiello ,  Attilio Arienti ,  Francesco Pasquali

IPC分类号： C08L25/08 ,  C08J9/20

CPC分类号： C08L25/08 ,  C08J9/0019 ,  C08J9/0061 ,  C08J9/0066 ,  C08J9/0095 ,  C08J9/141 ,  C08J9/16 ,  C08J9/20 ,  C08J9/224 ,  C08J9/232 ,  C08J2201/022 ,  C08J2201/03 ,  C08J2201/036 ,  C08J2203/14 ,  C08J2203/182 ,  C08J2325/04 ,  C08J2325/08 ,  C08J2425/04 ,  C08J2425/14 ,  C08J2433/14 ,  C08J2463/04 ,  C08K3/04 ,  C08K5/0066 ,  C08L25/06 ,  C08L25/14 ,  C08L2201/02

摘要： The present invention relates to a concentrated polymeric composition which comprises: a) vinyl aromatic polymers and/or copolymers in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition, b) at least one compound containing epoxy functional groups in an amount ranging from 0.01% to 5% by weight, calculated with respect to the overall composition, with respect to the overall composition, c) at least one infrared absorbing agent, in an amount ranging from 10% to 90% by weight, calculated with respect to the overall composition, with respect to the overall composition.

摘要翻译： 本发明涉及一种浓缩聚合物组合物，其包含：a）相对于总体组合物，相对于总组合物计算的量为10重量％至90重量％的乙烯基芳族聚合物和/或共聚物，b ）至少一种含有环氧官能团的化合物，所述化合物的含量相对于整个组合物为0.01-5重量％，相对于整个组合物计算，c）至少一种红外吸收剂，其量为 相对于整体组合物计算，相对于总体组成计算为10重量％至90重量％。

公开(公告)号：US09090544B2

公开(公告)日：2015-07-28

申请号：US14366416

申请日：2012-12-24

申请人： versalis S.p.A.

发明人： Alessandro Del Seppia ,  Fabio Assandri ,  Elena Ghirardo ,  Carmelo Vella

IPC分类号： C07C41/09 ,  C07C5/32 ,  C07C41/06 ,  C07C5/333 ,  C07C7/08

CPC分类号： C07C41/09 ,  C07C5/322 ,  C07C5/3332 ,  C07C5/3335 ,  C07C5/3337 ,  C07C7/08 ,  C07C41/06 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2523/63 ,  C07C11/167 ,  C07C43/046

摘要： The present invention relates to a process for the production of 1,3-butadiene which comprises the following phases: a) extracting, by means of extractive distillation, in an extraction section, an end-product containing 1,3-butadiene and a raffinate product, starting from mixtures of saturated and unsaturated compounds having from 2 to 10 carbon atoms in the chain; b) sending the raffinate product to a dehydrogenation section; c) dehydrogenating the raffinate product in the dehydrogenation section in the presence of a dehydrogenation catalyst and an inert product so as to form a reaction effluent containing 1,3-butadiene; d) recirculating the reaction effluent containing 1,3-butadiene directly to the extraction section after separating the incondensable compounds.

摘要翻译： 本发明涉及一种生产1,3-丁二烯的方法，该方法包括以下阶段：a）通过萃取蒸馏提取含有1,3-丁二烯和萃余液的最终产物 产物，从链中具有2至10个碳原子的饱和和不饱和化合物的混合物开始; b）将萃余液产品送至脱氢段; c）在脱氢段中，在脱氢催化剂和惰性产物的存在下使提余物产物脱氢，以形成含有1,3-丁二烯的反应流出物; d）在分离不可冷凝化合物之后，将含有1,3-丁二烯的反应流出物直接再循环到萃取部分。

公开(公告)号：US20140155543A1

公开(公告)日：2014-06-05

申请号：US14127339

申请日：2012-06-21

申请人： Luca Soddu ,  Gabriele Veneri

发明人： Luca Soddu ,  Gabriele Veneri

IPC分类号： C08C19/42

CPC分类号： C08C19/42 ,  C08C19/44 ,  C08F236/10 ,  C08F4/48

摘要： A process for the preparation of a 1,3-butadiene and styrene copolymer comprising the following steps: a) anionically polymerizing a blend comprising from 5% by weight to 40% by weight of styrene and from 60% by weight to 95% by weight of 1,3-butadiene, with respect to the overall weight of the mixture, in the presence of at least one hydrocarbon solvent, of at least one lithium-based catalyst having the general formula LiR1 wherein R1 represents a linear or branched C3-C10 alkyl group, and of least one polar modifier; b) optionally, reacting the copolymer obtained in step (a) with at least one chain-end monomer selected from 1,3-butadiene, styrene and α-methylstyrene; c) reacting from 10% by weight to 70% by weight, preferably from 20% by weight to 50% by weight, of the lithium-terminated polymeric chains present in the copolymer obtained in step (a) or in step (b), with at least one coupling agent selected from liquid polyepoxides having at least three reactive sites capable of reacting with the carbon-lithium chain-ends; d) optionally, reacting the copolymer obtained in step (c) with at least one chain-end monomer selected from 1,3-butadiene, styrene and a-methylstyrene; e) reacting the linear polymeric chains remaining in the copolymer obtained in step (c) or in step (d), with at least one tin compound having the general formula XSn(R2)3 wherein X represents a halogen atom such as, for example, chlorine and R2 represents a linear or branched C1-C10 alkyl group.

摘要翻译： 一种制备1,3-丁二烯和苯乙烯共聚物的方法，包括以下步骤：a）阴离子聚合共混物，其包含5重量％至40重量％的苯乙烯和60重量％至95重量％ 的1,3-丁二烯相对于混合物的总重量，在至少一种烃溶剂的存在下，至少一种具有通式LiR1的锂基催化剂，其中R 1表示直链或支链C 3 -C 10 烷基和至少一种极性改性剂; b）任选地，使步骤（a）中获得的共聚物与至少一种选自1,3-丁二烯，苯乙烯和α-甲基苯乙烯的链端单体反应; c）使步骤（a）或步骤（b）中获得的共聚物中存在的锂封端聚合物链的重量比为10重量％至70重量％，优选20重量％至50重量％ 其中至少一种偶联剂选自具有至少三个能够与碳 - 锂链端反应的活性位点的液态聚环氧化物; d）任选地，使步骤（c）中获得的共聚物与至少一种选自1,3-丁二烯，苯乙烯和α-甲基苯乙烯的链端单体反应; e）将步骤（c）或步骤（d）中获得的共聚物中剩余的线性聚合物链与至少一种具有通式XSn（R2）3的锡化合物反应，其中X表示卤素原子，例如 ，氯和R 2表示直链或支链的C 1 -C 10烷基。

公开(公告)号：US20140142348A1

公开(公告)日：2014-05-22

申请号：US14127421

申请日：2012-06-21

申请人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

发明人： Paolo Calaresu ,  Alessandro Del Seppia ,  Elena Bencini ,  Giovanni Antonio Fois ,  Alessandro Casalini

IPC分类号： C07C2/66 ,  C07C37/08

CPC分类号： C07C2/66 ,  C07C29/143 ,  C07C37/08 ,  C07C45/53 ,  C07C2529/70 ,  Y02P20/52 ,  Y02P20/582 ,  C07C15/085 ,  C07C15/107 ,  C07C15/073 ,  C07C39/04 ,  C07C49/08 ,  C07C31/10

摘要： Process for the alkylation of aromatic hydrocarbons by means of olefins containing from 2 to 8 carbon atoms, which comprises feeding the hydrocarbon, olefin, and possibly water, to the head of a fixed-bed reactor, operating with a “trickle flow” regime, containing at least one layer of a catalyst comprising a medium- or large-pore zeolite.

摘要翻译： 通过含有2-8个碳原子的烯烃烷基化芳族烃的方法，该方法包括将烃，烯烃和可能的水进料到以“滴流”方式运行的固定床反应器的头部， 含有至少一层包含中孔或大孔沸石的催化剂。

公开(公告)号：US08729315B2

公开(公告)日：2014-05-20

申请号：US13508619

申请日：2010-10-29

申请人： Mauro Burattini ,  Roberto Bagatin

发明人： Mauro Burattini ,  Roberto Bagatin

IPC分类号： C07C37/08

CPC分类号： C07C407/00 ,  C07C37/08 ,  C07C45/53 ,  C07C39/04 ,  C07C49/08 ,  C07C409/10

摘要： Process for the production in continuous or semi-continuous of phenol/acetone from cumene, via cumene hydroperoxide (CHP), which comprises: a. producing CHP in an air-lift reactor in which at least the upper and/or lower part of the downcomer has a flaring; b. cleaving the cumene hydroperoxide by means of acid treatment in a loop reactor comprising two heat exchangers connected in series and wherein the feedings of CHP and fresh acetone are in pairs and each pair is positioned up-stream of each exchanger.

摘要翻译： 由枯烯连续或半连续生产苯酚/丙酮的方法，通过氢过氧化枯烯（CHP），其包括：a。 在其中至少下降管的上部和/或下部具有扩口的空气提升反应器中产生CHP; b。 在包含串联连接的两个热交换器的环管反应器中通过酸处理裂解氢过氧化枯烯，其中CHP和新鲜丙酮的进料成对，并且每对在每个交换器的上游设置。

公开(公告)号：US20130333558A1

公开(公告)日：2013-12-19

申请号：US13976345

申请日：2011-12-28

申请人： Riccardo Felisari ,  Alessandro Casalini

发明人： Riccardo Felisari ,  Alessandro Casalini

IPC分类号： B01D19/00

CPC分类号： B01D19/0042 ,  B01D19/0057

摘要： The device of the present invention allows the pressure of a certain fluid to be reduced without reductions in the cross sectional area or organs in movement. The pressure reduction is obtained by passing the fluid to be depressurized, in sequence, through a plurality of pairs of steps. In the first step of each pair, part of the pressure energy of the fluid is converted to gravitational potential; in the second step the gravitational potential is converted into thermal energy, so as to prevent the reconversion of the same into pressure energy.

摘要翻译： 本发明的装置允许在不减少运动中的横截面积或器官的同时降低某一流体的压力。 通过使多个步骤顺序地使待减压的流体顺序地进行，来获得压力降低。 在每对的第一步中，流体的一部分压力能量转化为重力势; 在第二步中，重力电位转化为热能，以防止将其重新转化为压力能量。

公开(公告)号：US20130172624A1

公开(公告)日：2013-07-04

申请号：US13805478

申请日：2011-06-20

申请人： Francesco Recupero ,  Carlo Punta ,  Lucio Melone ,  Simona Prosperini ,  Nadia Pastori

发明人： Francesco Recupero ,  Carlo Punta ,  Lucio Melone ,  Simona Prosperini ,  Nadia Pastori

IPC分类号： C07C45/27

CPC分类号： C07C45/27 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C49/08 ,  C07C409/10 ,  C07C39/04

摘要： Process for the oxidation of alkylaromatic hydrocarbons to hydroperoxide catalyzed by N-hydroxy derivatives in the presence of a solvent which includes recovering the catalyst from the oxidation mixture by the possible removal of the solvent by distillation and/or cooling of the oxidation mixture, with the consequent precipitation and filtration of the N-hydroxy-derivative catalyst, and adsorption with non-basic adsorbing solids for the substantially complete recovery of the catalyst.

摘要翻译： 在溶剂存在下，通过N-羟基衍生物催化将烷基芳烃氧化为氢过氧化物的方法，其包括通过蒸馏和/或冷却氧化混合物可能除去溶剂从氧化混合物中回收催化剂， 随后沉淀和过滤N-羟基衍生物催化剂，并用非碱性吸附固体进行吸附以实质上完全回收催化剂。

公开(公告)号：US12030222B2

公开(公告)日：2024-07-09

申请号：US16958207

申请日：2018-12-21

申请人： VERSALIS S.P.A.

发明人： Riccardo Felisari ,  Sara Gavioli ,  Riccardo Inglese

IPC分类号： B29B9/06 ,  B29B9/12 ,  B29C48/00 ,  B29C48/04 ,  B29C48/08 ,  B29C48/25 ,  B29C48/92

CPC分类号： B29B9/065 ,  B29B9/12 ,  B29C48/0022 ,  B29C48/04 ,  B29C48/08 ,  B29C48/269 ,  B29C48/92

摘要： Circuit and to a process for managing transients and process and product anomalies in a plant for production of granulated expandable polymers EPS or extruded polymers XPS, said circuit being placed e.g. in a granulation plant along which are positioned:



a mixing device suitable for mixing additives and expanding agent within a stream of molten polymer;
a granulator or an extrusion device positioned downstream of said mixing device;
a deviation valve suitable for molten polymers placed along the line connecting said mixing device to said granulator or to said extrusion device upstream of said granulator or extruder, said deviation valve being provided with at least one inlet (A), a Stand-by position (A→C) and a Run position (A→B),

said circuit further comprising a heating device downstream of said valve, a separation device downstream of said heating device suitable for physically separating the blowing agent from the polymer and any additives present therein, and a cooling device positioned between said separation device and said mixing device.