公开(公告)号：US06617152B2

公开(公告)日：2003-09-09

申请号：US09947035

申请日：2001-09-04

申请人： Marie D. Bryhan ,  Paul E. Gagnon ,  Oliva V. LaChance ,  Zhong-he Shen ,  Hongming Wang

发明人： Marie D. Bryhan ,  Paul E. Gagnon ,  Oliva V. LaChance ,  Zhong-he Shen ,  Hongming Wang

IPC分类号： C12M300

CPC分类号： B29C59/14 ,  B05D3/144 ,  B05D7/22 ,  B29C59/142

摘要： A method, apparatus and product for producing an advantaged cell growth surface. According to the present invention, a stream of plasma is comprised of activated gaseous species generated by a microwave source. This stream is directed at the surface of a polymer substrate in a controlled fashion such that the surface is imparted with attributes for cell adhesion far superior to that of untreated polymer or polymer treated by other known methods.

摘要翻译： 用于生产有利的细胞生长表面的方法，装置和产品。 根据本发明，等离子体流由微波源产生的活化气态物质组成。 该流以受控的方式指向聚合物基材的表面，使得该表面具有远优于未处理的聚合物或通过其它已知方法处理的聚合物的细胞粘附的特性。

公开(公告)号：US20030161968A1

公开(公告)日：2003-08-28

申请号：US10083366

申请日：2002-02-27

申请人： Industrial Technology Research Institute

发明人： Tsung-Hsiung Wang ,  Jing-Pin Pan

IPC分类号： H05H001/24

CPC分类号： B05D3/20 ,  B05D3/14 ,  B05D3/144 ,  B05D5/12 ,  B05D2201/00 ,  C08G73/0266 ,  H01B1/128

摘要： The present invention is to provide a method of enhancement of electrical conductivity for conductive polymer by use of field effect control, wherein on the substrate, whose surface was treated with a field, was coated by a containing monomer or oligomer solution of conductive polymer, through a field mechanism a monomer or oligomer of conductive polymer can demonstrate the sequential order molecular structure layer on the substrate, on this molecular structure layer was coated by an available amount of oxidant to proceed the polymerization, it was subjected to a field during polymerization to form 3-dimensional order stacking structure in order to increase the functional characteristic and electrical conductivity for conductive polymer.

摘要翻译： 本发明提供一种通过场效应控制来提高导电性聚合物的导电性的方法，其中在表面用场处理的基板上，用含有导电聚合物的单体或低聚物溶液涂覆，通过 导电聚合物的单体或低聚物的场机理可以证明衬底上的顺序分子结构层，在该分子结构层上涂覆可用量的氧化剂以进行聚合，在聚合过程中进行场 为了增加导电聚合物的功能特性和导电性，三维订购堆叠结构。

公开(公告)号：US06594134B2

公开(公告)日：2003-07-15

申请号：US09792093

申请日：2001-02-21

申请人： Angelo Yializis

发明人： Angelo Yializis

IPC分类号： H01G4008

CPC分类号： B05D1/60 ,  B05D3/144 ,  B05D3/147 ,  B32B27/00 ,  C23C14/20 ,  H01G4/20 ,  Y10T428/12569 ,  Y10T428/12576 ,  Y10T428/1462 ,  Y10T428/31515 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31855 ,  Y10T428/31935

摘要： A polymer film capacitor is provided, utilizing a metallized film formed by a first vacuum-formed plasma treated surface, a vacuum-deposited, first radiation polymerized acrylate monomer film having first and second surfaces, the first surface being disposed on the first plasma-treated surface of the polymer substrate, and a metal layer disposed on the second surface of the first polymerized film. The metallized film is wound into a capacitor.

摘要翻译： 提供一种聚合物膜电容器，其利用由第一真空成形等离子体处理表面形成的金属化膜，具有第一和第二表面的真空沉积的第一辐射聚合丙烯酸酯单体膜，第一表面设置在第一等离子体处理 聚合物基材的表面和设置在第一聚合膜的第二表面上的金属层。 将金属化膜卷绕成电容器。

公开(公告)号：US20030068459A1

公开(公告)日：2003-04-10

申请号：US09792196

申请日：2001-02-21

发明人： Angelo Yializis

IPC分类号： B32B033/00

CPC分类号： B05D1/60 ,  B05D3/144 ,  B05D3/147 ,  B32B27/00 ,  C23C14/20 ,  H01G4/20 ,  Y10T428/12569 ,  Y10T428/12576 ,  Y10T428/1462 ,  Y10T428/31515 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31855 ,  Y10T428/31935

摘要： A hybrid film, comprising a first polymer film having a plasma-treated surface and a second polymer film having first and second surfaces, with the first surface of the second polymer film being disposed along the first plasma-treated surface of the first polymer film, has superior thermal and mechanical properties that improve performance in a number of applications, including food packaging, thin film metallized and foil capacitors, metal evaporated magnetic tapes, flexible electrical cables, and decorative and optically variable films. One or more metal layers may be deposited on either the plasma-treated surface of the substrate and/or the radiation-cured acrylate polymer. A ceramic layer may be deposited on the radiation-cured acrylate polymer to provide an oxygen and moisture barrier film. The hybrid film is produced using a high speed, vacuum polymer deposition process that is capable of forming thin, uniform, high temperature, cross-linked acrylate polymers on specific thermoplastic or thermoset films. Radiation curing is employed to cross-link the acrylate monomer. The hybrid film can be produced in-line with the metallization or ceramic coating process, in the same vacuum chamber and with minimal additional cost.

摘要翻译： 一种混合膜，包括具有等离子体处理表面的第一聚合物膜和具有第一和第二表面的第二聚合物膜，第二聚合物膜的第一表面沿着第一聚合物膜的第一等离子体处理表面设置， 具有优异的热和机械性能，可在许多应用中提高性能，包括食品包装，薄膜金属化和箔电容器，金属蒸发磁带，柔性电缆以及装饰和光学可变膜。 一个或多个金属层可以沉积在基板的等离子体处理的表面和/或辐射固化的丙烯酸酯聚合物上。 可以将陶瓷层沉积在辐射固化的丙烯酸酯聚合物上以提供氧气和湿气阻挡膜。 使用能够在特定热塑性或热固性膜上形成薄的，均匀的，高温的交联的丙烯酸酯聚合物的高速真空聚合物沉积工艺来制备混合膜。 辐射固化用于交联丙烯酸酯单体。 可以在相同的真空室中以与金属化或陶瓷涂覆方法一致的方式生产混合膜并以最小的额外成本。

公开(公告)号：US20020156142A1

公开(公告)日：2002-10-24

申请号：US09783926

申请日：2001-02-13

发明人： Michael G. Mikhael ,  Angelo Yializis

IPC分类号： C08J003/28 ,  C08G002/00

CPC分类号： C23C14/12 ,  B05D3/068 ,  B05D3/144 ,  B05D7/04

摘要： A thermally-stable cationic photoinitiator capable of flash vaporization under vacuum and temperature conditions of an available flash-evaporation chamber is selected. The photoinitiator is mixed with a cation-polymerizable monomer and/or oligomer of interest and the mixture is flash evaporated and condensed in conventional manner as a film on a cold substrate. The resulting vacuum-deposited, homogeneous layer is cured with a high-energy radiation source that causes the cationic photoinitiator to liberate acidic species that catalyze the crosslinking of the monomer/oligomer compounds in its deposited film form. As a result of the homogeneous, pinhole-free nature of the vacuum deposition process, the thin-film polymer product does not suffer from the disadvantages attendant to prior-art atmospheric processes for cationically-cured polymers. In addition, because of the versatility afforded by vacuum deposition, hybrid films of such polymers with inorganic materials are also easily manufactured in-line during the same process.

摘要翻译： 选择能够在可用的闪蒸室的真空和温度条件下闪蒸的热稳定的阳离子光引发剂。 将光引发剂与感兴趣的阳离子可聚合单体和/或低聚物混合，并将混合物以常规方式闪蒸并冷凝，在薄膜上冷却。 所得到的真空沉积的均匀层用高能量辐射源固化，其使得阳离子光引发剂释放催化以其沉积膜形式的单体/低聚物化合物的交联的酸性物质。 由于真空沉积工艺的均匀的无针孔特性，薄膜聚合物产品不会遭受与现有技术的阳离子固化聚合物的常规方法相关的缺点。 另外，由于通过真空沉积提供的通用性，这种与无机材料的聚合物的混合膜也可以在同一工艺中在线容易地制造。

公开(公告)号：US06468595B1

公开(公告)日：2002-10-22

申请号：US09783926

申请日：2001-02-13

申请人： Michael G. Mikhael ,  Angelo Yializis

发明人： Michael G. Mikhael ,  Angelo Yializis

IPC分类号： C23C1600

CPC分类号： C23C14/12 ,  B05D3/068 ,  B05D3/144 ,  B05D7/04

摘要： A thermally-stable cationic photoinitiator capable of flash vaporization under vacuum and temperature conditions of an available flash-evaporation chamber is selected. The photoinitiator is mixed with a cation-polymerizable monomer and/or oligomer of interest and the mixture is flash evaporated and condensed in conventional manner as a film on a cold substrate. The resulting vacuum-deposited, homogeneous layer is cured with a high-energy radiation source that causes the cationic photoinitiator to liberate acidic species that catalyze the crosslinking of the monomer/oligomer compounds in its deposited film form. As a result of the homogeneous, pinhole-free nature of the vacuum deposition process, the thin-film polymer product does not suffer from the disadvantages attendant to prior-art atmospheric processes for cationically-cured polymers. In addition, because of the versatility afforded by vacuum deposition, hybrid films of such polymers with inorganic materials are also easily manufactured in-line during the same process.

公开(公告)号：US6146462A

公开(公告)日：2000-11-14

申请号：US307078

申请日：1999-05-07

申请人： Angelo Yializis ,  Richard E. Ellwanger ,  Michael G. Mikhael ,  Wolfgang Decker ,  C. Barry Johnson ,  Gale Shipley ,  Timothy D. O'Brien

发明人： Angelo Yializis ,  Richard E. Ellwanger ,  Michael G. Mikhael ,  Wolfgang Decker ,  C. Barry Johnson ,  Gale Shipley ,  Timothy D. O'Brien

IPC分类号： B05D3/14 ,  C23C14/00 ,  D06M10/02 ,  D06M14/18 ,  D06M14/32 ,  H01J37/32 ,  C23C16/00

CPC分类号： H01J37/3266 ,  B05D3/144 ,  D06M10/025 ,  D06M14/18 ,  D06M14/32 ,  H01J37/32431 ,  H01J37/32596

摘要： Methods and apparatus for plasma modifying a substrate are disclosed along with associated techniques for applying coatings to the substrate. Particular utility has been found using a hollow cathode to generate the plasma along with magnetic focusing means to focus the plasma at the surface of a substrate.

摘要翻译： 公开了用于等离子体改性衬底的方法和装置以及用于将涂层施加到衬底的相关技术。 已经发现使用空心阴极产生等离子体以及磁聚焦装置以将等离子体聚焦在基底表面的特别实用性。

公开(公告)号：US6075086A

公开(公告)日：2000-06-13

申请号：US81199

申请日：1993-06-25

申请人： Katsuyuki Nitta ,  Keigo Suehiro ,  Yoichi Kawai ,  Katsumi Sekiguchi ,  Takeaki Inokuma ,  Yoshiyasu Kamiya

发明人： Katsuyuki Nitta ,  Keigo Suehiro ,  Yoichi Kawai ,  Katsumi Sekiguchi ,  Takeaki Inokuma ,  Yoshiyasu Kamiya

IPC分类号： B05D7/02 ,  B29C59/14 ,  C08J7/04 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L9/00

CPC分类号： B05D7/02 ,  B29C59/14 ,  C08J7/045 ,  C08L23/10 ,  C08L23/12 ,  C08L53/00 ,  B05D3/144 ,  B05D7/54 ,  B29K2023/12 ,  C08J2323/02 ,  C08L2205/02 ,  C08L23/16

摘要： Herein provided are a polypropylene resin composition which comprises (A) a polypropylene, (B) an ethylene-propylene-diene terpolymeric rubber having a Mooney viscosity, ML.sub.1+4 (100.degree. C.), ranging from 5 to 50 and an iodine value of not less than 15, the content of the component (B) ranging from 10 to 50% by weight on the basis of the total weight of the components (A) and (B), and optionally (C) an inorganic filler in an amount ranging from 0 to 40 parts by weight per 100 parts by weight of the sum of the components (A) and (B); a coating method which comprises the steps of applying a primer coating to a molded product obtained by molding the foregoing polypropylene resin composition or irradiating the molded product with plasma without degreasing and washing the product with a halogen atom-containing organic solvent and then applying a top coat to the product; and a coating method which comprises the steps of degreasing and washing a molded product obtained by molding the foregoing polypropylene resin composition and then applying a top coat to the product without applying a primer coating to the molded product or irradiating the molded product with plasma. The coated film obtained according to the foregoing methods has good bond strength to the molded product.

摘要翻译： 本发明提供一种聚丙烯树脂组合物，其包含（A）聚丙烯，（B）门尼粘度，ML1 + 4（100℃）为5〜50的乙烯 - 丙烯 - 二烯三元共聚橡胶， （A）和（B）的总重量的10〜50重量％的组分（B）的含量，以及（C）中的无机填料， 每100重量份组分（A）和（B）之和的量为0至40重量份; 一种涂布方法，包括以下步骤：对通过模塑上述聚丙烯树脂组合物而获得的模制品施加底漆涂层或者用等离子体照射成型产品而不进行脱脂，并用含卤素原子的有机溶剂洗涤产物，然后施加顶部 外套到产品; 以及涂布方法，其包括对通过模塑上述聚丙烯树脂组合物而获得的模塑产品进行脱脂和洗涤，然后对该产品施加顶涂层，而不对该模制产品施加底漆涂层或用等离子体照射模制产品。 根据上述方法获得的涂膜对模塑产品具有良好的粘结强度。

公开(公告)号：US5895744A

公开(公告)日：1999-04-20

申请号：US808367

申请日：1997-02-28

申请人： Janglin Chen ,  Gerald G. Reafler ,  David A. Glocker ,  Mark M. Romach ,  Richard C. Soper ,  Evelio A. Perez-Albuerne

发明人： Janglin Chen ,  Gerald G. Reafler ,  David A. Glocker ,  Mark M. Romach ,  Richard C. Soper ,  Evelio A. Perez-Albuerne

IPC分类号： B05D3/14 ,  B05D7/24 ,  B29C55/12 ,  B29C59/12 ,  B29C71/02 ,  B29K67/00 ,  B29L7/00 ,  C08J7/04 ,  G03C1/795 ,  G03C1/91 ,  B01J19/08

CPC分类号： G03C1/7954 ,  B05D3/144 ,  B29C59/12 ,  G03C1/915 ,  Y10S422/907

摘要： Method and apparatus for making thermoplastic web from polyester or polyester blends for subsequent aqueous coating without requirement of an undercoat or primer coat for adhesion of subsequent coatings. Feedstock pellets of polymer, such as polyethylene terephthalate or polyethylene naphthalate, are melted in a screw extruder. Molten polymer is extruded from an extrusion die as a thick, high-viscosity ribbon, which is tempered and stretched in both the machine direction and the transverse direction to form a web of biaxially-oriented polymer of the desired width and thickness. The web is heated to a temperature above T.sub.g to set the biaxial orientation and then is glow discharge treated by passing it through an in-line glow discharge apparatus at atmospheric pressure wherein a stable glow discharge is produced in a gas mixture containing helium between two electrodes connected by an alternating power source operating at a voltage between 0.5 kV and 20 kV at a frequency between 60 Hz and 40 MHz. The web is coated with an aqueous gelatin subbing layer. The coated web then is maintained at elevated temperature. The combination of glow discharge treatment before sub coating and heat treatment after sub coating greatly enhances the adhesion of subsequently-coated aqueous gelatin layers such as photographic emulsions to the web, sufficiently that adhesion-promoting U-coat or primer coat as required in prior base-making methods can be omitted.

摘要翻译： 用于由聚酯或聚酯共混物制备热塑性网的方法和设备用于随后的水性涂料，而不需要底涂层或底漆涂层用于后续涂层的粘附。 聚合物的原料颗粒如聚对苯二甲酸乙二醇酯或聚萘二甲酸乙二醇酯在螺杆挤出机中熔融。 将熔融聚合物从挤出模头挤出为厚的高粘度带，其在纵向和横向方向上进行回火和拉伸，以形成所需宽度和厚度的双轴取向聚合物网。 将幅材加热至高于Tg的温度以设定双轴取向，然后通过在大气压下通过直列辉光放电装置进行辉光放电处理，其中在包含两个电极之间的氦气的气体混合物中产生稳定的辉光放电 通过在60Hz至40MHz之间的频率以0.5kV和20kV之间的电压工作的交流电源连接。 网上涂有明胶胶层。 然后将涂覆的纸幅保持在升高的温度。 在次涂层之前的辉光放电处理和次涂层之后的热处理的组合大大增强了随后涂覆的含水明胶层（例如照相乳剂）对纸幅的粘附，足以使得在先前碱中所需的粘附促进U形涂层或底漆 制造方法可以省略。

公开(公告)号：US5789145A

公开(公告)日：1998-08-04

申请号：US685353

申请日：1996-07-23

申请人： David A. Glocker ,  Mark M. Romach ,  Richard C. Soper

发明人： David A. Glocker ,  Mark M. Romach ,  Richard C. Soper

IPC分类号： B01J19/08 ,  B05D3/06 ,  B05D3/14 ,  B29C59/12 ,  G03C1/91 ,  G03C1/85

CPC分类号： B29C59/12 ,  B05D3/144 ,  G03C1/915 ,  Y10S430/136 ,  Y10S430/151 ,  Y10S430/162

摘要： The present invention is a method for treating a polyester support such as polyethylene naphthalate or polyethylene terephthalate. The treatment is carried out at atmospheric pressure in a gas of helium and optionally nitrogen and/or oxygen. The treatment uses metallic electrodes and an atmospheric glow discharge results when the electrodes are connected to a generator and spaced about 1 to 2 mm apart. The process and apparatus improve adhesion of subsequently coated emulsions on the polyester support at high speeds and relatively low power by selecting a frequency of 40 kHz to 500 kHz.

摘要翻译： 本发明是用于处理聚萘二甲酸乙二醇酯或聚对苯二甲酸乙二醇酯等聚酯载体的方法。 处理在大气压下在氦气和任选的氮和/或氧气中进行。 处理使用金属电极，并且当电极连接到发生器并且间隔开约1至2mm间隔时，产生大气辉光放电。 该方法和设备通过选择40kHz至500kHz的频率来改善随后涂布的乳液在聚酯载体上的高速和相对低功率的粘附。