公开(公告)号：US20150147235A1

公开(公告)日：2015-05-28

申请号：US14411282

申请日：2012-10-25

申请人： IDT INTERNATIONAL CO., LTD.

发明人： Byoung Kyu Ji ,  Jung Young Choi ,  Cheol Min Shin

IPC分类号： C01B31/04 ,  B01J19/10

CPC分类号： C01B31/0446 ,  B01J19/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/05 ,  C01B32/184 ,  C01B32/192 ,  C01B32/20

摘要： There is provided an apparatus for preparing a graphene-structured material, the apparatus includes a supply hopper configured to supply graphite oxide; a supply line of which an end is connected to a lower end of the supply hopper; a reducing atmosphere gas supply unit connected to a side of the supply line; a vertical fluidized bed furnace of which a lower part is connected to another end of the supply line and configured to reduce the supplied graphite oxide with thermal-expansion; a discharge line of which an end is connected to an upper part of the vertical fluidized bed furnace; a vibrating type vertical micro filter connected to an opening portion on a side of the discharge line; a vacuum pump connected to the vertical micro filter; and, a collector positioned under the vertical micro filter and connected to another end of the discharge line.

摘要翻译： 提供了一种用于制备石墨烯结构材料的设备，该设备包括：供给料斗，其构造成供应氧化石墨; 其一端与供料斗的下端连接的供应管线; 连接到所述供给管线的一侧的还原气体气体供给单元; 垂直流化床炉，其下部连接到供应管线的另一端并构造成通过热膨胀减少供应的氧化石墨; 其一端与垂直流化床炉的上部连接的排出管线; 连接到排出线侧的开口部的振动式立式微型过滤器; 连接到垂直微滤器的真空泵; 以及位于垂直微滤器下方并连接到排出管线的另一端的收集器。

公开(公告)号：US20150140438A1

公开(公告)日：2015-05-21

申请号：US14406481

申请日：2013-05-23

申请人： TORAY INDUSTRIES, INC.

发明人： Peiyu Sun ,  Gangqiao Liu ,  Zhenqi Wu ,  Gang Wu ,  Eiichiro Tamaki ,  Yasuo Kubota

IPC分类号： H01M4/62 ,  H01M10/0525

CPC分类号： H01M4/625 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/192 ,  C01B32/194 ,  H01M10/052 ,  H01M10/0525

摘要： In order to prepare a highly conductive and highly dispersible graphene powder and to obtain an electrode for a lithium ion battery with excellent performance utilizing the highly conductive and highly dispersible graphene, a graphene powder and a preparation method thereof is provided. The graphene powder comprises a compound having a catechol group adsorbing on the surface of graphene in a weight ratio of 5-50% relative to the grapheme and the element ratio of oxygen to carbon in the graphene powder measured by X-ray photoelectron spectroscopy is 0.06 or more and 0.20 or less. The method for producing a graphene powder comprise the step of reducing a graphite oxide with a reducing agent having no catechol group in the presence of a compound having a catechol group.

摘要翻译： 为了制备高导电性和高度分散的石墨烯粉末，并且利用高导电性和高度分散的石墨烯获得具有优异性能的锂离子电池用电极，提供了石墨烯粉末及其制备方法。 石墨烯粉末包含以石墨烯表面吸附有邻苯二酚基团的化合物，其重量比为5-50％，并且通过X射线光电子能谱法测定的石墨烯粉末中氧与碳的元素比为0.06 以上且0.20以下。 石墨烯粉末的制造方法包括在具有儿茶酚基的化合物的存在下，用不含儿茶酚基的还原剂还原石墨氧化物的工序。

公开(公告)号：US20150111039A1

公开(公告)日：2015-04-23

申请号：US14220399

申请日：2014-03-20

申请人： SNU R&DB FOUNDATION

发明人： Sung Hyun KIM ,  Jyongsik JANG ,  Kyoung-Hwan SHIN

IPC分类号： H01B1/04 ,  H01L51/10

CPC分类号： H01B1/04 ,  C01B32/192 ,  C23C16/40 ,  C23C16/50 ,  H01L51/0045 ,  H01L51/055 ,  Y10T428/30

摘要： The embodiments described herein pertain generally to a preparing method of a reduced graphene oxide film, a reduced graphene oxide film prepared by the preparing method, a graphene electrode including the reduced graphene oxide film, an organic thin film transistor including the graphene electrode, and an antistatic film including the reduced graphene oxide film.

摘要翻译： 本文描述的实施方案通常涉及还原型氧化烯石膜的制备方法，通过制备方法制备的还原型石墨烯氧化物膜，包括还原型氧化烯石墨膜的石墨烯电极，包括石墨烯电极的有机薄膜晶体管和 抗静电膜包括还原的石墨烯氧化膜。

公开(公告)号：US20150093324A1

公开(公告)日：2015-04-02

申请号：US14397302

申请日：2012-08-10

申请人： Arockiadoss Thevasaharam

发明人： Arockiadoss Thevasaharam

IPC分类号： C01B31/04

CPC分类号： C01B31/0446 ,  B01J23/6527 ,  B01J35/0033 ,  B01J35/004 ,  B01J37/0225 ,  B01J37/036 ,  B01J37/347 ,  C01B13/0237 ,  C01B32/184 ,  C01B32/192 ,  C01B32/23 ,  C01B32/50 ,  C01B2204/02 ,  C01B2204/22

摘要： Compositions comprising graphene and methods for preparing graphene are described.

摘要翻译： 描述了包括石墨烯的组合物和用于制备石墨烯的方法。

公开(公告)号：US20150086977A1

公开(公告)日：2015-03-26

申请号：US14554912

申请日：2014-11-26

申请人： University of Pittsburgh - Of the Commonwealth System of Higher Education

发明人： ALEXANDER STAR ,  NARASIMHA HARINDRA VEDALA ,  GREGG PETER KOTCHEY

IPC分类号： G01N27/414 ,  G01N33/569 ,  G01N33/543 ,  C01B31/04 ,  G01N27/12

CPC分类号： G01N27/4146 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/192 ,  C01B32/194 ,  C12P3/00 ,  G01N27/127 ,  G01N27/4145 ,  G01N33/5438 ,  G01N33/56916 ,  G01N2333/245 ,  Y10S977/734 ,  Y10S977/898

摘要： A device including a composition formed by oxidation of graphene oxide to form holey graphene oxide having defects therein and reduction of the holey graphene oxide. A composition includes graphene oxide sheets including holes therein formed by oxidation to form a network of interconnected graphene oxide nanoribbons.

摘要翻译： 包括由氧化石墨烯氧化物形成的组合物以形成其中具有缺陷的孔状石墨烯氧化物并减少有孔石墨烯氧化物的装置。 组合物包括石墨烯氧化物片，其包括通过氧化形成的孔，以形成相互连接的氧化烯氧化物纳米带的网络。

公开(公告)号：US20150027900A1

公开(公告)日：2015-01-29

申请号：US14383877

申请日：2013-03-08

申请人： The University of Manchester

发明人： Robert Angus William Dryfe ,  Ian Anthony Kinloch ,  Amr M. Abdelkader

IPC分类号： C01B31/04 ,  C25B1/00

CPC分类号： C25B3/04 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/19 ,  C01B32/192 ,  C01B32/20 ,  C01B32/22 ,  C01B2204/04 ,  C25B1/00

摘要： A method for the production of graphene and graphite nanoplatelet structures having a thickness of less than 100 nm in an electrochemical cell, wherein the cell comprises: (a) a negative electrode which is graphitic; (b) a positive electrode which may be graphitic or another material; and (c) an electrolyte which is ions in a solvent where the cations are organic ions and metal ions; and wherein the method comprises the step of passing a current through the cell.

摘要翻译： 一种在电化学电池中生产厚度小于100nm的石墨烯和石墨纳米片结构的方法，其中所述电池包括：（a）石墨的负极; （b）可以是石墨或其他材料的正电极; 和（c）在阳离子是有机离子和金属离子的溶剂中的离子的电解质; 并且其中所述方法包括使电流通过所述电池的步骤。

公开(公告)号：US20140335011A1

公开(公告)日：2014-11-13

申请号：US14364970

申请日：2012-12-11

申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALT

发明人： Lionel Dubois ,  Serge Gambarelli ,  Ashok Nanjundan

IPC分类号： C01B31/04 ,  C25B1/00

CPC分类号： C01B31/0492 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B32/192 ,  C01B32/196 ,  C25B1/00

摘要： The present invention relates to a method for preparing graphene substantially free of contamination by metallic, magnetic, organic and inorganic impurities, and also to the use of the resulting graphene for the production of transparent electrodes, batteries, electron-acceptor or electron-donor materials, in particular in photovoltaic systems, photovoltaic panels, transistor channels, in particular in electronics, nonlinear emitters or absorbers of infrared photons, current-conducting electrodes, anti-static coatings, chemical detectors, vias and interconnections in electronics, current-conducting cables, and solar cells.

摘要翻译： 本发明涉及一种制备基本上不受金属，磁性，有机和无机杂质污染的石墨烯的方法，还涉及使用所得的石墨烯制备透明电极，电池，电子受体或电子给体材料 特别是在光伏系统，光伏面板，晶体管通道中，特别是在电子学领域，电子学中的非线性发射器或红外光子的吸收体，导电电极，防静电涂层，化学检测器，通路和互连，电流传导电缆， 和太阳能电池。

公开(公告)号：US08871171B2

公开(公告)日：2014-10-28

申请号：US13636712

申请日：2011-03-25

申请人： M. Samy El-Shall ,  Victor Abdelsayed ,  Hassan M. A. Hassan ,  Abd El Rahman S. Khder ,  Khaled M. Abouzeid ,  Qilin Dai ,  Parichehr Afshani ,  Frank Gupton ,  Ali R. Siamaki ,  Zeid Abdullah M. Alothman ,  Hamad Zaid Alkhathlan

发明人： M. Samy El-Shall ,  Victor Abdelsayed ,  Hassan M. A. Hassan ,  Abd El Rahman S. Khder ,  Khaled M. Abouzeid ,  Qilin Dai ,  Parichehr Afshani ,  Frank Gupton ,  Ali R. Siamaki ,  Zeid Abdullah M. Alothman ,  Hamad Zaid Alkhathlan

IPC分类号： C01B31/02 ,  B01J37/34 ,  B01J35/00 ,  B01J19/12 ,  C07B37/04 ,  B01J21/18 ,  B01J23/75 ,  B82Y30/00 ,  B01J23/50 ,  B01J23/755 ,  B01J23/44 ,  B01J23/745 ,  B01J23/72 ,  B82Y40/00 ,  C01B31/04

CPC分类号： B01J23/44 ,  B01J19/126 ,  B01J21/18 ,  B01J23/50 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J37/346 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B32/192 ,  C07B37/04

摘要： Microwave irradiation is used to synthesize graphene and metallic nanocatalysts supported on graphene either by solid or solution phase. In solid phase methods, no solvents or additional reducing agents are required so the methods are “environmentally friendly” and economical, and the graphene and nanocatalysts are substantially free of residual contaminants. Recyclable, high efficiency Pd nanocatylysts are prepared by these methods.

摘要翻译： 微波辐射用于通过固相或溶液相合成支持在石墨烯上的石墨烯和金属纳米催化剂。 在固相方法中，不需要溶剂或其它还原剂，因此该方法是“环境友好”且经济的，并且石墨烯和纳米催化剂基本上没有残留的污染物。 通过这些方法制备可回收的高效Pd纳米复合物。

公开(公告)号：US20140227211A1

公开(公告)日：2014-08-14

申请号：US14264360

申请日：2014-04-29

申请人： Peerless Worldwide, LLC

发明人： Richard S. Shankman

IPC分类号： A61K8/11 ,  A61Q17/04 ,  C10M125/04 ,  A61Q19/00 ,  C10M125/02 ,  C10M129/70

CPC分类号： C01B32/192 ,  A61K8/0241 ,  A61K8/19 ,  A61K2800/10 ,  A61K2800/28 ,  A61K2800/413 ,  A61Q17/04 ,  A61Q19/00 ,  B01J13/0056 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B32/186 ,  C01B32/20 ,  C01B32/225 ,  C01B32/23 ,  C10M103/02 ,  C10M125/02 ,  C10M125/04 ,  C10M129/70 ,  C10M171/06 ,  C10M177/00 ,  C10M2201/041 ,  C10M2201/0413 ,  C10N2220/082 ,  C10N2230/06 ,  C22C33/00 ,  C22C33/006 ,  C22C38/00 ,  F16D2300/06 ,  F16D2300/10 ,  Y10S977/734 ,  Y10S977/755 ,  Y10S977/843 ,  Y10S977/902

摘要： Methods of ex situ synthesis of graphene, graphene oxide, reduced graphene oxide, other graphene derivative structures and nanoparticles useful as polishing agents are disclosed. Compositions and methods for polishing, hardening, protecting, adding longevity to, and lubricating moving and stationary parts in devices and systems, including, but not limited to, engines, turbos, turbines, tracks, races, wheels, bearings, gear systems, armor, heat shields, and other physical and mechanical systems employing machined interacting hard surfaces through the use of nano-polishing agents formed in situ from lubricating compositions and, in some cases, ex situ and their various uses are also disclosed.

公开(公告)号：US20140154165A1

公开(公告)日：2014-06-05

申请号：US13980715

申请日：2012-03-27

申请人： Wensheng Yang ,  Jie Sun ,  Haimei Liu ,  Xu Chen ,  Xue Duan

发明人： Wensheng Yang ,  Jie Sun ,  Haimei Liu ,  Xu Chen ,  Xue Duan

IPC分类号： C01B31/04

CPC分类号： C01B31/0446 ,  C01B32/192 ,  C01B32/22 ,  Y10S977/789

摘要： The present invention relates to a method for preparing graphene using the two-dimensional confined space between the layers of inorganic layered materials. Such method comprises the following steps: mix a soluble salt of a divalent metal ion M2+, a soluble salt of a trivalent metal ion M′3+, a soluble salt of a chain alkyl anion A− and a carbon source molecule C and dissolve them in deionized and CO2-eliminated water to prepare a mixed salt solution; mix the mixed salt solution with an alkali solution under nitrogen protection and subject them to reaction and crystallization under nitrogen, and filter the suspension obtained thereafter and wash the filter cake with deionized water until the pH of the filtrate is 7 to 7.5, and then dry the filter cake to obtain layered double hydroxides with an intercalated structure; under an inert atmosphere or a reducing atmosphere, calcinate the layered double hydroxides with an intercalated structure to provide a calcinated product; add the calcinated product into a hydrochloric acid solution for ultrasonic treatment, and separate the solution by centrifugation and wash the precipitate obtained by centrifugation with deionized water until the pH of the filtrate is 6.5 to 7 to obtain the graphene.

摘要翻译： 本发明涉及使用无机层状材料层之间的二维密闭空间来制备石墨烯的方法。 该方法包括以下步骤：将二价金属离子M2 +的可溶性盐，三价金属离子M'3 +的可溶性盐，链烷基阴离子A的可溶性盐和碳源分子C混合并溶解 在去离子水和二氧化碳消除的水中制备混合盐溶液; 在氮气保护下将混合盐溶液与碱溶液混合，并在氮气下进行反应和结晶，过滤后得到的悬浮液，用去离子水洗涤滤饼直到滤液的pH为7至7.5，然后干燥 滤饼得到具有插层结构的层状双氢氧化物; 在惰性气氛或还原气氛下，以层间结构煅烧层状双氢氧化物，得到煅烧产物; 将煅烧后的产物加入到盐酸溶液中进行超声波处理，离心分离溶液，用去离子水离心洗涤沉淀，直到滤液的pH值达到6.5〜7，得到石墨烯。