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    Mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives
    113.
    发明授权
    Mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效

    公开(公告)号：US4448984A

    公开(公告)日：1984-05-15

    申请号：US458890

    申请日：1983-01-18

    Applicant: Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    Inventor： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    IPC: A24B15/34 ,  C07C47/347 ,  C07C47/445 ,  C07C43/162 ,  C07C35/28 ,  C07C67/035 ,  C07C67/04

    CPC classification number: A24B15/345 ,  C07C47/347 ,  C07C47/445

    Abstract: Described are mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++] is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl. Also described are processes for preparing such mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives, and processes for using the above defined mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives for their organoleptic properties and compositions containing said mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives including perfumes, perfumed articles (such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softeners and cosmetic powders), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos and smoking tobacco articles.

    Flavoring with methyl-thio-2-methyl-2-pentenoate
    114.
    发明授权
    Flavoring with methyl-thio-2-methyl-2-pentenoate 失效
    用甲基硫代-2-甲基-2-戊烯酸酯调味

    公开(公告)号：US4404184A

    公开(公告)日：1983-09-13

    申请号：US458892

    申请日：1983-01-18

    Applicant: Alan O. Pittet ,  Ranya Muralidhara ,  Manfred H. Vock

    Inventor： Alan O. Pittet ,  Ranya Muralidhara ,  Manfred H. Vock

    IPC: A23G3/00 ,  A23G3/36 ,  A23G4/00 ,  A23G4/06 ,  A23L27/20 ,  A61K7/16 ,  A23L1/226 ,  A23L1/234 ,  A23L1/235

    CPC classification number: A23G3/36 ,  A23G4/06 ,  A23L27/2022

    Abstract: Described are cis isomers, trans isomers and mixtures of cis and trans isomers of methyl-thio-2-methyl-2-pentenoate defined according to one of the structures: ##STR1## wherein the wavy lines represent "cis" and "trans" configurations of methyl, ethyl and methylthiocarboxy moieties around the carbon-carbon double bond; ##STR2## and uses of such methyl-thio-2-methyl-2-pentenoates in augmenting or enhancing the aroma or taste of foodstuffs, chewing gums, medicinal products or toothpastes.

    Abstract translation: 描述了根据以下结构之一定义的甲基 - 硫代-2-甲基-2-戊烯酸酯的顺式异构体，反式异构体和顺式和反式异构体的混合物：其中波浪线代表“顺式”和“反式”构型 在碳 - 碳双键周围的甲基，乙基和甲基硫代羧基部分; 此类甲基硫代-2-甲基-2-戊烯酸酯在增加或增强食品，口香糖，药用产品或牙膏的香气或味道方面的用途。

    Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives
    115.
    发明授权
    Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效
    用于改变吸烟烟草香气和风味或单氧甲基取代的多羟基甲基萘衍生物

    公开(公告)号：US4391284A

    公开(公告)日：1983-07-05

    申请号：US354387

    申请日：1982-03-02

    Applicant: Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    Inventor： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    IPC: A24B15/34 ,  C07C47/347 ,  C07C47/445 ,  A24B3/12 ,  A24B15/30

    CPC classification number: A24B15/345 ,  C07C47/347 ,  C07C47/445

    Abstract: Described is the use in modifying, augmenting or enhancing the aroma or taste of smoking tobacco products of mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++]is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl.

    Abstract translation: 描述了用于改变，增强或增强具有以下通用结构的单氧代甲基取代的多羟基甲基萘衍生物的烟草产品的香气或味道：其中虚线表示碳 - 碳单键或碳 - 碳双 键; 其中R1，R1'，R1“，R1”，R1“，R3，R5，R5'，R5”，R5“，R5”和R6表示氢或甲基， 条件：（i）R1，R1'，R1“，R1”和R1“”中的至少四个为氢; 和（ii）R5，R5'，R5“，R5”和R5“中的至少四个表示氢; （ⅰ）具有以下结构的甲醛：（ⅱ）具有以下结构的亚烷基二氧基或二烷氧基甲基：（ⅲ）具有以下结构的羟基甲基：（ⅳ） 具有以下结构的乙酰氧基甲基：其中R7和R8分别代表C1-C4低级烷基或R7和R8一起代表C2-C4亚烷基; 其中由以下各项表示的线：[++++]是（i）当R 7和R 8一起为C 2 -C 4亚烷基时的碳 - 碳单键或（ii）当R7和R8分别表示C1 -C4低级烷基。

    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof
    116.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯及其感官用途

    公开(公告)号：US4374055A

    公开(公告)日：1983-02-15

    申请号：US314002

    申请日：1981-10-22

    Applicant: Ronald P. Schreck ,  Kenneth K. Light ,  John B. Hall ,  Frederick L. Schmitt ,  Manfred H. Vock ,  William L. Schreiber ,  Joaquin F. Vinals ,  Jacob Kiwala

    Inventor： Ronald P. Schreck ,  Kenneth K. Light ,  John B. Hall ,  Frederick L. Schmitt ,  Manfred H. Vock ,  William L. Schreiber ,  Joaquin F. Vinals ,  Jacob Kiwala

    IPC: A24B15/34 ,  C11B9/00 ,  C11D3/50 ,  A61K7/46

    CPC classification number: A24B15/34 ,  C11B9/0026 ,  C11D3/50

    Abstract: Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    Abstract translation: 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法：其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基，二甲基或三甲基取代的环烷基部分 环，其中R 3是C 1 -C 3低级烷基，R 4是甲基或氢，通过使具有通式结构的化合物：在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品，食品香料，口香糖，口香糖调味剂，牙膏，牙膏调味剂，药用产品，药用香料，咀嚼烟草，咀嚼烟草香料，烟草烟草， 吸烟烟草调味剂，香料组合物，香料制品，例如阳离子，阴离子，非离子和两性离子洗涤剂，织物柔软剂组合物，干燥剂添加的织物柔软剂制品，纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

    Process of enhancing or augmenting the aroma of detergents using norbornyl esters
    117.
    发明授权
    Process of enhancing or augmenting the aroma of detergents using norbornyl esters 失效
    使用降冰片烯酯增强或增加洗涤剂香气的方法

    公开(公告)号：US4357253A

    公开(公告)日：1982-11-02

    申请号：US303161

    申请日：1981-09-17

    Applicant: Philip T. Klemarczyk ,  James M. Sanders ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Frederick L. Schmitt ,  Edward J. Granda

    Inventor： Philip T. Klemarczyk ,  James M. Sanders ,  Manfred H. Vock ,  Joaquin F. Vinals ,  Frederick L. Schmitt ,  Edward J. Granda

    IPC: C07C45/62 ,  C07C61/13 ,  C11B9/00 ,  C11D3/50

    CPC classification number: C11D3/50 ,  C07C45/62 ,  C07C61/13 ,  C11B9/0046

    Abstract: Described are compounds both separately and in admixture having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.6 and R.sub.7 represents hydrogen or methyl with the proviso that one of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is methyl and each of the other of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed. In addition organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents) fabric softeners, dryer-added fabric softener articles and smoking tobaccos. Also disclosed is a process for preparing such compounds according to one of the reaction schemes: ##STR2## wherein R' represents C.sub.1 -C.sub.3 alkyl; m+n equals 3 with the proviso that m is one or two and n is one or two; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are defined as above; or ##STR3## wherein R.sub.1 -R.sub.7 are defined as above.

    Abstract translation: 描述的是具有通用结构的单独和混合的化合物：其中虚线是碳 - 碳单键或碳 - 碳双键，R1，R2，R3，R4，R6和R7各自表示 氢或甲基，条件是R 1，R 2，R 6和R 7中的一个为甲基，R 1，R 2，R 6和R 7中的每一个为氢，且R 3和R 4不为甲基; 其中R5代表C1-C4烷基。 此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，医药产品，牙膏，香料，香料制品（如液体或固体阴离子，阳离子，非离子或非离子的 两性离子洗涤剂）织物柔软剂，干燥剂添加织物柔软剂制品和吸烟烟草。 还公开了根据以下反应方案之一制备这种化合物的方法：其中R'表示C 1 -C 3烷基; m + n等于3，条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4和R 5如上定义; 或 dbb HR2COOR5 R3HR7R4 + dbb R1R4R3COOR5R6HH + RE其中R1-R7如上定义。

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