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    Process for produced stabilized olefin
    112.
    发明授权
    Process for produced stabilized olefin 失效
    生产的稳定烯烃的方法

    公开(公告)号：US3892712A

    公开(公告)日：1975-07-01

    申请号：US27593672

    申请日：1972-07-28

    Applicant: SNAM PROGETTI

    Inventor： ARRIGHETTI SERGIO ,  CESCA SEBASTIANO ,  GHETTI GIUSEPPE ,  VAJNA EUGENIO

    IPC: C08F8/00 ,  C08F8/32 ,  C08F8/34 ,  C08F15/40 ,  C08F27/18

    CPC classification number: C08F8/34 ,  C08F210/18 ,  C08F8/00

    Abstract: A method is described whereby olefin terpolymers, consisting of ethylene, an alpha olefin and a polyene having in the molecule, in addition to the double bond participating in the formation of the macromolecule, at least one conjugated double bond system, are stabilied against oxidative aging without destroying their characteristic high vulcanization rate by reacting them with a dienophilic agent represented by one of the following formulae:

    WHEREIN R and R6 may be an alkyl, alkenyl, cycloalkyl, aryl or aralkyl radical having up to 8 carbon atoms, R1, R2, R3, R4 and R5 may be hydrogen or alkyl, aryl, cycloalkyl or aralkyl radicals having up to 8 carbon atoms, the R1-R2 and R-R pairs may be divalent radicals forming condensed rings.

    Abstract translation: 描述了一种方法，其中由乙烯，α-烯烃和分子内具有多键的烯烃三元共聚物除了参与高分子形成的双键之外，还具有至少一个共轭双键体系，以抵抗氧化老化 通过使它们与由下式表示的二亲性剂反应而破坏它们的特征性高硫化速率：WHEREIN R和R 6可以是具有至多8个碳原子的烷基，烯基，环烷基，芳基或芳烷基，R 1，R 2， R3，R4和R5可以是氢或具有至多8个碳原子的烷基，芳基，环烷基或芳烷基，R1-R2和RR对可以是形成稠环的二价基团。

    Production of synthetic lubricants from alpha-olefins through a ternary catalytic system
    114.
    发明授权
    Production of synthetic lubricants from alpha-olefins through a ternary catalytic system 失效
    通过三元催化体系从α-烯烃生产合成润滑剂

    公开(公告)号：US3884988A

    公开(公告)日：1975-05-20

    申请号：US33262773

    申请日：1973-02-15

    Applicant: SNAM PROGETTI

    Inventor： GIROTTI PIERLEONE ,  TESEI RENATO ,  FLORIS TELEMACO

    IPC: C08F110/14 ,  C07C2/08 ,  C07C2/30 ,  C07C6/02 ,  C07C9/14 ,  C08F4/14 ,  C08F10/14 ,  C10M107/10 ,  C10M169/00 ,  C07C3/10

    CPC classification number: C10M3/00 ,  C08F10/14 ,  C10M2205/00

    Abstract: Synthetic, high quality lubricating oils are produced through the polymerization of a single alpha-olefin or a mixture of alpha-olefins from ''''wax-cracking'''' having the formula R - CH CH2 wherein R is an alkyl radical containing from 2 to 16 C atoms, by the use, in a dry nitrogen atmosphere, of a catalyst system constituted by a compound of a transition metal selected from groups IV to VIII of the periodic system (e.g., TiCl4) and by two coordinate anionic cocatalysts, one of which is an aluminum compound of inorganic nature devoid of any metal-carbon bond and consisting of a polyiminic linear polymer (e.g., a polyimine alane represented by the formula:

    WHEREIN R is alkyl, aryl or cycloalkyl and n is a whole number from 4 to 25) and the other of which is an aluminum compound of the conventional Ziegler type with a metal-carbon link (e.g., an aluminum alkyl sesquichloride or an aluminum dialkyl monochloride.

    Abstract translation: 合成的高品质润滑油是通过单个α-烯烃或由具有式R-CH = CH 2的“蜡裂解”）的α-烯烃的混合物的聚合制备的，其中R是含有2至16个碳原子的烷基 原子通过在干燥的氮气气氛中使用由周期性系统的IV至VIII族的过渡金属的化合物（例如TiCl 4）构成的催化剂体系以及由两个配位阴离子助催化剂组成的催化剂体系，其中之一是 不含任何金属 - 碳键并由多元线性聚合物（例如，由下式表示的聚亚烷基亚烷基，其中R是烷基，芳基或环烷基并且n是整数4至25）的无机性的铝化合物， 另一种是具有金属 - 碳键的常规齐格勒型铝化合物（例如，烷基倍半氯化铝或一氯化铝二烷基铝。

    Hydrogen transfer process
    117.
    发明授权
    Hydrogen transfer process 失效
    氢转移过程

    公开(公告)号：US3849510A

    公开(公告)日：1974-11-19

    申请号：US18905071

    申请日：1971-10-13

    Applicant: SNAM PROGETTI

    Inventor： MASPERO F ,  PERROTTI E

    IPC: C07C11/12 ,  C07C5/27 ,  C07C5/52 ,  C07C5/02 ,  C07C5/18

    CPC classification number: C07C5/52

    Abstract: 1. A PROCESS FOR TRANSFORMING AN OLEFINIC COMPOUND INTO A MIXTURE OF COMPOUNDS WHICH COMPRISE A COMPOUND THAT IS THE CORRESPONDING SATURATED HYDROCARBON AND A COMPOUND THAT IS THE CORRESPONDING DIOLEFIN, SAID PROCESS COMPRISING PASSING AN OLEFIN OVER (IR(P(C6H5)3)2)2, SAID PROCESS BEING CARRIED OUT AT A PRESSURE EQUAL TO OR HIGHER THAN ATOMSPHERIC PRESSURE.

    Process for the oxidative dehydrocyclization of imines
    119.
    发明授权
    Process for the oxidative dehydrocyclization of imines 失效
    过氧化氢脱氢酶的方法

    公开(公告)号：US3845072A

    公开(公告)日：1974-10-29

    申请号：US19492671

    申请日：1971-11-02

    Applicant: SNAM PROGETTI

    Inventor： ROMANO U ,  MAOGGI P ,  MAURI M

    IPC: C07D209/08 ,  C07D27/56

    CPC classification number: C07D209/08

    Abstract: A-N=C(-R)-B

    WHEREIN N IS NITROGEN; C IS CARBONIUM; R IS A MEMBER OF THE GROUP CONSISTING OF HYDROGEN, LOWER ALKYL, LOWER ALKENYL AND CARBOCYCLIC MONOCYCLIC ARYL; A AND B ARE MEMBERS OF THE GROUP CONSISTING OF LOWER ALKYL LOWER ALKENYL, MONOCYCLIC CARBOCYCLIC ARLY AND ARALKYL REPRESENTED BY CH3C6H.4 AND C2H5H.4, ARE CAUSED TO REACT INTHE VAPORR PHASE BY HEATING SAID OXYGEN AND IMINE TOGETHER IN THE MOLAR RANGE FROM 0.2:01 TO 10:1 TO A TEMPERATURE IN THE RANGE OFF 300* TO 800* C. FOR A TIME RANGING FROM 0.1 TO 20 SECONDS IN THE PRESENCE OF ACTIVATED SILICA AND STEAM.
    1. A PROCESS FOR THE PRODUCTION OF HIGH YIELDS OF INDOLE AND ALKYL, ARALKYL AND PHENYL SUBSTITUTED INDOLES THROUGH THE OXIDATIVE DEHYDROCYCLIZATION OF IMINES WHEREIN OXYGEN AND THE CORRESPONDING IMINE RE MULA

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