公开(公告)号：US5500398A

公开(公告)日：1996-03-19

申请号：US336864

申请日：1994-11-09

Applicant: Tobin J. Marks ,  Xinmin Yang

Inventor： Tobin J. Marks ,  Xinmin Yang

IPC: B01J31/14 ,  B01J31/22 ,  C07C2/34 ,  B01J31/38

CPC classification number: C07C2/34 ,  B01J31/146 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2531/22

Abstract: A new class of olefin dimerization catalysts and an efficient method for their preparation is disclosed. B(C.sub.6 F.sub.5).sub.3 reacts quantitatively with Group 4 metallocene type catalysts to yield highly reactive cationic complexes as follows:(L.sub.2 MR.sup.2).sup.+ X.sup.- whereL=R.sub.2 (C.sub.5 H.sub.3); R=a C.sub.3 -C.sub.20 tert-alkyl group; R.sup.2 =a C.sub.1 -C.sub.20 alkyl group, HM=Ti, Zr, Hf;X.sup.- =RB(C.sub.5 F.sub.3).sup.-.sub.3, or methylalumoxane, where R"=a C.sub.1 -C.sub.20 alkyl group, H.These complexes are potent catalysts and may be used in the dimerization of .alpha.-olefins.

Abstract translation: 公开了一类新的烯烃二聚催化剂及其制备方法。 B（C6F5）3与第4族金属茂型催化剂定量反应，得到高反应性阳离子络合物如下：（L2MR2）+ X-，其中L = R2（C5H3）; R = C 3 -C 20叔烷基; R2 = C1-C20烷基，H M = Ti，Zr，Hf; X = RB（C5F3）-3或甲基铝氧烷，其中R“= C1-C20烷基，H.这些络合物是有效的催化剂，可用于α-烯烃的二聚。

公开(公告)号：US5447895A

公开(公告)日：1995-09-05

申请号：US209668

申请日：1994-03-10

Applicant: Tobin J. Marks ,  Li Ja ,  Xinmin Yang

Inventor： Tobin J. Marks ,  Li Ja ,  Xinmin Yang

IPC: B01J31/02 ,  B01J31/14 ,  B01J31/22 ,  C08F4/619 ,  C08F10/00 ,  B01J31/16

CPC classification number: B01J31/146 ,  B01J31/2295 ,  C08F10/00 ,  B01J2531/48 ,  C08F4/619 ,  C08F4/61908

Abstract: A non-coordinating anion, preferably containing a sterically shielded diboron hydride, if combined with a cyclopenta-dienyl-substituted metallocene cation component, such as a zirconocene metallocene, is a useful olefin polymerization catalyst component. The anion preferably has the formula ##STR1## where R is branched lower alkyl, such as t-butyl.

Abstract translation: 如果与环戊二烯基取代的茂金属阳离子组分如二茂锆茂金属组合，则非配位阴离子优选含有空间屏蔽的二硼氢化物，是有用的烯烃聚合催化剂组分。 阴离子优选具有式“IMAGE”，其中R是支链低级烷基，例如叔丁基。

公开(公告)号：US5300598A

公开(公告)日：1994-04-05

申请号：US962390

申请日：1992-10-16

Applicant: Tobin J. Marks ,  Xinmin Yang ,  Li Jia

Inventor： Tobin J. Marks ,  Xinmin Yang ,  Li Jia

IPC: C08F4/642 ,  B01J31/22 ,  C07F17/00 ,  C08F4/64 ,  C08F4/643 ,  C08F4/6592 ,  C08F210/02 ,  C08G61/06 ,  C03G61/06

CPC classification number: B01J31/146 ,  B01J31/2295 ,  C07F17/00 ,  C08F210/02 ,  C08G61/06 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  Y10S526/943

Abstract: The regiospecific (1,2-Me.sub.2 C.sub.5 H.sub.3).sub.2 ZrMe.sup.+ MeB(C.sub.6 F.sub.5).sub.3.sup.- mediated ring-opening polymerization of methylenecyclobutane and its copolymerization with ethylene to polyolefins of microstructure--{CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.n and {--[CH.sub.2 CHR]--.sub.x [CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.y }.sub.n' respectively, is disclosed.

Abstract translation: 区域特异性（1,2-Me2C5H3）2ZrMe + MeB（C6F5）3-介导的亚甲基环丁烷的开环聚合及其与乙烯与微观结构的聚烯烃（CH 2 CH 2 CH 2 C（CH 2）） - n和（ - （CH 2 CHR） （CH 2 CH 2 CH 2 C（CH 2）） - y）n'。

公开(公告)号：US5156918A

公开(公告)日：1992-10-20

申请号：US676992

申请日：1991-03-28

Applicant: Tobin J. Marks ,  DeQuan Li

Inventor： Tobin J. Marks ,  DeQuan Li

IPC: B05D1/18 ,  G02F1/361

CPC classification number: B82Y30/00 ,  B05D1/185 ,  B82Y40/00 ,  G02F1/3617 ,  Y10T428/31612 ,  Y10T428/31663

Abstract: Polymer-based second harmonic generation materials are disclosed, including electric field poled, chromophore-functionalized polyphenylene ethers with second harmonic coefficients (d.sub.33) as high as 65.times.10.sup.-9 esu, Tg.apprxeq.173.degree. C., and with superior temporal stability of the poling-induced chromophore orientation. Procedures for simultaneously poling and diepoxide cross-linking chromophore-functionalized poly(.rho.-hydroxystyrene) are set forth, resulting in a significant improvement in the temporal stability of chromophore orientation. Chromophore immobilization is disclosed involving highly cross-linkable epoxy matrices. In a first procedure chromophore molecules are embedded in a matrix which can be simultaneously poled and thermally cured. In a second procedure, a functionalized high-.beta. chromophore is synthesized for use as an epoxy matrix component.

Abstract translation: 公开了基于聚合物的二次谐波发生材料，其包括具有高达65×10 -9 esu的二次谐波系数（d33）的电场极化，发色团官能化聚苯醚，Tg约为173℃，并且具有优异的极化时间稳定性 诱导发色团取向。 阐述了同时极化和双环氧化物交联发色团官能化的聚（对羟基苯乙烯）的方法，导致发色团取向的时间稳定性的显着改善。 公开涉及高度可交联的环氧基质的发色团固定化。 在第一步骤中，发色团分子嵌入基质中，其可以同时极化并热固化。 在第二程序中，合成功能化的高β发色团用作环氧基质组分。

公开(公告)号：US5110948A

公开(公告)日：1992-05-05

申请号：US492823

申请日：1990-03-13

Applicant: Tobin J. Marks ,  Steven P. Nolan ,  Michel R. Gagne

Inventor： Tobin J. Marks ,  Steven P. Nolan ,  Michel R. Gagne

IPC: C07D209/08 ,  C07D295/023

CPC classification number: C07D295/023 ,  C07D209/08

Abstract: The reaction of a samarium catalyst [.eta..sup.5 --(CH.sub.3).sub.5 C.sub.5 ].sub.2 Sm(THF).sub.2 with amino-olefins provides a straightforward route to a heterocyclic compound. Alternatively, the reaction of olefins with the samarium catalyst in the presence of an amine results in an aminoalkane.

Abstract translation: 钐催化剂[η5（CH3）5C5] 2Sm（THF）2与氨基烯烃的反应为杂环化合物提供了直接的途径。 或者，烯烃与钐催化剂在胺存在下的反应产生氨基烷烃。

公开(公告)号：US4716257A

公开(公告)日：1987-12-29

申请号：US29186

申请日：1987-05-14

Applicant: Tobin J. Marks ,  Heiko Mauermann

Inventor： Tobin J. Marks ,  Heiko Mauermann

IPC: B01J31/16 ,  B01J31/22 ,  C07C5/03 ,  C07F5/00 ,  C07F7/02 ,  C07F17/00 ,  C08F10/00

CPC classification number: C07F17/00 ,  B01J31/2295 ,  C07C5/03 ,  C07F5/00 ,  C07F7/025 ,  C08F10/00 ,  B01J2231/12 ,  B01J2231/645 ,  B01J2531/37 ,  B01J2531/38 ,  C07C2531/22

Abstract: The reaction of the organolanthanide complexes [.eta..sup.5 --(CH.sub.3).sub.5 C.sub.5 ].sub.2 MCl.sub.2.sup.- Li((C.sub.2 H.sub.5).sub.2 O).sub.2.sup.+, M=La, Nd, Sm, Lu, with LiCH[Si(CH.sub.3).sub.3 ].sub.2 provides a straight-forward route to ether-free and halide-free bis(pentamethylcyclopentadienyl) lanthanide alkyls, (.eta..sup.5 (CH.sub.3).sub.5 C.sub.5).sub.2 MCH-[Si(CH.sub.3).sub.3 ].sub.2. The (.eta..sup.5 (CH.sub.3).sub.5 C.sub.5).sub.2 NdCH[Si(CH.sub.3).sub.3 ].sub.2 complexes react with H.sub.2 under mild conditions to yield the corresponding hydrides [(.eta..sup.5 (CH.sub.3).sub.5 C.sub.5).sub.2 MH].sub.2. These complexes have been found to be extremely active homogeneous olefin polymerization catalysts, as well as catalysts for olefin and acetylene hydrogenation.

公开(公告)号：US4563300A

公开(公告)日：1986-01-07

申请号：US451408

申请日：1982-12-20

Applicant: Kenneth J. Wynne ,  Tobin J. Marks ,  Tamotsu Inabe

Inventor： Kenneth J. Wynne ,  Tobin J. Marks ,  Tamotsu Inabe

IPC: C08G79/00 ,  C08L77/00 ,  C08L83/08 ,  C08L85/00 ,  H01B1/12 ,  H01M4/60 ,  H01B1/20

CPC classification number: H01M4/60 ,  C08G79/00 ,  C08L77/00 ,  C08L83/08 ,  C08L85/00 ,  H01B1/12 ,  Y10T428/2913 ,  Y10T428/294 ,  Y10T428/2969 ,  Y10T428/31765

Abstract: Methods and formable compositions for fabricating electrically conductive articles comprising ionically bonding cofacially stacking organomacrocycles and as cofacially stacking phthalocyanines, in which a composition comprising a cofacially stacking phthalocyanine in strong Bronsted acid is formed into a desired shape such as a fiber or film, solidified by removal of the solvent, and provided in fractional valence state.

Abstract translation: 用于制造导电制品的方法和可成形组合物包含离子键合共面层叠的有机钼和作为共表面层叠酞菁，其中将包含强布朗斯台德酸中的共表面层叠酞菁的组合物形成为期望的形状，例如纤维或膜，通过去除固化 的溶剂，并以分数价态提供。

公开(公告)号：US20160170244A1

公开(公告)日：2016-06-16

申请号：US15018361

申请日：2016-02-08

Applicant: Seng-Tiong Ho ,  Fei Yi ,  Tobin J. Marks

Inventor： Seng-Tiong Ho ,  Fei Yi ,  Tobin J. Marks

IPC: G02F1/065 ,  G02F1/00

CPC classification number: G02F1/065 ,  G02F1/0018 ,  G02F1/2255 ,  G02F2201/122 ,  G02F2202/02

Abstract: Electro-optic (EO) modulator and related device structures which can be used in conjunction with high EO materials to lower switching voltage and improve related performance parameters.

Abstract translation: 电光（EO）调制器和相关的器件结构，可与高EO材料结合使用，以降低开关电压并改善相关性能参数。

公开(公告)号：US08471253B2

公开(公告)日：2013-06-25

申请号：US13111545

申请日：2011-05-19

Applicant: Tobin J. Marks ,  Young-geun Ha ,  Antonio Facchetti

Inventor： Tobin J. Marks ,  Young-geun Ha ,  Antonio Facchetti

IPC: H01L29/12 ,  H01L51/00

CPC classification number: H01L29/7869 ,  B82Y40/00 ,  H01L21/02159 ,  H01L21/02282 ,  H01L27/1292 ,  H01L29/4908 ,  H01L51/0537

Abstract: Disclosed are thin film transistor devices incorporating a crosslinked inorganic-organic hybrid blend material as the gate dielectric. The blend material, obtained by thermally curing a mixture of an inorganic oxide precursor sol and an organosilane crosslinker at relatively low temperatures, can afford a high gate capacitance, a low leakage current density, and a smooth surface, and can be used to enable satisfactory transistor device performance at low operating voltages.

Abstract translation: 公开了掺入交联的无机 - 有机混合共混材料作为栅极电介质的薄膜晶体管器件。 通过在较低温度下热固化无机氧化物前体溶胶和有机硅烷交联剂的混合物获得的共混材料可以提供高栅极电容，低漏电流密度和光滑表面，并且可以用于令人满意 晶体管器件在低工作电压下的性能。

公开(公告)号：US20120252976A1

公开(公告)日：2012-10-04

申请号：US13449750

申请日：2012-04-18

Applicant: Tobin J. Marks ,  Michael T. Lanagan ,  Neng Guo ,  Sara A. DiBenedetto

Inventor： Tobin J. Marks ,  Michael T. Lanagan ,  Neng Guo ,  Sara A. DiBenedetto

IPC: C08L23/12 ,  C08F4/76 ,  C08F4/42 ,  B82Y30/00

CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08J2323/02 ,  H01G4/1227 ,  C08F4/025 ,  C08F4/65916 ,  C08F2500/15

Abstract: Metal oxide-polymer composites and methods of preparation.

Abstract translation: 金属氧化物 - 聚合物复合材料及其制备方法。