摘要:
Disclosed are processes for the preparation of copper containing molecular sieves with the CHA structure wherein the copper is exchanged into the Na+-form of the Chabazite, using a liquid copper solution wherein the concentration of copper is in the range of about 0.001 to about 0.4 molar. Also described are copper containing molecular sieves with the CHA structure, catalysts incorporating molecular sieves, systems and methods for their use.
摘要:
The invention relates to a method for controlling the withdrawal of gas from a sorption reservoir. The temperature in the sorption reservoir having a decreasing amount of gas therein is increased until a maximum acceptable temperature is reached such that a predetermined minimum pressure in the sorption reservoir does not fall below that threshold. The invention also relates to a device for storing at least one gas, having a sorption reservoir that has at least one attachment via which the sorption reservoir can be filled with gas or via which gas can be withdrawn from the sorption reservoir. The invention also relates to a device having at least one heating element which can warm the sorption reservoir, also a control system that can increase the temperature in the sorption reservoir when withdrawing the gas in such a manner that a predetermined minimum temperature in the sorption reservoir is not fallen below in order to attain a maximum acceptable pressure.
摘要:
A method for arranging an optical module in a measuring apparatus includes: providing the measuring apparatus with an irradiation system for irradiating the optical module with electromagnetic radiation, a reference component, and a detection element defining a detection surface, the detection element being disposed in a defined position in relation to the reference component, disposing the optical module in the measuring apparatus such that the radiation emitted by the irradiation system passes through the optical module and impinges onto the detection surface as an exit beam, measuring a position of the exit beam in relation to the detection surface, adjusting the position of the optical module within the measuring apparatus such that the position of the exit beam in relation to the detection surface is brought to correspond to a predetermined position, and establishing position parameters defining the position of the optical module in relation to the reference component.
摘要:
The present invention relates to a process for preparing porous organic frameworks by reaction of a reaction mixture in a liquid phase comprising the appropriate starting compounds in the presence of a nonaqueous organic solvent in the presence of and/or with liberation of water, wherein the latter is withdrawn from the liquid phase of the reaction mixture during the reaction. Here, frameworks having relatively high specific surface areas can be obtained in a reproducible way.
摘要:
Process for the integrated preparation of aromatics and ammonia by reaction of a gas stream A comprising at least one C1-C6-aliphatic and nitrogen in the presence of at least one catalyst, wherein the C1-C6-aliphatics are converted nonoxidatively into aromatics in one reaction and the hydrogen liberated in this reaction is reacted with nitrogen to form ammonia in a further reaction.
摘要:
The present invention relates to a porous metal organic framework formed by Mg2+ ions to which 5-tert-butylisophthalate ions are coordinated to form a framework structure. The invention further provides a process for preparing it and its use, for example for the storage, separation or controlled release of a substance such as a gas or gas mixture.
摘要:
The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.
摘要:
The invention relates to a lock device comprising a key and a lock cylinder, said lock cylinder comprising a fixed cylinder housing and a cylinder core mounted to rotate therein. The key shaft (10.3) has an edge profile and may be inserted in a key way of the cylinder core in which displaceable tumblers (41, 42) are located transverse to the above. The key shaft (10.3) has profiled recesses running in the longitudinal direction, comprising a pair of follow points for each tumbler (41, 42) for coding the key, whilst the tumbler (41, 42) has a pair of counter follow points which are the basis of the corresponding counter coding. According to this invention, a space-saving design of the lock device may be achieved with a large range of variation for the coding wherein both follow points are on the key shaft (10.3) in the form of recesses, arranged on opposing lateral surfaces to an edge (57.2; 57.3) of the edge profile of the key shaft (10.3). A web (22; 23) is thus generated in the corner region of the edge profile between both recesses. Said web functions a code web (22; 23), as the opposing web edges serve for the coding. The corresponding tumblers (41, 42) have a cut-out, which in use enclose the code web (22; 23) on opposing web edges. The lateral limits of the cut-out form the counter follow points in the tumblers (41, 42).
摘要:
In the pumping unit disclosed, the friction acting on the impeller is reduced, and the efficiency is increased by at least two adjacent indentations of at least one face end of the impeller and/or of the at least one end wall of the pump chamber communicate with one another via a respective groove.
摘要:
The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.