公开(公告)号：US08728972B2

公开(公告)日：2014-05-20

申请号：US13123872

申请日：2009-10-08

Applicant: Zhiping Shan

Inventor： Zhiping Shan

IPC: B01J20/34 ,  B01J38/50 ,  B01J38/52 ,  B01J27/198

CPC classification number: B01J27/198 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/06 ,  C07C51/215 ,  C07C57/145

Abstract: Embodiments of the present invention disclose improved micro-pore catalyst structures containing catalytic material comprised of mixed oxides of vanadium and phosphorus and using such improved micro-pore catalyst structures for the production of maleic anhydride.

Abstract translation: 本发明的实施方案公开了包含由钒和磷的混合氧化物组成的催化材料的改进的微孔催化剂结构，并且使用这种用于生产马来酸酐的改进的微孔催化剂结构。

公开(公告)号：US08652988B2

公开(公告)日：2014-02-18

申请号：US13095419

申请日：2011-04-27

Applicant: Dick Nagaki ,  Heiko Weiner ,  Josefina T. Chapman ,  Mark O. Scates ,  Alexandra S. Locke ,  Craig J. Peterson

Inventor： Dick Nagaki ,  Heiko Weiner ,  Josefina T. Chapman ,  Mark O. Scates ,  Alexandra S. Locke ,  Craig J. Peterson

IPC: B01J27/198 ,  B01J23/00

CPC classification number: C07C51/347 ,  B01J23/22 ,  B01J27/198 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/353 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C57/04

Abstract: In one embodiment, the invention is to a catalyst composition, comprising vanadium and titanium. Preferably, the molar ratio of vanadium to titanium in an active phase of the catalyst composition is greater than 0.5:1.

Abstract translation: 在一个实施方案中，本发明涉及包含钒和钛的催化剂组合物。 优选地，催化剂组合物的活性相中的钒与钛的摩尔比大于0.5:1。

公开(公告)号：US20140018550A1

公开(公告)日：2014-01-16

申请号：US13943134

申请日：2013-07-16

Applicant: BASF SE

Inventor： Michael Krämer ,  Jürgen Zühlke ,  Stefan Altwasser ,  Nico Frederik Fischer ,  Frank Rosowski ,  Hans-Martin Allmann

IPC: B01J27/198 ,  C07D307/89

CPC classification number: B01J27/198 ,  B01J23/002 ,  B01J23/22 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0221 ,  B01J2523/00 ,  C07D307/89 ,  B01J2523/15 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55

Abstract: The present invention relates to a catalyst for preparing carboxylic acids and/or carboxylic anhydrides, which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonate having a maximum content of crystalline valentinite of 5% by weight. The present invention further relates to a process for gas-phase oxidation in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst which has a plurality of catalyst zones arranged in series and has been produced using a vanadium antimonate having a maximum content of crystalline valentinite of 5% by weight.

Abstract translation: 本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂，其具有多个串联排列的催化剂区域，并且使用结晶度为5重量％的最大含量的锑酸锑生产。 本发明还涉及一种用于气相氧化的方法，其中包含至少一种烃和分子氧的气流通过催化剂，所述催化剂具有串联排列的多个催化剂区，并且已经使用具有 结晶度的最大含量为5重量％。

公开(公告)号：US20130338378A1

公开(公告)日：2013-12-19

申请号：US13988583

申请日：2011-11-22

Applicant: Andreas Reitzmann ,  Willi Michael Brandstädter ,  Leopold Streifinger ,  Marvin Estenfelder

Inventor： Andreas Reitzmann ,  Willi Michael Brandstädter ,  Leopold Streifinger ,  Marvin Estenfelder

IPC: B01J27/198 ,  C07C67/00 ,  C07C51/215 ,  C07C51/25 ,  C07C45/33 ,  C07D307/60 ,  C07C45/35

CPC classification number: B01J27/198 ,  B01J35/026 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C51/252 ,  C07C67/00 ,  C07D307/60 ,  Y10T428/13

Abstract: The invention relates to a shaped catalyst body for the catalytic conversion of organic and inorganic components in fixed-bed reactors, wherein the shaped catalyst body is formed as cylinder with a base, a cylinder surface, a cylinder axis and at least one continuous opening running parallel to the cylinder axis, and the base of the cylinder has at least four corners.

Abstract translation: 本发明涉及一种用于固定床反应器中有机和无机组分的催化转化的成型催化剂体，其中成形催化剂体形成为具有基体，气缸表面，气缸轴线和至少一个连续的开口运行的气缸 平行于气缸轴线，气缸底部至少有四个角。

公开(公告)号：US08581014B2

公开(公告)日：2013-11-12

申请号：US12637232

申请日：2009-12-14

Applicant: Carlo Perego ,  Franco Baldiraghi ,  Suheil Fares Abdo ,  Terry Louise Marker ,  Luigina Maria Flora Sabatino

Inventor： Carlo Perego ,  Franco Baldiraghi ,  Suheil Fares Abdo ,  Terry Louise Marker ,  Luigina Maria Flora Sabatino

IPC: C07C1/00 ,  C10G1/10

CPC classification number: B01J21/12 ,  B01J23/42 ,  B01J23/60 ,  B01J23/62 ,  B01J23/6482 ,  B01J23/652 ,  B01J23/85 ,  B01J23/883 ,  B01J27/185 ,  B01J27/1856 ,  B01J27/188 ,  B01J27/198 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/036 ,  B01J37/084 ,  C10G2300/1011 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

Abstract: Provided is a process for producing, in a single step, hydrocarbon fractions useful as diesel fuel or as a component of diesel fuel, from a mixture of a biological origin containing esters of fatty acids and, optionally, aliquots of free fatty acids. The process comprises the contemporaneous hydrodeoxygenation and hydroisomerization of the mixture of a biological origin, with the formation of linear and branched paraffins. The process is carried out in the presence of a catalytic composition comprising an amorphous carrier of an acidic nature and a metallic component containing one or more metals of group VIII.

Abstract translation: 本发明提供了一种从含有脂肪酸酯和任选地等分游离脂肪酸的生物来源的混合物中单独制备可用作柴油燃料或作为柴油燃料组分的烃馏分的方法。 该方法包括生物来源的混合物的同时加氢脱氧和加氢异构化，形成直链和支链烷烃。 该方法在包含酸性的无定形载体和含有一种或多种VIII族金属的金属组分的催化组合物存在下进行。

公开(公告)号：US08535628B2

公开(公告)日：2013-09-17

申请号：US13731387

申请日：2012-12-31

Applicant: Yasuyoshi Kato ,  Keiichiro Kai ,  Naomi Imada

Inventor： Yasuyoshi Kato ,  Keiichiro Kai ,  Naomi Imada

IPC: B01D53/56 ,  B01D53/94

CPC classification number: B01J27/199 ,  B01D53/64 ,  B01D53/8628 ,  B01D53/8665 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2257/602 ,  B01J21/063 ,  B01J23/002 ,  B01J27/198 ,  B01J35/06 ,  B01J37/0225 ,  B01J37/0242 ,  B01J37/0244 ,  B01J37/04 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level.The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10: 0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.5, and an exhaust gas purifying method comprising exposing an exhaust gas containing a nitrogen oxide (NOX) and metallic mercury (Hg) to the catalyst in the presence of ammonia as a reducing agent, to thereby perform reduction of NOX contained in the exhaust gas and oxidation of metallic mercury (Hg) contained in the exhaust gas.

Abstract translation: 为了克服常规催化剂的问题，提供一种符合Hg氧化活性和SO2氧化活性要求的排气净化催化剂; 即特别减少SO2氧化百分比的废气净化催化剂，同时保持高水平的Hg氧化百分比。 本发明提供一种废气净化催化剂，其包含含有（i）钛（Ti），（ii）钼（Mo）和/或钨（W），（iii）钒（V）和（iv） 磷（P），其中催化剂含有Ti，Mo和/或W，原子比例为V原子比为85〜97.5:2〜10:0.5〜10，原子比为P /（V与Mo和 /或W）为0.5〜1.5，以及废气净化方法，其包括在氨作为还原剂的存在下将含有氮氧化物（NOX）和金属汞（Hg）的废气暴露于所述催化剂，从而进行还原 的废气中含有的NO x和废气中所含的金属汞（Hg）的氧化。

公开(公告)号：US20130217896A1

公开(公告)日：2013-08-22

申请号：US13770449

申请日：2013-02-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Cornelia Katharina Dobner ,  Frank Rosowski ,  Mark Eichelbaum ,  Annette Trunschke ,  Robert Schloegl

IPC: B01J27/198 ,  C07D307/60

CPC classification number: B01J27/198 ,  B01J23/002 ,  B01J23/22 ,  B01J35/0033 ,  B01J35/023 ,  B01J37/08 ,  C07D307/60

Abstract: A catalyst for the gas phase oxidation of organic hydrocarbons comprises a multielement oxide which comprises at least one transition meal such as vanadium, wherein the catalyst has a charge transport activation energy Ec at a temperature of 375 to 425° C. of less than 0 kJ/mol. The catalyst serves for preparation of maleic anhydride.

Abstract translation: 用于有机烃的气相氧化的催化剂包括多元素氧化物，其包含至少一种过渡膳食，例如钒，其中催化剂在375至425℃的温度下具有小于0kJ的电荷转移活化能Ec / mol。 催化剂用于制备马来酸酐。

公开(公告)号：US20130053599A1

公开(公告)日：2013-02-28

申请号：US13214325

申请日：2011-08-22

Applicant: Heiko Weiner ,  Josefina T. Chapman ,  Alexandra S. Locke ,  Dick Nagaki ,  Craig J. Peterson ,  Mark O. Scates

Inventor： Heiko Weiner ,  Josefina T. Chapman ,  Alexandra S. Locke ,  Dick Nagaki ,  Craig J. Peterson ,  Mark O. Scates

IPC: B01J27/14 ,  C07C67/30 ,  B01J29/04 ,  C07C51/347 ,  B01J27/198 ,  B01J27/182

CPC classification number: B01J27/198 ,  B01J27/14 ,  B01J27/18 ,  B01J35/1004 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/21 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  C07C57/04

Abstract: In one embodiment, the invention is to a catalyst composition comprising titanium, phosphorus, and less than 1 wt. % vanadium. The catalyst composition has a molar ratio of phosphorus to titanium of at least 1.0:1.0.

Abstract translation: 在一个实施方案中，本发明涉及包含钛，磷和小于1wt。 ％钒。 催化剂组合物的磷与钛的摩尔比至少为1.0:1.0。

公开(公告)号：US20120289743A1

公开(公告)日：2012-11-15

申请号：US13105558

申请日：2011-05-11

Applicant: Dick Nagaki ,  Heiko Weiner ,  Josefina T. Chapman ,  Mark O. Scates ,  Alexandra S. Locke ,  Craig J. Peterson

Inventor： Dick Nagaki ,  Heiko Weiner ,  Josefina T. Chapman ,  Mark O. Scates ,  Alexandra S. Locke ,  Craig J. Peterson

IPC: B01J27/198 ,  B01J21/08 ,  C07C51/377 ,  B01J21/06

CPC classification number: B01J23/22 ,  B01J27/198 ,  B01J35/1004 ,  B01J35/1033 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0201 ,  B01J37/08 ,  B01J2523/00 ,  C07C51/353 ,  C07C51/377 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/48 ,  C07C57/04

Abstract: In one embodiment, the invention is to a catalyst composition comprising vanadium, titanium; and at least one oxide additive. The at least one oxide additive is present in an amount of at least 0.1 wt % based on the total weight of the catalyst composition. The molar ratio of titanium to metal additive in an active phase of the catalyst composition is at least 0.05:1.

Abstract translation: 在一个实施方案中，本发明涉及一种催化剂组合物，其包含钒，钛; 和至少一种氧化物添加剂。 基于催化剂组合物的总重量，至少一种氧化物添加剂的存在量为至少0.1重量％。 在催化剂组合物的活性相中钛与金属添加剂的摩尔比为至少0.05:1。

公开(公告)号：US20120071688A1

公开(公告)日：2012-03-22

申请号：US13233560

申请日：2011-09-15

Applicant: Stefanie HERZOG ,  Stefan Altwasser ,  Klaus Joachim Mueller-Engel

Inventor： Stefanie HERZOG ,  Stefan Altwasser ,  Klaus Joachim Mueller-Engel

IPC: C07C57/04 ,  C07C51/36

CPC classification number: C07C45/38 ,  B01J23/002 ,  B01J23/881 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2523/00 ,  C07B2200/05 ,  C07C51/353 ,  C07C51/44 ,  C07C57/04 ,  C07C47/04 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/842

Abstract: A process for preparing acrylic acid from methanol and acetic acid, in which, in a reaction zone A, the methanol is partially oxidized to formaldehyde in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and an acetic acid source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed to acrylic acid under heterogeneous catalysis in a reaction zone B with acetic acid present in reaction gas input mixture B, and unconverted acetic acid still present alongside the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.

Abstract translation: 一种从甲醇和乙酸制备丙烯酸的方法，其中在反应区A中甲醇在异质催化气相反应中部分氧化成甲醛，得到的产物气体混合物A和乙酸源用于 得到包含乙酸和甲醛并且乙酸超过甲醛的反应气体输入混合物B，反应气体输入混合物B中存在的甲醛在反应区B内的非均相催化下醛醇缩合成丙烯酸， 存在于反应气体输入混合物B中的乙酸和从得到的产物气体混合物B中仍然存在于丙烯酸目标产物旁边的未转化的乙酸，将除去的乙酸循环到反应气体输入混合物B的生产中。