公开(公告)号：US10590050B2

公开(公告)日：2020-03-17

申请号：US16337407

申请日：2018-06-25

申请人： Zhejiang Quhua Fluor-Chemistry Co Ltd

发明人： Jiangyong Hong ,  Bo Yang ,  Yan Zhang ,  Guojun Yu ,  Yang Zhao ,  Hao Ouyang ,  Haitao Gong

IPC分类号： C07C17/20 ,  B01J21/04 ,  B01J23/26 ,  C07C17/21 ,  C07C17/358 ,  B01J23/60 ,  B01J23/62 ,  C07C17/383 ,  C07C21/18 ,  B01J23/58

摘要： Disclosed is a method for co-producing various alkenyl halides and hydrofluoroalkanes: cis-1-chloro-3,3,3-trifluoropropene is introduced into a first reactor to carry out an isomerization reaction in the presence of a first catalyst, and the reaction product is rectified to obtain a product trans-1-chloro-3,3,3-trifluoropropene; and 30-70 wt % of trans-1-chloro-3,3,3-trifluoropropene and hydrogen fluoride are mixed and then introduced into a second reactor to carry out a reaction in the presence of a second catalyst to obtain a second reactor reaction product; the second reactor reaction product is introduced into a phase separator for separation, and the obtained organic phase is rectified to obtain the products trans-1,3,3,3-tetrafluoropropene, cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane. The invention has the advantages of simple process, high efficiency, high operation flexibility, less investment and low energy consumption.

公开(公告)号：US20180215689A1

公开(公告)日：2018-08-02

申请号：US15578405

申请日：2016-05-27

申请人： Central Glass Company, Limited

发明人： Takamasa KITAMOTO ,  Satoru OKAMOTO ,  Masahiko TANI ,  Masatomi KANAI ,  Kohei SUMIDA

IPC分类号： C07C17/358 ,  B01J27/135 ,  B01J27/125 ,  B01J37/26

摘要： A method for isomerizing a hydrohalofluoroolefin isomer to produce a corresponding hydrohalofluoroolefin isomer includes a step contacting a composition that contains at least a hydrohalofluoroolefin isomer and that has been adjusted to 100 ppm or lower in moisture concentration, with a catalyst in a gas phase, thereby obtaining a product. This method makes it possible to suppress the catalyst performance lowering.

公开(公告)号：US09878969B2

公开(公告)日：2018-01-30

申请号：US15535220

申请日：2015-02-05

申请人： XI'AN MODERN CHEMISTRY RESEARCH INSTITUTE

发明人： Jian Lv ,  Hui Ma ,  Yujie Gu ,  Bo Wang ,  Yue Qin ,  Zhenhua Zhang ,  Zhijun Hao ,  Chunying Li ,  Fengxian Li ,  Jing Lv ,  Yanbo Bai

IPC分类号： C07C17/20 ,  C07C21/18 ,  C07C17/358 ,  B01J23/00

CPC分类号： C07C17/20 ,  B01D2255/2045 ,  B01D2255/2047 ,  B01D2255/20715 ,  B01D2255/20723 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01J23/00 ,  B01J23/002 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/8472 ,  B01J23/8892 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  B01J37/26 ,  B01J2523/00 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/35 ,  C07C17/358 ,  C07C21/18 ,  C07C19/10 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/845 ,  B01J2523/22 ,  B01J2523/23 ,  B01J2523/48 ,  B01J2523/847 ,  B01J2523/3706 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/36 ,  B01J2523/25 ,  B01J2523/17 ,  B01J2523/55

摘要： Disclosed is a process for the preparation of 1,3,3,3-tetrafluoropropene, comprising: (a) a compound having the formula CF3-xClxCHClCHF2-yCly and in the presence of a compound catalyst, undergoes, through n serially-connected reactors, gas-phase fluorination with hydrogen fluoride, producing 1,2,3-trichloro-1,1,3-trifluoropropane, and 1,2-dichloro-1,1,3,3-tetrafluoropropane; in said formula, x=1, 2 or 3; y=1 or 2, and 3≦x+y≦5; (b) 1,2,3-trichloro-1,1,3-trifluoropropane, and 1,2-dichloro-1,1,3,3-tetrafluoropropane undergo, in the presence of a dehalogenation catalyst, gas-phase dehalogenation with hydrogen, producing 3-chloro-1,3,3-trifluoropropene, and 1,1,3,3-tetrafluoropropene; (c) 3-chloro-1,3,3-trifluoropropene and 1,1,3,3-tetrafluoropropene undergo, in the presence of a fluorination catalyst, gas-phase fluorination with hydrogen fluoride, producing 1,3,3,3-tetrafluoropropene. The present invention is primarily used to produce 1,3,3,3-tetrafluoropropene.

公开(公告)号：US09643903B2

公开(公告)日：2017-05-09

申请号：US14195893

申请日：2014-03-04

申请人： Honeywell International Inc.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh Sung Tung

IPC分类号： C07C17/20 ,  B01D3/00 ,  C01B7/07 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  C07C21/18

CPC分类号： C07C17/20 ,  B01D3/009 ,  C01B7/0706 ,  C01B7/0712 ,  C07C17/206 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  C07C21/18 ,  Y02P20/582

摘要： Disclosed is process for the production of (E) 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) by conducting a continuous reaction without the use of a catalyst. Also disclosed is an integrated system for producing hydrofluoro olefins, particularly 1233zd(E). The manufacturing process includes six major unit operations: (1) a fluorination reaction of HCC-240fa (in continuous or semi-batch mode) using HF with simultaneous removal of by-product HCl and the product 1233zd(E); (2) recycle of unreacted HCC-240fa and HF together with under-fluorinated by-products back to (1); (3) separation and purification of by-product HCl; (4) separation of excess HF back to (1); (5) purification of final product, 1233zd(E); and (6) isomerization of by-product 1233zd(Z) to 1233zd(E) to maximize the process yield.

公开(公告)号：US20160185692A1

公开(公告)日：2016-06-30

申请号：US14886628

申请日：2015-10-19

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

摘要翻译： 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US09255046B2

公开(公告)日：2016-02-09

申请号：US12125045

申请日：2008-05-21

申请人： Stephen A. Cottrell ,  Hsueh Sung Tung ,  Haiyou Wang ,  Yuon Chiu ,  Gustavo Cerri

发明人： Stephen A. Cottrell ,  Hsueh Sung Tung ,  Haiyou Wang ,  Yuon Chiu ,  Gustavo Cerri

IPC分类号： C07C17/00 ,  C07C19/08 ,  C07C21/18 ,  C07C23/00 ,  C07C25/13 ,  C07C17/25 ,  C07C17/358

CPC分类号： C07C17/25 ,  C07C17/358 ,  C07C21/18

摘要： Disclosed is a method for forming HFO-1234ze, and for forming compositions comprising HFO-1234ze, by (a) converting, preferably by dehydrofluorination, pentafluorpropane (HFC-245), preferably 1,1,1,3,3-pentafluorpropane (HFC-245fa), preferably by contact with a caustic solution, to a reaction product comprising cis-HFO-1234ze and trans-HFO-1234ze; and (b) contacting at least a portion, preferably substantially portion, and in certain embodiments substantially all of said reaction product with at least one isomerization catalyst to convert at least a portion, and preferably at least a substantial portion, of cis-HFO-1234ze in said reaction product to trans-HFO-1234ze.

摘要翻译： 公开了形成HFO-1234ze的方法，以及用于形成包含HFO-1234ze的组合物的方法，通过（a）优选通过脱氟化氢转化五氟丙烷（HFC-245），优选1,1,1,3,3-五氟丙烷（HFC -245fa），优选通过与苛性碱溶液接触，加入到包含顺-HFO-1234ze和反-HFO-1234ze的反应产物中; 并且（b）使至少一部分，优选基本上部分，在某些实施方案中使基本上所有的所述反应产物与至少一种异构化催化剂接触，以将至少一部分，优选至少大部分的顺-HFO- 1234ze在所述反应产物中以反式HFO-1234ze。

公开(公告)号：US20160023971A1

公开(公告)日：2016-01-28

申请号：US14876445

申请日：2015-10-06

申请人： MEXICHEM AMANCO HOLDING S.A. DE C.V.

发明人： Andrew P. Sharratt ,  LESLIE RICHARD SEDDON

IPC分类号： C07C17/25 ,  C09K5/04 ,  C07C17/358 ,  C07C21/18 ,  C07C17/20

CPC分类号： C07C17/25 ,  B01J23/06 ,  B01J23/26 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/04 ,  C07C17/087 ,  C07C17/18 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/275 ,  C07C17/358 ,  C07C21/18 ,  C07C45/63 ,  C09K5/045 ,  C09K2205/126 ,  C07C19/10 ,  C07C19/01 ,  C07C19/08 ,  C07C49/16

摘要： The invention relates to a process for preparing a C3-6 (hydro)fluoroalkene comprising dehydrohalogenating a C3-6 hydro(halo)fluoroalkane in the presence of a zinc/chromia catalyst, wherein the C3-6 (hydro)fluoroalkene produced is isomerised in the presence of the zinc/chromia catalyst.

摘要翻译： 本发明涉及一种制备C3-6（氢）氟代烯烃的方法，该方法包括在锌/氧化铬催化剂存在下将C3-6氢（卤代）氟代烷烃脱卤化氢，其中制备的C 3-6（氢）氟代烯烃异构化为 存在锌/氧化铬催化剂。

公开(公告)号：US09162947B2

公开(公告)日：2015-10-20

申请号：US14204637

申请日：2014-03-11

申请人： Honeywell International Inc.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C21/02 ,  C07C21/18

CPC分类号： C07C17/358 ,  C07B35/08 ,  C07B2200/09 ,  C07C5/22 ,  C07C17/007 ,  C07C21/18

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

摘要翻译： 公开了将（E）-1-氯-3,3,3-三氟丙烯转化为（Z）-1-氯-3,3,3-三氟丙烯的高温异构化反应方法。 在本发明的某些方面，这种方法包括使进料流与加热的表面接触，其中进料流包含（E）-1-氯-3,3,3-三氟丙烯或（E）-1-氯 -3,3,3-三氟丙烯与（Z）-1-氯-3,3,3-三氟丙烯。 所得产物流包含（Z）-1-氯-3,3,3-三氟丙烯和（E）-1-氯-3,3,3-三氟丙烯，其中（Z）异构体与（E）异构体 在产品流中比进料流高。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US20150099907A1

公开(公告)日：2015-04-09

申请号：US14564606

申请日：2014-12-09

申请人： CENTRAL GLASS COMPANY, LIMITED

发明人： Hideaki IMURA ,  Satoru OKAMOTO ,  Masamune OKAMOTO ,  Naoto TAKADA ,  Fuyuhiko SAKYU

IPC分类号： C07C17/358

CPC分类号： C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C11D7/30 ,  C11D7/5018 ,  C07C21/18

摘要： A method for producing a desired isomer of 1-chloro-3,3,3-trifluoro-1-propene or a desired isomer of 1,3,3,3-tetrafluoropropene at a high conversion ratio with no use of a solid catalyst is provided. Since no solid catalyst is used, a desired isomer of 1-chloro-3,3,3-trifluoro-1-propene and a desired isomer of 1,3,3,3-tetrafluoropropene can be stably obtained with no undesired possibility that the solid catalyst is deteriorated due to coking or the like caused as a result of long-time use thereof.

摘要翻译： 不使用固体催化剂以高转化率生产所需异构体的1-氯-3,3,3-三氟-1-丙烯或所需异构体的1,3,3,3-四氟丙烯的方法， 提供。 由于不使用固体催化剂，因此可以稳定地获得所需的1-氯-3,3,3-三氟-1-丙烯异构体和所需的1,3,3,3-四氟丙烯异构体，而不存在不希望的可能性， 固体催化剂由于长时间使用引起的焦化等而劣化。

公开(公告)号：US08987534B2

公开(公告)日：2015-03-24

申请号：US14167150

申请日：2014-01-29

申请人： Arkema Inc.

发明人： Maher Y. Elsheikh ,  Philippe Bonnet ,  John A. Wismer ,  Sri R. Seshadri

IPC分类号： C07C19/08 ,  C07C17/38 ,  C07C17/20 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383

CPC分类号： C07C17/38 ,  C07B2200/09 ,  C07C17/206 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  C07C21/18

摘要： The invention also relates a process for the manufacture of trans 1-chloro3,3,3-trifluoropropene. The process comprises an isomerization step from cis 1233zd to trans 1233zd.

摘要翻译： 本发明还涉及制备反式1-氯-3,3,3-三氟丙烯的方法。 该方法包括从顺式1233zd到反式1233zd的异构化步骤。