Abstract:
Ammonia off-gas, which is separated and recovered by an ammonia recovery device from gasification gas produced in a gasification furnace in a two-column gasification system, is injected as reducing agent for denitration into an inlet of a cyclone for separation of bed material heated in a combustion furnace from combustion exhaust gas and for returning the bed material to the gasification furnace. The ammonia off-gas is contacted with the high-temperatured combustion exhaust gas to reduce and remove NOx through non-catalytic decomposition. Any excess of the ammonia off-gas is distributed for burning to primary air to the combustion furnace.
Abstract:
The present invention relates to a process and system for gasifying biomass or other carbonaceous feedstocks in an indirectly heated gasifier and provides a method for the elimination of condensable organic materials (tars) from the resulting product gas with an integrated tar removal step. More specifically, this tar removal step utilizes the circulating heat carrier to crack the organics and produce additional product gas. As a benefit of the above process, and because the heat carrier circulates through alternating steam and oxidizing zones in the process, deactivation of the cracking reactions is eliminated.
Abstract:
Provided are a fluidized-bed combustion furnace 1, a separator 8 for separation into bed material 11 and an exhaust gas, a fluidized-bed gasification furnace 40 into which the bed material 11 is introduced through a downcomer 46 and into which raw material is introduced, a circulation passage for circulating char and the bed material 11 to the combustion furnace 1, a dispersion section 43 extending along a width of a bed-material-introduction-side wall 41 of the gasification furnace 40 to receive the bed material 11 from the downcomer, fluidizing-gas introduction means 47 for blowing fluidizing gas into the dispersion section 43 to fluidize the bed material 11 in the section 43, and a supply section 48 for supplying the bed material 11 in the dispersion section 43 to the fluidized-bed gasification furnace 40 substantially evenly throughout the width on the bed-material-introduction side.
Abstract:
Proposed are a system and method for wasteless pyrolytic processing and complete utilization of municipal and domestic wastes. The wastes are sequentially passed through units of sorting, grinding, drying, accumulating, and sending to a pyrolysis reactor for pyrolytic treatment. The syngas produced in the pyrolysis is passed through dry cleaning, dust catching, a first wet cleaning with water, a second wet cleaning with alkali, and a floatation unit for separation of water which is purified to an extent sufficient for technical use. The purified syngas is also passed through an absorber and is then used as a working medium for a power generation unit such as a gas turbine co-generator that generates electricity. Solid products of the pyrolysis reaction, such as coke, are returned to the reactor for afterburning, and the heat of the reaction can be utilized in a dryer, or the like.
Abstract:
Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.
Abstract:
A small scale integrated waste processing system for the thermal destructions of waste. The system comprises a compactor (12) for densifying waste and expressing air, a pyrolyzer (13) to receive waste delivered from the compactor, a gasifier (14) with an ash vessel (23) that receives dried waste, and an oxidizer (15) receiving gas from the gasifier to be combusted. Heat energy from the oxidizer can be routed back to the pyrolyzer.
Abstract:
Proposed are a system and method for wasteless pyrolytic processing and complete utilization of municipal and domestic wastes. The wastes are sequentially passed through units of sorting, grinding, drying, accumulating, and sending to a pyrolysis reactor for pyrolytic treatment. The syngas produced in the pyrolysis is passed through dry cleaning, dust catching, a first wet cleaning with water, a second wet cleaning with alkali, and a floatation unit for separation of water which is purified to an extent sufficient for technical use. The purified syngas is also passed through an absorber and is then used as a working medium for a power generation unit such as a gas turbine co-generator that generates electricity. Solid products of the pyrolysis reaction, such as coke, are returned to the reactor for afterburning, and the heat of the reaction can be utilized in a dryer, or the like.
Abstract:
Disclosed are flexible hybrid conversion systems that can be used with a wide spectrum of resources and feedstock. The disclosed systems can be sufficiently versatile to provide many added value products including clean energy, synthetic fuels and chemical products. Processes and system disclosed herein can produce, for example, shaft power and/or electricity from the expansion of species change of hot, hydrogen-laden syngas produced by gasification or steam reforming of inferior feedstock such as coal, bitumen, tar from sands and wastes, including biomass, municipal solid waste (MSW) sewage sludge and certain industrial wastes. This disclosure also teaches innovative system thermal integration methods of endothermic and exothermic processes and reaction enhancement approaches for the economic, clean and flexible production of synthetic gaseous and liquid fuels as well as chemicals.
Abstract:
A municipal or like refuse is crushing, mixing with crushed limestone, dry up in two stages—by hot air and by part of solid products of pyrolysis which other part goes on washing out and filtration. Pyrolysis is carried out in two stages—due to heat of the specified part of solid products of pyrolysis and simultaneous neutralization of allocated hydrogen chloride by limestone with reception of calcium chloride, and then due to heat of final chimney gases of the combustion chamber, where in three stages the washed solid products of pyrolysis preliminary drained by a part of combustion chamber slag are burnt together with liquid and gaseous products of pyrolysis. Gas allocated at pyrolysis condense and divide on organic, which is liquid fuel and water phases. Air after a dryer moves to blowing away of light organic substances from the specified water phase, is heated up due to heat of slag and moves in combustion chamber. Washing water goes on allocation of salts of heavy metals and calcium chloride, and slag after molding of a concrete mixture goes to the chamber of thermohumid processing of the slag concrete by a part of damp chimney gases after drying calcium chloride, other part of gases moves to manufacture of liquid carbon dioxide.
Abstract:
The present invention provides a process for the treatment of waste, the process comprising a gasification step comprising treating the waste in a gasification unit in the presence of oxygen and steam to produce an offgas and a char, and a plasma treatment step comprising subjecting the offgas and the char to a plasma treatment in a plasma treatment unit in the presence of oxygen and steam. An apparatus for carrying out the process is also provided.