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    Electrolytic composition with polymer base for electrochemical generator
    11.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 有权
    电化学发生器用电解质组合物

    公开(公告)号：US06280882B1

    公开(公告)日：2001-08-28

    申请号：US09142055

    申请日：1998-12-14

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M614

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂电解组合物包括由聚醚 和至少第二聚合物基质，宏观上分离的，以及至少一种碱性盐以及极性非质子传递溶剂。聚合物基质能够被至少一种极性非质子传递溶剂溶胀。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

    Polyionic polymeric compounds, process of preparing same and use thereof as photoinitiators
    12.
    发明授权
    Polyionic polymeric compounds, process of preparing same and use thereof as photoinitiators 失效

    公开(公告)号：US6008267A

    公开(公告)日：1999-12-28

    申请号：US943590

    申请日：1997-10-03

    申请人： Alain Vallee ,  Michel Armand ,  Xavier Ollivrin ,  Christophe Michot

    发明人： Alain Vallee ,  Michel Armand ,  Xavier Ollivrin ,  Christophe Michot

    IPC分类号： C07C19/07 ,  C07C245/14 ,  C07C307/02 ,  C07C311/48 ,  C07C317/02 ,  C07C381/12 ,  C08F2/46 ,  C08F4/42 ,  C08F12/02 ,  C08F112/14 ,  C08G59/68 ,  C08G75/02 ,  C08G77/08 ,  C08G79/00 ,  C09K3/00 ,  G03F7/00 ,  G03F7/004

    CPC分类号： C08F2/50 ,  C07C307/02 ,  C07C309/80 ,  C07C311/48 ,  C07C381/12 ,  C08F8/44 ,  C08G77/392 ,  C08G77/398 ,  G03F7/029 ,  G03F7/039

    摘要： Polymer or oligomer ionic compound made of a polycationic part (A.sup.+).sub.p comprising a plurality of onium units and a sufficient number of anions X.sup.- to provide electrical neutrality to the compound, characterized in thatthe onium units are selected from the group consisting of biaryliodonium, arylsulfonium, arylacylsulfonium, diazonium, organometallic cations comprising a transition metal which is complexed by at least one unsaturated cycle comprising 4 to 12 carbon atoms;X.sup.- is an imide anion [R.sub.F SO.sub.2 NSO.sub.2 R'.sub.F ].sup.- or a methylide anion [R.sub.F SO.sub.2 C(Q)SO.sub.2 R'.sub.F ].sup.- in which:1) Q represents:H--, Cl--, F--, Br--or CN--;an alkyl radical having 1 to 30 carbon atoms;an aryl, alkylaryl or arylakyl radical having 6 to 30 carbon atoms;a group R".sub.F or a group R".sub.F SO.sub.2 ;2) R.sub.F and R'.sub.F, as well as R".sub.F possibly when X.sup.- is a methylide anion, are independently selected from the group consisting of fluorine, perhaloalkyl groups having 1 to 30 carbon atoms, (perhaloalkyl)alkyloxy groups, perhalogenated cycloaliphatic groups having 3 to 30 carbon atoms possibly containing hetero atoms selected from O and N, and/or possibly comprising at least one perhaloalkyl chain, the perhalogenated aryl having 6 to 30 carbon atoms; or3) R.sub.F and R'.sub.F together form a bivalent radical constituting a cycle respectively with group --SO.sub.2 --N--SO.sub.2 -- or with group --SO.sub.2 --C(Q)--SO.sub.2 --, or when X.sup.- is a methylide anion, R".sub.F constitutes with one of the radicals R.sub.F or R'.sub.F a bivalent radical constituting a cycle respectively with group --SO.sub.2 --C--SO.sub.2 -- or group --SO.sub.2 --C--, said bivalent radical being selected from perfluorinated alkylene radicals having 2 to 12 carbon atoms, the third radical which is possibly present being selected from the monovalent radicals mentioned above in 2);4) p represents the number of onium units.These compounds are useful as photoinitiators for cationic polymerization or cross-linking of monomers or for the modification of polymers for example when they are used as photoresists. The preparation of these compounds is also disclosed.

    Process for making electrodes for lithium based electrochemical cells
    14.
    发明授权
    Process for making electrodes for lithium based electrochemical cells 有权
    锂基电化学电池制作电极的工艺

    公开(公告)号：US08420158B2

    公开(公告)日：2013-04-16

    申请号：US12399648

    申请日：2009-03-06

    申请人： Patrick Leblanc ,  Frederic Cotton ,  Dave Lessard ,  Alain Vallee

    发明人： Patrick Leblanc ,  Frederic Cotton ,  Dave Lessard ,  Alain Vallee

    IPC分类号： B05D5/12

    CPC分类号： H01M4/139 ,  H01M4/0404

    摘要： A process for making an electrode sheet for lithium electrochemical cells is disclosed. The process comprises the steps of: a) admixing a polyether polymer or copolymer soluble in water, at least one lithium salt, at least one electrochemically active material, water and an organic solvent miscible with water in a water/organic solvent ratio of a maximum of 50% organic solvent by volume to form a water-based solution/suspension containing by weight at least 20% active electrode material, at least 5% of a polyether polymer or copolymer, and at least 1.5% lithium salt; b) coating the water-based solution/suspension in the form of an electrode thin film onto an electrode support; and, c) drying the electrode thin film to obtain an electrode thin sheet having less than 1000 ppm of residual water.

    摘要翻译： 公开了一种制造锂电池的电极片的方法。 该方法包括以下步骤：a）将可溶于水的聚醚聚合物或共聚物，至少一种锂盐，至少一种电化学活性材料，水和与水混合的有机溶剂与水/有机溶剂的最大比例混合， 的50％有机溶剂，以形成含有至少20％活性电极材料，至少5％的聚醚聚合物或共聚物和至少1.5％的锂盐的水基溶液/悬浮液; b）将电极薄膜形式的水性溶液/悬浮液涂布到电极载体上; c）干燥电极薄膜，得到残留水小于1000ppm的电极薄片。

    Electrolytic composition with polymer base for electrochemical generator
    18.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 失效
    电化学发生器用电解质组合物

    公开(公告)号：US06806002B2

    公开(公告)日：2004-10-19

    申请号：US09878356

    申请日：2001-06-12

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M462

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂。 电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质，以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种 的极性非质子溶剂。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。