摘要:
The invention proposes a method for producing glass ceramics which is particularly well suited as light conversion material, especially for down conversion. One initially produces a starting glass, containing (on an oxide basis) 5-50% by weight of SiO2, 5-50% by weight of Al2O3 and 10-80% by weight of at least one oxide selected from the from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well as 0.1-30% by weight of at least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Thereafter, the material is heated up for ceramization at a heating rate of at least 100 K/min to a temperature in the range of between 1000° C. to 1400° C. until crystallites are formed that contain a garnet phase. Thereafter, the material is cooled down to room temperature. Alternatively, controlled cooling-down from the molten state is possible.
摘要翻译:本发明提出一种特别适合作为光转换材料的玻璃陶瓷的制造方法,特别是用于下转换。 最初产生起始玻璃,其含有5-50重量%的SiO 2,5-50重量%的Al 2 O 3和10-80重量%的至少一种氧化物的起始玻璃,所述氧化物选自由Y 2 O 3 ,Lu 2 O 3,Sc 2 O 3,Gd 2 O 3,Yb 2 O 3,Ce 2 O 3,以及选自B 2 O 3,Th 2 O 3的至少一种氧化物和除了Lu 2 O 3,Gd 2 O 3,Yb 2 O 3,Ce 2 O 3以外的镧系元素的氧化物的至少一种氧化物。 此后,将材料以至少100K /分钟的加热速率加热至陶瓷化,至1000℃至1400℃的温度,直至形成含有石榴石相的微晶。 此后,将材料冷却至室温。 或者,可以从熔融状态控制冷却。
摘要:
A method for making glass ceramic composite structures, wherein a first and at least a second glass component, with an intermediate layer of a joining solder consisting of glass placed between them, are assembled to form a raw composite structure, wherein the joining solder has a radiation absorption capacity higher than the components to be joined, and wherein the raw composite structure is irradiated with energy, for example IR energy, at least in the area of the joining solder until the joining solder has softened sufficiently to bond together the components and the joining solder to produce a composite glassy structure. Thereafter a ceramization treatment is performed.
摘要:
A method of hot forming of at least a part of an article is provided. The article includes a material selected from the group consisting of transparent and semitransparent materials. The method includes semi-homogeneously heating at least a part of the article by radiation and forming the heated part of the article.
摘要:
The process of making the glass-ceramic includes ceramicizing a starting glass at a heating or cooling rate during the ceramicization of at least 10 K/min, so that the glass-ceramic contains at least 50% by volume of ferroelectric crystallites with a maximum diameter of from 20 to 100 nm and not more than 10% by volume of nonferroelectric crystallitesis. The glass ceramic produced by the process contains no pores or not more than 0.01% by volume of the pores and a value of e′·V2max of the glass-ceramic is at least 20 (MV/cm)2, wherein e′ is the dielectric constant at 1 kHz and Vmax is the breakdown voltage per unit thickness. The ferroelectric crystallites preferably have a perovskite structure and are composed of substantially pure or doped BaTiO3 and/or BaTi2O5.
摘要:
The invention proposes a method for producing glass ceramics which is particularly well suited as light conversion material, especially for down conversion. One initially produces a starting glass, containing (on an oxide basis) 5-50% by weight of SiO2, 5-50 % by weight of Al2O3 and 10-80% by weight of at least one oxide selected from the from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well as 0.1-30% by weight of at least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Thereafter, the material is heated up for ceramization at a heating rate of at least 100 K/min to a temperature in the range of between 1000° C. to 1400° C. until crystallites are formed that contain a garnet phase. Thereafter, the material is cooled down to room temperature. Alternatively, controlled cooling-down from the molten state is possible.
摘要翻译:本发明提出一种特别适合作为光转换材料的玻璃陶瓷的制造方法,特别是用于下转换。 最初产生起始玻璃,其含有(以氧化物为基准)5-50重量%的SiO 2,5-50重量%的Al 2 O 3 > 3重量%和10-80重量%的至少一种氧化物,其选自Y 2 N 3 O 3,Lu 2 3 sub> 3 sub> 3,3 3> 3 SUB> 3 SUB> 3 SUB> ,Yb 2 O 3,Ce 2 O 3,以及0.1-30重量%的 选自由B 2 O 3 O 3,Th 2 O 3 3形成的基团中的至少一种氧化物和氧化物 的镧系元素,除了Lu 2 O 3 3,Gd 2 O 3 N 3,Yb 2, 3个O 3,3个O 3,3个O 3。 此后,将材料以至少100K /分钟的加热速率加热至陶瓷化,至1000℃至1400℃的温度,直至形成含有石榴石相的微晶。 此后,将材料冷却至室温。 或者,可以从熔融状态控制冷却。
摘要:
The invention provides a method for producing a glass ceramic comprising the steps of melting a starting glass that is free from alkali, except for incidental contamination, and that contains at least one garnet-forming agent and at least one oxide of a lanthanoid; grinding the starting glass to produce a glass frit; molding by pressing and sintering the glass frit until at least one garnet phase containing lanthanoids is formed. A glass ceramic produced in this way may contain 5-50 % by weight of SiO2, 5-50 % by weight of Al2O3 and 10-80 % by weight of at least one oxide selected from the group formed by Y2O3, Lu2O3, Sc2O3, Gd2O3, Yb2O3, Ce2O3, as well least one oxide selected from the group formed by B2O3, Th2O3, and oxides of the lanthanoids, except Lu2O3, Gd2O3, Yb2O3, Ce2O3. Such a glass ceramic is suited especially for down conversion of excitation radiation in the blue and in the UV region of the spectrum.
摘要翻译:本发明提供了一种制备玻璃陶瓷的方法,包括以下步骤:熔化除了偶然污染之外不含碱的起始玻璃,并含有至少一种石榴石形成剂和至少一种镧系元素氧化物; 研磨起始玻璃以生产玻璃料; 通过压制和烧结玻璃料成型至含有镧系元素的至少一个石榴石相。 以这种方式制造的玻璃陶瓷可以含有5-50重量%的SiO 2,5-50重量%的Al 2 O 3 3 / >和10-80重量%的至少一种氧化物,其选自由Y 2 O 3 N 2,O 2 O 3,N 2 O 3, > 3 sub> 3,3 3>,3 3> 3, 以及至少一种选自由B 2 O 3 O 3所形成的基团的氧化物, anthan anthan anthan anthan <<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<<< 3个,3个,3个,3个,3个,3个,3个,3个,3个,3个, 2 O> 3。 这种玻璃陶瓷特别适用于在光谱的蓝色和紫外区域的激发辐射的下变换。
摘要:
The invention relates to a method of producing glass-ceramic parts and/or glass parts by deformation of a glass-ceramic blank and/or glass blank. The invention is characterized in that forming is carried out using infrared radiation.
摘要:
A method of hot forming of at least a part of an article is provided. The article includes a material selected from the group consisting of transparent and semitransparent materials. The method includes semi-homogeneously heating at least a part of the article by radiation and forming the heated part of the article.
摘要:
Pusher centrifuge having a pusher plate and a guiding wall for the mixture to be fed onto the centrifuge drum, with a free flow space between the pusher plate and the guiding wall; the improvement that the surfaces of the pusher plate and guiding wall facing the mixture to be fed extend at least substantially perpendicular to the axis of the centrifuge drum or extend away from the axis of the drum in the radial area which extends from the outer surface of the inlet pipe to the inner surface of the layer of mixture lying on the drum.
摘要:
Processes for producing shaped glass articles with a defined geometry are provided. In some embodiment, the process includes arranging a glass pane on a mould, heating the glass pane by infrared radiation, deforming the heated glass pane over the mould by gravity, negative pressure, and/or positive pressure, and cooling the shaped glass pane to obtain the shaped glass article with a defined geometry.