公开(公告)号：US20070102281A1

公开(公告)日：2007-05-10

申请号：US11271580

申请日：2005-11-10

Applicant: Yuon Chiu ,  Daniel Merkel ,  Hsuehsung Tung

Inventor： Yuon Chiu ,  Daniel Merkel ,  Hsuehsung Tung

IPC: C07C17/00

CPC classification number: C07C17/38 ,  C07C17/395 ,  C07C19/08

Abstract: A continuous, vapor phase method for purifying a crude mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds, the process comprising: a) providing a photochlorinator vessel comprising: 1) a UV lamp unit comprising a UV lamp located in a transparent inner well, the transparent inner well being located within a transparent outer well, the outer well being provided with material for cooling walls of the inner and outer wells; the inner well and the outer well defining separate chambers isolated from each other; and 2) a reaction vessel into which the UV lamp unit has been inserted; b) introducing into the reaction vessel a gaseous mixture of Cl2 and a distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated fluorocarbon compounds; c) reacting, in the gaseous state and in the presence of UV light from the photochlorinator, the mixture with Cl2 with the distillation inseparable mixture of 1,1,1,3,3,3-hexafluoropropane and one or more unsaturated compounds to saturate unsaturated fluorocarbons into a reacted mixture, and d) separating a purified 1,1,1,3,3,3-hexafluoropropane product containing less than 1000 ppm, most preferably less than 100 ppm unsaturated fluorocarbons.

Abstract translation: 一种用于纯化1,1,1,3,3,3-六氟丙烷和一种或多种不饱和碳氟化合物的粗混合物的连续气相法，该方法包括：a）提供光氯化器容器，其包括：1）UV灯 该单元包括位于透明内部井中的UV灯，所述透明内部井位于透明外部井内，所述外部井具有用于冷却所述内部和外部井的壁的材料; 所述内部井和所述外部井定义分离的彼此隔离的室; 和2）UV灯单元插入其中的反应容器; b）向反应容器中加入Cl 2 Cl 2与1,1,1,3,3,3-六氟丙烷与一种或多种不饱和碳氟化合物的蒸馏不可分离混合物的气态混合物; c）以气态和在来自光氯提取器的紫外光存在下，将Cl 2与Cl 2的混合物与1,1,1,3,3,3-六氟丙烷的蒸馏不可分离的混合物反应 和一种或多种不饱和化合物使不饱和碳氟化合物饱和到反应混合物中，以及d）分离含有小于1000ppm，最优选小于100ppm的不饱和碳氟化合物的纯化1,1,1,3,3,3-六氟丙烷产物。

公开(公告)号：US20050222472A1

公开(公告)日：2005-10-06

申请号：US10816447

申请日：2004-04-01

Applicant: Daniel Merkel ,  Hsuehsung Tung ,  Ian Shankland

Inventor： Daniel Merkel ,  Hsuehsung Tung ,  Ian Shankland

IPC: B01J21/18 ,  B01J23/20 ,  B01J23/22 ,  B01J27/08 ,  B01J27/125 ,  B01J27/135 ,  B01J37/26 ,  C07C17/20 ,  C07C17/21 ,  C07C19/08 ,  C07C17/08

CPC classification number: B01J27/125 ,  B01J21/18 ,  B01J27/08 ,  B01J27/135 ,  B01J37/26 ,  C07C17/206 ,  C07C17/208 ,  C07C17/21 ,  C07C19/08 ,  Y02P20/582

Abstract: A process for the production of difluoromethane (HFC-32), 1,1,1-trifluoroethane (HFC-143a) and 1,1-difluoroethane (HFC-152a). In the process the following steps are employed: (a) providing a reaction vessel, (b) providing in the reaction vessel activated carbon impregnated with a strong Lewis acid fluorination catalys selected from halides of As, Sb, Al, TI, In, V, Nb, Ta, Ti, Zr and Hf, (c) activating the catalyst by passing through the activated carbon impregnated with a strong Lewis acid fluorination catalyst anhydrous hydrogen fluoride gas and chlorine gas, (d) contacting, in a vapor state in the reaction vessel containing the activated catalyst, hydrogen fluoride and one or more halogenated hydrocarbons selected from chlorofluoromethane, dichloromethane, 1,1,1-trichloroethane, vinyl chloride, 1,1-dichloroethylene, 1.2-dichloroethylene, 1,2-dichloroethane, and 1,1-dichloroethane for a time and at a temperature to produce a product stream comprising hydrofluorocarbon product(s) corresponding to the chlorinated hydrocarbon reactant(s), and one or more of hydrogen chloride, unreactacted chlorinated hydrocarbon reactant(s), under-fluorinated intermediates, and unreacted hydrogen fluoride, and (e) separating the hydrofluorocarbon product(s) from the product stream.

Abstract translation: 制备二氟甲烷（HFC-32），1,1,1-三氟乙烷（HFC-143a）和1,1-二氟乙烷（HFC-152a）的方法。 在该过程中，采用以下步骤：（a）提供反应容器，（b）在反应容器中提供浸渍有选自As，Sb，Al，TI，In，V ，Nb，Ta，Ti，Zr和Hf，（c）通过浸渍有强路易斯酸氟化催化剂的无水氟化氢气体和氯气的活性炭活化催化剂，（d）以蒸气状态在 含有活化催化剂的反应容器，氟化氢和一种或多种选自氯氟甲烷，二氯甲烷，1,1,1-三氯乙烷，氯乙烯，1,1-二氯乙烯，1,2-二氯乙烯，1,2-二氯乙烷和1 ，1-二氯乙烷，并在一定温度下产生包含对应于氯代烃反应物的氢氟烃产物的产物流，以及一种或多种氯化氢，未反应的氯化烃 反应物，非氟化中间体和未反应的氟化氢，和（e）从产物流中分离氢氟烃产物。

公开(公告)号：US20050090698A1

公开(公告)日：2005-04-28

申请号：US10694272

申请日：2003-10-27

Applicant: Daniel Merkel ,  Rajiv Singh ,  Hsueh Tung

Inventor： Daniel Merkel ,  Rajiv Singh ,  Hsueh Tung

IPC: C07C17/20 ,  C07C17/25 ,  C07C21/18

CPC classification number: C07C21/18 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10 ,  C07C19/08

Abstract: Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.

Abstract translation: 用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法，其中氟丙烯具有式CF 3 C 1 -C 6 N N H P H，其中X Y独立地为氢或选自氟，氯，溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数，条件是（N + P）= 2。

公开(公告)号：US08217208B2

公开(公告)日：2012-07-10

申请号：US12633420

申请日：2009-12-08

Applicant: Ryan Hulse ,  Rajiv R. Singh ,  Konstantin A. Pokrovski ,  Hsueh Sung Tung ,  Daniel Merkel ,  Haiyou Wang ,  Michael Van Der Puy

Inventor： Ryan Hulse ,  Rajiv R. Singh ,  Konstantin A. Pokrovski ,  Hsueh Sung Tung ,  Daniel Merkel ,  Haiyou Wang ,  Michael Van Der Puy

IPC: C07C17/00

CPC classification number: C07C17/358 ,  C07C17/383 ,  C07C21/18

Abstract: Disclosed are processes for an isomerization reaction between (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene. Some of the disclosed processes include the step of contacting a feed stream with a heated surface, where the feed stream includes (E)1-chloro-3,3,3-trifluoropropene, (Z)1-chloro-3,3,3-trifluoropropene or mixtures thereof. The resulting product stream includes (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene, where the ratio of (E) isomer to (Z) isomer in the product stream is different than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

Abstract translation: 公开了（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯之间异构化反应的方法。 一些所公开的方法包括使进料流与加热表面接触的步骤，其中进料流包含（E）1-氯-3,3,3-三氟丙烯，（Z）1-氯-3,3,3 - 三氟丙烯或其混合物。 所得产物流包含（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯，其中（E）异构体与（Z）异构体的比例 产品流与进料流比不同。 产物流中的（E）和（Z）异构体可以彼此分离。

公开(公告)号：US20070112230A1

公开(公告)日：2007-05-17

申请号：US11592761

申请日：2006-11-03

Applicant: Sudip Mukhopadhyay ,  Haridasan Nair ,  Hsueh Tung ,  Michael Van Der Puy ,  Daniel Merkel ,  Rajesh Dubey ,  Jing Ji Ma

Inventor： Sudip Mukhopadhyay ,  Haridasan Nair ,  Hsueh Tung ,  Michael Van Der Puy ,  Daniel Merkel ,  Rajesh Dubey ,  Jing Ji Ma

IPC: C07C17/093

CPC classification number: C07C17/04 ,  C07C17/00 ,  C07C17/06 ,  C07C17/206 ,  C07C17/25 ,  C07C17/26 ,  C07C17/269 ,  C07C17/272 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

Abstract: Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X   (I) to at least one compound of formula (II) CF3CZCHZ   (II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.

Abstract translation: 公开了用于制备包括氢氟丙烯的氟化有机化合物的方法，其优选包括转化至少一种式（I）的化合物：<？in-line-formula description =“In-Line Formulas”end =“lead” 至少一种式（III）化合物（其中R 1，R 2，R 3，R 4， II）<？in-line-formula description =“In-line Formulas”end =“lead”？> CF 3 3 CZCHZ（II）。 其中X独立地为Cl，Br，I或F，Z独立地为H或F.在某些优选实施方案中，每个Z为 不同。

公开(公告)号：US20070112227A1

公开(公告)日：2007-05-17

申请号：US11592842

申请日：2006-11-03

Applicant: Sudip Mukhopadhyay ,  Haridasan Nair ,  Hsueh Tung ,  Michael Van Der Puy ,  Robert Johnson ,  Daniel Merkel

Inventor： Sudip Mukhopadhyay ,  Haridasan Nair ,  Hsueh Tung ,  Michael Van Der Puy ,  Robert Johnson ,  Daniel Merkel

IPC: C07C17/00

CPC classification number: C07C17/25 ,  B01J23/02 ,  B01J23/44 ,  B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J35/06 ,  C07C17/00 ,  C07C17/269 ,  C07C21/18 ,  C07C19/08

Abstract: Disclosed is a process for the preparation of fluorinated olefins. In preferred embodiments C3 olefins are produced by methods comprising contacting a compound of the Formula (I) C(R1aR2bR3c)   (I) with a compound of Formula (II) C(R1aR2bR3c)Cn(R1aR2bR3c)   II wherein R1a, R2b, and R3c are independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula I has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently=0, 1, 2 or 3 and (a+b+c)=2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.

Abstract translation: 公开了一种制备氟化烯烃的方法。 在优选的实施方案中，C3烯烃通过以下方法制备：包括使式（I）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→C（R 1> （I）＆lt;＆lt;＆lt; 2＆gt;＆lt; 3＆gt; in-line-formula description =“In-line Formulas”end =“tail”？>与式（II）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> C（R 1）1 R 2 R 2 R 3 R 3 R 3， （R 1）R 1 R 2 R 2 R 2 R 2 R 2 R 2 其中R 1' R 1，R 2，R 3和R 3独立地是氢原子或 选自氟的卤素; 氯，溴和碘，条件是式I化合物具有至少三个卤素取代基，并且在三个卤素取代基上含有至少一个氟; a，b和c独立地为= 0,1,2或3，（a + b + c）= 2或3; 在有效产生至少一种C3氟代烯烃的条件下，n为0或1。

公开(公告)号：US20050033097A1

公开(公告)日：2005-02-10

申请号：US10637976

申请日：2003-08-08

Applicant: Hseuh Sung Tung ,  Kevin Uhrich ,  Daniel Merkel

Inventor： Hseuh Sung Tung ,  Kevin Uhrich ,  Daniel Merkel

IPC: C07C17/20 ,  C07C17/25 ,  C07C19/00 ,  C07C19/08

CPC classification number: C07C17/206 ,  C07C17/25 ,  C07C21/18

Abstract: A process for producing 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) from 1,1,1-3,3-pentachloropropane (HCC-240fa) by its reaction with hydrogen fluoride, the reactants are reacted in a liquid phase reaction at a temperature of less than 150° C. in the presence of a Lewis acid catalyst or mixture of Lewis acid catalysts, and hydrogen chloride and HCFC-1233zd formed in the reaction are continuously removed and the HCFC-12333zd is isolated.

Abstract translation: 通过与氟化氢反应从1,1,1-3,3-五氯丙烷（HCC-240fa）生产1-氯-3,3,3-三氟丙烯（HCFC-1233zd）的方法，反应物在 在路易斯酸催化剂或路易斯酸催化剂的混合物和反应中形成的氯化氢和HCFC-1233zd的存在下，在小于150℃的温度下，连续除去液相反应，分离出HCFC-12333zd。

公开(公告)号：US20050013764A1

公开(公告)日：2005-01-20

申请号：US10620018

申请日：2003-07-15

Applicant: Daniel Merkel ,  HsuehSung Tung

Inventor： Daniel Merkel ,  HsuehSung Tung

IPC: C01B7/19 ,  C07C17/38

CPC classification number: C01B7/195

Abstract: Provided are methods of producing anhydrous hydrogen fluoride comprising: providing a mixture comprising hydrogen fluoride and at least one halogenated hydrocarbon; and extracting hydrogen fluoride from the mixture by contacting the mixture with a solution of less than about 93 wt. % sulfuric acid solution in water.

Abstract translation: 提供了生产无水氟化氢的方法，其包括：提供包含氟化氢和至少一种卤代烃的混合物; 并从混合物中提取氟化氢，使混合物与小于约93wt。 ％硫酸溶液在水中。