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    Phillips catalyst and its use for the preparation of ethylene homopolymers and copolymers
    11.
    发明授权
    Phillips catalyst and its use for the preparation of ethylene homopolymers and copolymers 失效
    菲利普斯催化剂及其在制备乙烯均聚物和共聚物中的应用

    公开(公告)号：US5352658A

    公开(公告)日：1994-10-04

    申请号：US16277

    申请日：1993-02-11

    Applicant: Kaspar Evertz ,  Roland Saive ,  Guido Funk ,  Peter Koelle ,  Rainer Konrad ,  Hans Gropper

    Inventor： Kaspar Evertz ,  Roland Saive ,  Guido Funk ,  Peter Koelle ,  Rainer Konrad ,  Hans Gropper

    IPC: C08F2/42 ,  C08F4/00 ,  C08F4/02 ,  C08F4/06 ,  C08F4/22 ,  C08F4/24 ,  C08F4/69 ,  C08F10/00 ,  C08F10/02 ,  B01J31/00

    CPC classification number: C08F10/00

    Abstract: A novel Phillips catalyst for the homopolymerization of ethylene and the copolymerization of ethylene with .alpha.-olefins contains, as a catalytically active component, a chromium catalyst supported on a finely divided aluminum silicate gel, modified with a fluoride and activated in an oxidizing atmosphere at elevated temperatures. The finely divided aluminum silicate gel (carrier gel) used here has an alumina content of from 0.5 to 6% by weight, the alumina being concentrated in the surface region of the carrier gel particles. The novel Phillips catalyst has high productivity and gives high molecular weight ethylene homopolymers and copolymers which have excellent low temperature impact strength and do not tend to swell in the blow molding process on emergence from the extruder die.

    Abstract translation: 用于乙烯均聚和乙烯与α-烯烃共聚的新型菲利普斯催化剂含有负载在细分硅酸铝凝胶上的铬催化剂作为催化活性组分，用氟化物改性并在升高的氧化气氛中活化 温度。 这里使用的细分的硅酸铝凝胶（载体凝胶）的氧化铝含量为0.5〜6重量％，氧化铝浓缩在载体凝胶粒子的表面区域。 该新型菲利普斯催化剂具有高生产率，并得到具有优异的低温冲击强度的高分子量乙烯均聚物和共聚物，并且在吹塑模制过程中不会从挤出机模头出现而膨胀。

    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system
    14.
    发明授权
    Preparation of homopolymers of ethene and copolymers of ethene with higher a-monoolefins using a Ziegler catalyst system 失效
    使用齐格勒催化剂体系制备乙烯与乙烯共聚物与高级单环戊二烯的共聚物

    公开(公告)号：US5210160A

    公开(公告)日：1993-05-11

    申请号：US410047

    申请日：1989-09-19

    Applicant: Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    Inventor： Roland Saive ,  Guido Funk ,  Rainer Hemmerich

    IPC: C08F4/607 ,  C08F4/642 ,  C08F4/647 ,  C08F4/65 ,  C08F4/685 ,  C08F10/02

    CPC classification number: C08F10/02

    Abstract: Homopolymerization and copolymerization of ethene is carried out using a Ziegler catalyst system consisting of (1) a transition metal catalyst component, (2) an organoaluminum catalyst component and (3) an organohalogen catalyst component. The component (1) used is the solid-phase product (VI) which has been obtained by a method in which (1.1) first (1.1.1) an inorganic oxidic substance (I) as a carrier and (1.1.2) a solution (II) of (IIa) a certain oxahydrocarbon and (IIb) a mixture of (IIb1) a vanadium trichloride/alcohol complex and (IIb2) a titanium trihalide or titanium trihalide/alcohol complex and (IIc) a silicon or boron compound are combined with formation of a suspension (III) and the latter is evaporated to form a solid-phase intermediate (IV) and (1.2) then (1.2.1) the intermediate (IV) obtained in (1.1) and (1.2.2) a dissolved organoaluminum compound (V) are combined with formation of a suspension, the solid-phase product (VI) formed as the suspended substance being the transition metal catalyst component (1).

    Abstract translation: 使用由（1）过渡金属催化剂组分，（2）有机铝催化剂组分和（3）有机卤化物催化剂组分组成的齐格勒催化剂体系进行乙烯的均聚和共聚。 所使用的组分（1）是通过以下方法获得的固相产物（VI）：（1.1）第一（1.1.1）作为载体的无机氧化物质（I）和（1.1.2）a （IIa）的某些氧杂烃的溶液（II）和（IIb）（IIb1）三氯化钒/醇络合物和（IIb2）三卤化钛或三卤化钛/醇络合物和（IIc）硅或硼化合物的混合物 （IV）和（1.2）然后（1.2.1）（1.1）和（1.2.2）中得到的中间体（Ⅳ），然后蒸发形成悬浮液（III） 将溶解的有机铝化合物（V）与形成悬浮液组合，形成为作为过渡金属催化剂组分（1）的悬浮物质的固相产物（VI）。

    Supported chromium oxide catalyst
    15.
    发明授权
    Supported chromium oxide catalyst 失效
    支持的氧化铬催化剂

    公开(公告)号：US5164353A

    公开(公告)日：1992-11-17

    申请号：US435681

    申请日：1989-11-14

    Applicant: Siegfried Weber ,  Guido Funk

    Inventor： Siegfried Weber ,  Guido Funk

    IPC: C08F4/02 ,  C08F4/24 ,  C08F4/60 ,  C08F4/622 ,  C08F4/623 ,  C08F4/629 ,  C08F4/69 ,  C08F10/02

    CPC classification number: C08F10/02

    Abstract: A supported catalyst for ethene polymerization by Phillips catalysis is disclosed. The supported catalyst is prepared by (1) mixing a porous silicate in an inert, organic liquid to produce a silicate suspension, (2) providing an ester of phosphoric acid or phosphorous acid, (3) mixing an organic liquid, a chromium compound, and a trialkylaluminum compound to produce a chromium compound/aluminum compound and combining the silicate suspension, the phosphorus compound and the chromium compound/aluminum compound suspension. This resulting suspension is evaporated to dryness to form a catalyst intermediate. The catalyst intermediate is heated in nitrogen, then heated in an oxygen-containing atmosphere, and then heated again in nitrogen to produce an activated catalyst. The activated catalyst is suspended in an organic liquid and treated with an alkyl boron compound to produce the desired supported catalyst.

    Abstract translation: 公开了通过菲利普斯催化剂进行乙烯聚合的负载型催化剂。 负载型催化剂的制备方法是：（1）将惰性有机液体中的多孔硅酸盐混合以制备硅酸盐悬浮液，（2）提供磷酸或亚磷酸的酯，（3）将有机液体，铬化合物， 和三烷基铝化合物，以制备铬化合物/铝化合物并将硅酸盐悬浮液，磷化合物和铬化合物/铝化合物悬浮液混合。 将所得悬浮液蒸发至干，形成催化剂中间体。 将催化剂中间体在氮气中加热，然后在含氧气氛中加热，然后在氮气中再次加热以产生活化的催化剂。 将活化的催化剂悬浮在有机液体中并用烷基硼化合物处理以产生所需的负载型催化剂。

    Preparation of finely divided homopolymers and copolymers of ethene using a liquid alkane as reaction medium
    17.
    发明授权
    Preparation of finely divided homopolymers and copolymers of ethene using a liquid alkane as reaction medium 失效
    使用液体烷烃作为反应介质制备细碎的乙烯均聚物和共聚物

    公开(公告)号：US4794151A

    公开(公告)日：1988-12-27

    申请号：US035919

    申请日：1987-04-08

    Applicant: Rudolf Mueller-Mall ,  Guido Funk ,  Robert Bachl ,  Peter Hennenberger ,  Erich Kolk

    Inventor： Rudolf Mueller-Mall ,  Guido Funk ,  Robert Bachl ,  Peter Hennenberger ,  Erich Kolk

    IPC: C08F2/06 ,  C08F2/14 ,  C08F2/18 ,  C08F10/02 ,  C08F210/16 ,  C08F10/08

    CPC classification number: C08F10/02 ,  C08F210/16 ,  Y10S526/909 ,  Y10S526/922

    Abstract: A process for the continuous preparation of finely divided homopolymers and copolymers of ethene by catalytic polymerization in a circular tube reactor using a liquid alkane as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the polymer formed is present in suspended form and running the reaction mixture as a cycle stream to which the feed materials are added by bleeding in and from which the polymer formed is withdrawn by bleeding out reaction mixture, comprising (a) maintaining the mean concentration C.sub.m of polymer in the cycle stream at a value within a certain range and (b) effecting the bleeding out of reaction mixture at a point of the cycle stream at which the concentration of polymer has a value which is lower than the mean concentration C.sub.m by a distinct and definite amount.

    Abstract translation: 通过催化聚合在圆管反应器中连续制备乙烯的均匀聚合物和共聚物的方法，其中使用液体烷烃作为反应介质，其中待聚合的乙烯或乙烯/共聚单体混合物以溶解形式存在并形成聚合物 以悬浮形式存在，并以作为循环流的方式运行反应混合物，通过渗出反应混合物，通过渗出所形成的聚合物而将原料加入到该循环流中，通过渗出反应混合物排出，其包括（a）将聚合物的平均浓度Cm保持在 循环流在一定范围内的值，和（b）在聚合物浓度具有低于平均浓度C m的值的循环流的点处，通过不同的和明确的方式实现反应混合物的渗出 量。

    Process for preparing a chromium-based catalyst for the polymerization and/or copolymerization of olefins
    19.
    发明授权
    Process for preparing a chromium-based catalyst for the polymerization and/or copolymerization of olefins 有权
    制备用于烯烃聚合和/或共聚的铬基催化剂的方法

    公开(公告)号：US07705097B2

    公开(公告)日：2010-04-27

    申请号：US11628827

    申请日：2005-06-09

    Applicant: Shahram Mihan ,  Andreas Haufe ,  Peter Kölle ,  Joachim Wulff-Döring ,  Ingo Treffkorn ,  Guido Funk

    Inventor： Shahram Mihan ,  Andreas Haufe ,  Peter Kölle ,  Joachim Wulff-Döring ,  Ingo Treffkorn ,  Guido Funk

    IPC: C08F4/22 ,  C08F4/16 ,  B01J31/34 ,  B01J31/38

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F2410/04 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/17 ,  C08F2500/12 ,  C08F4/22 ,  C08F4/025 ,  C08F4/16

    Abstract: Process for preparing a supported catalyst for the polymerization and/or copolymerization of olefins which has a chromium content of from 0.01 to 5% by weight, based on the element, which comprises (a) preparing a homogeneous solution comprising an organic or inorganic chromium compound and at least one further organic or inorganic compound of elements selected from among Mg, Ca, Sr, B, Al, Si, P, Bi, Sc, V, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Hf, Ta, W in a protic or aprotic polar solvent, (b) bringing the solution from a) into contact with a finely divided inorganic support to form a catalyst precursor, (c) if appropriate, removing the solvent from the catalyst precursor and (d) calcining the catalyst precursor at temperatures of from 350 to 950° C., preferably 400 to 900° C., under oxidative conditions.

    Abstract translation: 制备用于烯烃聚合和/或共聚的负载催化剂的方法，该催化剂的铬含量为0.01至5重量％，基于该元素，其包括（a）制备包含有机或无机铬化合物的均匀溶液 以及选自Mg，Ca，Sr，B，Al，Si，P，Bi，Sc，V，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb中的至少一种有机或无机化合物， Mo，Ru，Rh，Pd，Hf，Ta，W在质子或非质子极性溶剂中，（b）使来自a）的溶液与细碎的无机载体接触以形成催化剂前体，（c） 从催化剂前体中除去溶剂，和（d）在氧化条件下，在350-950℃，优选400-900℃的温度下煅烧催化剂前体。

    Process for Preparing a Support for Olefin Polymerization Catalysts
    20.
    发明申请
    Process for Preparing a Support for Olefin Polymerization Catalysts 审中-公开
    制备烯烃聚合催化剂的方法

    公开(公告)号：US20090286671A1

    公开(公告)日：2009-11-19

    申请号：US12086464

    申请日：2006-12-04

    Applicant: Christoph Kiener ,  Ingo Treffkorn ,  Guido Funk

    Inventor： Christoph Kiener ,  Ingo Treffkorn ,  Guido Funk

    IPC: B01J29/04

    CPC classification number: C08F10/00 ,  B01J21/08 ,  B01J35/08 ,  B01J35/1047 ,  B01J37/036 ,  C01B33/16 ,  C01G23/047 ,  C01G25/02 ,  C01G29/00 ,  C01P2004/32 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/82 ,  C08F4/24 ,  C08F4/025

    Abstract: The invention relates to a process for preparing an essentially spherical support for olefin polymerization catalysts, which comprises the steps: preparation of a hydrogel comprising a cogel of silicon oxide and at least one further metal oxide, if appropriate, washing of the hydrogel until the content of alkali metal ions is less than 0.1% by weight, based on the weight of solids, extraction of the water from the hydrogel until the water content is less than 5% by weight, based on the total content of liquid, and drying of the hydrogel to form a xerogel. According to the invention, the extraction step comprises at least one batchwise extraction with an organic solvent which is at least partially miscible with water down to a water content of less than 50% by weight, followed by at least one continuous extraction with an organic solvent which is at least partially miscible with water.

    Abstract translation: 本发明涉及一种制备用于烯烃聚合催化剂的基本上为球形的载体的方法，其包括以下步骤：制备包含氧化硅和至少一种其它金属氧化物的共凝胶的水凝胶（如果合适的话），洗涤水凝胶，直到含量 的碱金属离子的含量小于0.1重量％，基于固体的重量，从水凝胶中提取水直到水含量低于5重量％，基于液体的总含量，并干燥 水凝胶形成干凝胶。 根据本发明，提取步骤包括至少一种有机溶剂的间歇萃取，所述有机溶剂至少部分地与水混合，直到水含量低于50重量％，然后至少一次连续萃取有机溶剂 其至少部分地与水混溶。

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