Abstract:
Coating compositions are disclosed that include an alkoxide and a silica sol that includes silica nanoparticles and a polymerizable (meth)acrylate binding agent. The polymerizable (meth)acrylate binding agent remains substantially uncrosslinked after the coating composition has been cured to form a hard coat. Also disclosed are articles at least partially coated with a hard coat deposited from such a coating composition, methods for depositing a hard coat on at least a portion of a plastic substrate, and methods for improving the adhesion and abrasion resistance of a coating composition.
Abstract:
Coated articles are provided comprising: (a) a substrate; (b) a porous sol-gel layer superimposed on at least one surface of the substrate; wherein the porous sol-gel layer comprises a hydrolyzed tetraalkoxysilane; and (c) a sealant layer superimposed on at least one surface of the porous sol-gel layer; wherein the sealant layer comprises an alkyltrihalosilane. The coated articles demonstrate superior abrasion resistance due to a glass-like layer formed from the combination of the porous sol-gel layer and sealant layer.
Abstract:
Coating compositions are disclosed that include an alkoxide of the general formula RxM(OR′)z-x where R is an organic radical, M is silicon, aluminum, titanium, and/or zirconium, each R′ is independently an alkyl radical, z is the valence of M, and x is a number less than z and may be zero. The coating composition is cationically curable. Also disclosed are articles at least partially coated with a hard coat deposited from such a coating composition, methods for depositing a hard coat on at least a portion of a plastic substrate, and methods for improving the adhesion and abrasion resistance of a substrate.
Abstract:
Provided are curable film-forming compositions are provided including: (a) a binder of an alkoxysilane; (b) a metal oxide compound containing titanium, zirconium, cerium, niobium, tantalum, and/or tin; and (c) a polyglycidyl ether. Also provided are optical articles including a substrate and the curable film-forming composition superposed on a surface thereof.
Abstract:
Liquid compositions are disclosed that include a photocatalytic material and a hydrophilic binder that includes an essentially completely hydrolyzed organosilicate. Also disclosed are methods of making such compositions, methods of coating a substrate with a hydrophilic composition, and substrates coated with such compositions. The compositions may, for example, be embodied as stable one-pack compositions.
Abstract:
Disclosed are tinted, abrasion resistant coating compositions comprising polymer-enclosed color-imparting particles. Also disclosed are methods for making such a composition and substrates at least partially coated with a hard coat deposited from such a composition.
Abstract:
A process is provided for preparing a coated optical element. The process Includes: a) providing an optical element substrate; b) contacting the optical element with a pretreatment composition of an aqueous solution of hydrolyzed aminosilane; and c) applying a film-forming composition to the optical element of (b) to form a coating on the optical element, thereby yielding a coated optical element. The pretreatment composition may further include a substantially water-miscible solvent that is capable of swelling the substrate surface without causing haze or degradation of the substrate. The coated optical element demonstrates improved adhesion between the film-forming composition and the substrate compared to a substantially identical optical element that has not been contacted with the pretreatment composition of step b) prior to application of the film-forming composition.
Abstract:
A process is provided for preparing a coated optical element. The process Includes:a) providing an optical element substrate;b) contacting the optical element with a pretreatment composition of an aqueous solution of hydrolyzed aminosilane; andc) applying a film-forming composition to the optical element of (b) to form a coating on the optical element, thereby yielding a coated optical element. The pretreatment composition may further include a substantially water-miscible solvent that is capable of swelling the substrate surface without causing haze or degradation of the substrate. The coated optical element demonstrates improved adhesion between the film-forming composition and the substrate compared to a substantially identical optical element that has not been contacted with the pretreatment composition of step b) prior to application of the film-forming composition.
Abstract:
Multi-layer coatings are disclosed that include (a) a first layer deposited from at least one composition that includes a polymeric composition, and (b) a second layer applied over at least a portion of the first layer in which the second layer is deposited from at least one liquid composition that includes (i) a photocatalytic material, and (ii) a binder that is hydrophilic and comprises an essentially completely hydrolyzed organosilicate. Also disclosed are substrates coated with such multi-layer coatings, methods of applying such multi-layer coatings to a substrate and methods of making a painted surface easy-to-clean.
Abstract:
Described is a coating composition adapted to enhance the adhesion of a polymeric coating or film applied to a substrate. The coating composition is interposed between the substrate and the polymeric coating and comprises (a) at least one coupling agent, partial hydrolysates thereof or mixtures thereof in a concentration greater than 25 weight percent, based on the weight of the total composition, and (b) an adhesion enhancing amount of an epoxy-containing material having at least two epoxy groups. The coating composition is substantially free of photochromic materials and colloidal particles chosen from silica, alumina or mixtures thereof. Also described is a process for using the coating composition and articles coated with the composition and additional coatings and films which can be photochromic.