Abstract:
An adhesive tape for lead-on-chip (LOC) IC applications containing a polyamide-based adhesive composition which is the reaction product from a reaction mixture of: (a) a pre-imidized polyamic acid; and (b) a bismaleimide that has been modified by a barbituric acid of a derivative of barbituric acid to become a barbituric acid modified bismaleimide. The pre-imidized polyamic acid is a reaction product from a reaction mixture that contains a polyamic acid and a cyclizing agent. The polyamide-based adhesive composition provides all the desirable heat resistance and other mechanical and dielectric characteristics. But, most significantly, its microscopic rheological properties are adjusted such that excellent contact is achieved between the resin molecules and the lead frame surface while eliminating or at least minimizing the extent of adhesive overflow, which can substantially reduce the reliability of the final IC product.
Abstract:
A heat resistant composition comprising a mixture of (a) a polyurethane or a modified polyurethane and (b) a bismaleimide oligomer, in which the bismaleimide oligomer is in an amount of about 1 to 35 percent by weight based on overall solid contents. The polyurethane is formed by reacting a diisocyanate-containing compound with a dihydroxy diol-compound. Then the polyurethane is reacted with a trimellitic anhydride, a diacid or a mixture thereof to form the modified polyurethane. The bismaleimide oligomer is formed by reacting a bismaleimide resin with a barbituric acid or a derivative thereof.
Abstract:
A process for manufacturing a high glass transition temperature printed circuit board comprising blending a modified bismaleimide resin into a modified epoxy resin is disclosed. Particularly the material is manufactured by blending a bismaleimide resin reacted with barbituric acid and its derivative thereof and an epoxy resin with an oxazolidone ring resulting from the reaction of a polyisocyanate and an epoxy resin modified with a secondary diamine and followed by curing. The resultant product has a high glass transition temperature, a good adhesion, flame retardancy, and a low bromine content.
Abstract:
A polyimide composition for use in making polyimide/copper foil laminate that does not require an adhesive layer between the polyimide substrate and the copper foil. A polyimide precursor is first prepared from a monomer composition, which comprises a dianhydride and an imidazole-containing or benzimidazole-containing compound, or mixture thereof The polyimide precursor is then coated onto a copper foil and subsequently subject to an imidization reaction to form a polyimide/copper foil laminate, which exhibits excellent peel strength and flatness while retaining all the advantageous properties that are characteristic of polyimide resins, such as excellent mechanical strength and heat and chemical resistance. Because the polyimide/copper foil laminates disclosed in the present invention are made without the need to apply an adhesive layer, the process of manufacturing the same is greatly simplified and the cost of production therefor can be substantially reduced. Furthermore, many of the problems caused by the inferior chemical and/or physical properties of the adhesive layer are completely eliminated.
Abstract:
A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.
Abstract:
A cathode material structure and a method for preparing the same are described. The cathode material structure includes a material body and a composite film coated thereon. The material body has a particle size of 0.1-50 μm. The composite film has a porous structure and electrical conductivity.
Abstract:
A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.
Abstract:
Binder composites for membrane electrode assemblies and membrane electrode assemblies employing the same are provided. The binder composition includes a solvent, a hyper-branched polymer and a polymer with high ion conductivity, wherein the hyper-branched polymer and the polymer with high conductivity of hydronium are distributed uniformly over the solvent, and the hyper-branched polymer has a DB (degree of branching) of more than 0.5.
Abstract:
Disclosed is a lithium battery including a silicon negative electrode, a lithium mixed metal oxide positive electrode, a separator disposed between the negative and positive electrodes to define a reservoir region, an electrolytic solution filled in the reservoir region, and a sealant structure wrapped around the silicon negative electrode, the lithium mixed metal oxide positive electrode, the separator, and the electrolytic solution. The electrolytic solution includes an organic solvent, a lithium salt, and an additive. The additive includes a maleimide compound and vinylene carbonate. The silicon negative electrode of the lithium battery employing the described electrolytic solution has higher cycle efficiency and longer operating lifespan.
Abstract:
A gel polymer electrolyte precursor and a rechargeable cell comprising the same are provided. The gel polymer electrolyte precursor comprises a bismaleimide monomer or bismaleimide oligomer, a compound having formula (I): , a non-aqueous metal salt electrolyte, a non-protonic solvent, and a free radical initiator, wherein the bismaleimide oligomer is prepared by reaction of barbituric acid and bismaleimide, X comprises oxygen, organic hydrocarbon compounds, organic hydrocarbon oxide compounds, oligomers or polymers, n is 2 or 3, and A independently comprises wherein m is 0˜6, X comprises hydrogen, cyano, nitro or halogen, and R1 independently comprises hydrogen or C1˜4 alkyl.
Abstract translation:提供了一种凝胶聚合物电解质前体和包含该前体的可充电电池。 凝胶聚合物电解质前体包含双马来酰亚胺单体或双马来酰亚胺低聚物,具有式(I)的化合物:非水金属盐电解质,非质子溶剂和自由基引发剂,其中双马来酰亚胺低聚物通过反应 的巴比妥酸和双马来酰亚胺,X包括氧,有机烃化合物,有机烃氧化物,低聚物或聚合物,n为2或3,A独立地包含其中m为0〜6,X为氢,氰基,硝基或卤素, R 1和R 2独立地包括氢或C 1-4烷基。