Process for producing aliphatic tricarbonitriles
    15.
    发明授权
    Process for producing aliphatic tricarbonitriles 失效
    生产脂肪族三羰腈的方法

    公开(公告)号:US06790976B2

    公开(公告)日:2004-09-14

    申请号:US09893858

    申请日:2001-06-28

    CPC classification number: C07C253/00 C07C255/05

    Abstract: The present invention relates to a process for producing tricarbonitriles corresponding to formula I wherein n is an integer from 2 to 11 by forming an intermediate in the presence of a strong base in a first stage from an aliphatic &agr;-&ohgr;-dinitrile corresponding to formula II wherein n is an integer from 3 to 12, and reacting the intermediate in a second stage to form a trinitrile corresponding to formula I by the addition of acrylonitrile.

    Abstract translation: 本发明涉及一种制备相应于式I的方法,其中n为2至11的整数,通过在第一阶段中在强碱存在下,形成对应于式II的脂族α-ω-二腈的中间体,其中n为 3至12的整数,并在第二阶段使中间体反应,通过加入丙烯腈形成对应于式I的三腈。

    Picolylamine resins
    16.
    发明授权
    Picolylamine resins 有权
    吡啶基胺树脂

    公开(公告)号:US08563622B2

    公开(公告)日:2013-10-22

    申请号:US12919851

    申请日:2009-02-27

    Abstract: The present application relates to novel monodisperse, gel-type or macroporous picolylamine resins which are based on at least one monovinylaromatic compound and at least one polyvinylaromatic compound and/or a (meth)acrylic compound and contain tertiary nitrogen atoms in structures of the general formula (I) as functional group, where R1 is an optionally substituted radical from the group consisting of picolyl, methylquinoline and methylpiperidine, R2 is a radical —(CH2)q—COOR3, R3 is a radical from the group consisting of H, Na and K, m is an integer from 1 to 4, n and p are each, independently of one another, a number in the range from 0.1 to 1.9 and the sum of n and p is 2, q is an integer from 1 to 5 and M is the polymer matrix, a process for preparing them and their uses, in particular the use in hydrometallurgy and electroplating.

    Abstract translation: 本申请涉及基于至少一种单乙烯基芳族化合物和至少一种聚乙烯基芳族化合物和/或(甲基)丙烯酸化合物并且在通式结构中含有叔氮原子的新型单分散,凝胶型或大孔吡甲基胺树脂 (I)作为官能团,其中R 1是由吡啶甲基,甲基喹啉和甲基哌啶组成的组中的任选取代的基团,R 2是 - (CH 2)q -COOR 3基团,R 3是由H,Na和 K,m为1〜4的整数,n和p各自独立地为0.1〜1.9的数,n与p的和为2,q为1〜5的整数, M是聚合物基质,其制备方法及其用途,特别是在湿法冶金和电镀中的应用。

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