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    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
    14.
    发明授权
    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins 失效
    乙烯和/或α-烯烃和邻近二取代烯烃的共聚物

    公开(公告)号：US07037989B2

    公开(公告)日：2006-05-02

    申请号：US10446325

    申请日：2003-05-27

    Applicant: Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    Inventor： Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    IPC: C08F4/52

    CPC classification number: C08F210/02 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/20 ,  C08F2500/03 ,  C08F210/06

    Abstract: Substantially random ethylene and/or α-olefin copolymers containing units derived from vicinally disubstituted olefin monomers are described. The vicinally disubstituted olefin monomers may be represented by the generic formula (R1)CH═CH(R2), where R1 and R2 independently comprise hydrocarbyl or silyl-hydrocarbyl groups containing 1 or more carbon atoms, or may be linear, branched or cyclic substituted or unsubstituted hydrocarbyl groups having from 1-100 carbon atoms, or they may contain 30 or less carbon atoms. The copolymers may be prepared by coordination polymerization by means of contacting at least one vicinally disubstituted olefin monomer and ethylene and/or α-olefin, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl heteroatom-containing Group 4 transition metal catalyst component.

    Abstract translation: 描述了含有衍生自邻近二取代的烯烃单体的单元的基本无规的乙烯和/或α-烯烃共聚物。 邻位二取代的烯烃单体可以由通式（R 1）CH-CH（R 2）表示，其中R 1和R 2 独立地包含含有1个或更多个碳原子的烃基或甲硅烷基 - 烃基，或者可以是具有1-100个碳原子的直链，支链或环状取代或未取代的烃基，或者它们可以含有30或 碳原子少。 共聚物可以通过使至少一个相邻二取代的烯烃单体和乙烯和/或α-烯烃（任选地与一种或多种其它配位可聚合单体）与含有单环戊二烯基杂原子的第4组的催化剂体系 过渡金属催化剂组分。

    Olefin polymerization catalyst system and process for use thereof
    16.
    发明申请
    Olefin polymerization catalyst system and process for use thereof 有权

    公开(公告)号：US20060009595A1

    公开(公告)日：2006-01-12

    申请号：US11178147

    申请日：2005-07-08

    Applicant: Francis Rix ,  Smita Kacker ,  Sudhin Datta ,  Rul Zhao ,  Vetkav Eswaran

    Inventor： Francis Rix ,  Smita Kacker ,  Sudhin Datta ,  Rul Zhao ,  Vetkav Eswaran

    IPC: C08F4/44 ,  B01J31/00 ,  C07F17/00

    CPC classification number: C07F17/00 ,  C08F4/65912 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/544 ,  Y10S526/943 ,  C08F2500/03 ,  C08F2500/20 ,  C08F210/16 ,  C08F4/65927

    Abstract: This invention relates to a compound represented by the formula: where M is a transition metal selected from group 4 of the periodic table; each R1 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and functional group, and any two R1 may be linked, provided that if the two R1 groups are linked, then they do not form a butadiene group when M is Zr; each R2 is independently selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl and the isomers thereof, provided that when R3 and R6 and or R12 and R15 form a 5 carbon ring, then each R2 is independently selected from the group consisting of ethyl, propyl, butyl, pentyl, hexyl and the isomers thereof; R3 is carbon or silicon; R4 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; a is 0, 1, or 2; R5 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, R4 and R5 may be bound together to form a ring, and R5 and R3 may be bound together to form a ring; b is 0, 1, or 2; R6 is carbon or silicon; and R4 and R6 may be bound together to form a ring; each R7 is hydrogen; each R8 is independently selected from the group consisting of hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl and the isomers thereof; each R9 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group, and two R9 groups may be linked together to form a ring, R9 and R8 may be linked together to form a ring, R9 and R16 may be linked together to form a ring, R9 and R11 may be linked together to form a ring; c is 0, 1 or 2; R10 is -M2(R16)h— where M2 is B, Al, N, P, Si or Ge, h is an integer from 1 to 2, such that the valence of M2 is filled, and R16 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and two R16 groups may be linked together to form a ring; d is 0, 1, or 2; each R11 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and a functional group, and two R11 groups may be linked together to form a ring. R11 and R8 may be linked together to form a ring. R11 and R16 may be linked together to form a ring; e is 0, 1, or 2; where the sum of c, d, and e is 1, 2 or 3; R12 is carbon or silicon; R13 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and R13 and R14 may be bound together to form a ring, and R13 and R15 may be bound together to form a ring, when g is 0; f is 0, 1, or 2; R14 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and R14 and R12 may be bound together to form a ring, when f is 0; g is 0, 1, or 2; and R15 is carbon or silicon. This invention further relates to a process to polymerize unsaturated monomers using the above compositions.

    Fibers and non-wovens prepared with propylene-based elastomers
    18.
    发明授权
    Fibers and non-wovens prepared with propylene-based elastomers 有权
    用丙烯基弹性体制备的纤维和非织造布

    公开(公告)号：US07943701B2

    公开(公告)日：2011-05-17

    申请号：US11698359

    申请日：2007-01-26

    Applicant: Narayanaswami Raja Dharmarajan ,  Smita Kacker

    Inventor： Narayanaswami Raja Dharmarajan ,  Smita Kacker

    IPC: C08L23/04 ,  D04H1/00

    CPC classification number: C08L23/10 ,  C08L23/142 ,  C08L51/06 ,  C08L57/02 ,  C08L91/06 ,  C08L2205/02 ,  C08L2205/03 ,  D01F6/46 ,  D04H1/544 ,  Y10T442/60 ,  C08L2666/02 ,  C08L2666/06

    Abstract: A nonwoven fabric made from a composition comprising (a) a propylene-based elastomer characterized by including from about 5% to about 35% by weight units deriving from alpha-olefin and a heat of fusion, as determined by DSC, of less than 80 J/g, (b) a propylene-based thermoplastic polymer characterized by an MFR (ASTM D-1238 2.16 kg @ 230° C.) of from about 3 to about 300 dg/min, and a heat of fusion, as determined by DSC, of greater than 80 J/g, and (c) a feel modifier selected from the group consisting of (i) a high-MFR thermoplastic resin having an MFR (ASTM D-1238 2.16 kg @ 230° C.) in excess of 400 dg/min, (ii) a hydrocarbon resin, (iii) a polyolefin wax, (iv) a functionalized hydrocarbon resin, (v) a functionalized polyolefin, and (vi) a combination of two or more of the foregoing feel modifiers, and (d) optionally a slip aid.

    Abstract translation: 一种由组合物制成的非织造织物，所述组合物包含（a）基于丙烯的弹性体，其特征在于包含约5％至约35％重量的衍生自α-烯烃的单元和通过DSC测定的熔融热小于80 J / g，（b）丙烯类热塑性聚合物，其特征在于约3至约300dg / min的MFR（ASTM D-1238 2.16kg @ 230℃）和约3至约300dg / min的熔融热，如 DSC，大于80J / g，和（c）选自下组的手感改性剂：（i）过量的MFR（ASTM D-1238 2.16kg，230℃）的高MFR热塑性树脂 400dg / min，（ii）烃树脂，（iii）聚烯烃蜡，（iv）官能化烃树脂，（v）官能化聚烯烃，和（vi）上述两种或更多种感觉改性剂的组合 ，和（d）任选的助滑剂。

    Late transition metal catalysts for olefin oligomerizations
    19.
    发明授权
    Late transition metal catalysts for olefin oligomerizations 有权
    用于烯烃低聚的晚期过渡金属催化剂

    公开(公告)号：US07871953B2

    公开(公告)日：2011-01-18

    申请号：US10692827

    申请日：2003-10-24

    Applicant: Baiyi Zhao ,  Smita Kacker ,  Jo Ann Marie Canich

    Inventor： Baiyi Zhao ,  Smita Kacker ,  Jo Ann Marie Canich

    IPC: B01J31/00 ,  B01J21/02 ,  B01J27/00 ,  B01J27/185

    CPC classification number: B01J31/1805 ,  B01J31/189 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/80 ,  B01J2531/824 ,  B01J2531/847 ,  C07F15/0026 ,  C07F15/004 ,  C07F15/0053 ,  C07F15/006 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/0093 ,  C07F15/02 ,  C07F15/025 ,  C07F15/04 ,  C07F15/045 ,  C07F15/06 ,  C07F15/065 ,  C08F10/00 ,  C08F4/7006

    Abstract: As series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalyst system includes a Group 8, 9 or 10 transition metal and an activator. The catalysts demonstrate high activity and selectivity for linear α-olefins. Preferably this invention relates to a catalyst system comprising the reaction product of: (a) an activator selected from the group consisting of alumoxane, aluminum alkyl, alkyl aluminum halide, alkylaluminum alkoxide, discrete ionic activator, and Lewis acid; and (b) a catalyst precursor wherein the catalyst precursor has the following formula: wherein (i) M is a Group-8, -9 , or -10 transition metal; (ii) N is nitrogen (iii) P is phosphorus; (iv) R1, R2, R3, and R4 are independently hydrocarbyl radicals; (v) Y is a hydrocarbyl bridge comprising a backbone wherein the backbone comprises a chain that is four or more carbon atoms long; (vi) X are independently abstractable ligands.

    Abstract translation: 已经发明了用于烯烃低聚的新型后期过渡金属催化剂系列。 催化剂体系包括第8,9或10族过渡金属和活化剂。 催化剂表现出对线性α-烯烃的高活性和选择性。 优选本发明涉及包含以下反应产物的催化剂体系：（a）选自铝氧烷，烷基铝，烷基铝卤化物，烷基铝醇盐，离散离子活化剂和路易斯酸的活化剂; 和（b）催化剂前体，其中催化剂前体具有下式：其中（i）M是8族-9或-10族过渡金属; （ii）N是氮（iii）P是磷; （ⅳ）R 1，R 2，R 3和R 4独立地为烃基; （v）Y是包含主链的烃基桥，其中主链包含长度为四个或更多个碳原子的链; （vi）X独立地是可抽出的配体。

    Fibers and Non-Wovens Prepared with Propylene-Based Elastomers
    20.
    发明申请
    Fibers and Non-Wovens Prepared with Propylene-Based Elastomers 有权
    用丙烯基弹性体制备的纤维和非织造布

    公开(公告)号：US20090124153A1

    公开(公告)日：2009-05-14

    申请号：US11938030

    申请日：2007-11-09

    Applicant: Narayanaswami Raja Dharmarajan ,  Vincent B. Gallez ,  Smita Kacker ,  Chia Yung Cheng

    Inventor： Narayanaswami Raja Dharmarajan ,  Vincent B. Gallez ,  Smita Kacker ,  Chia Yung Cheng

    IPC: C08L23/12 ,  D04H1/00

    CPC classification number: D01F6/46 ,  C08L23/10 ,  C08L23/142 ,  C08L2205/02 ,  D04H1/4291 ,  D04H1/4382 ,  D04H3/16 ,  Y10T442/60 ,  Y10T442/601 ,  Y10T442/602 ,  C08L2666/06 ,  C08L2666/08

    Abstract: A non-woven fabric made from a composition prepared by combining a first propylene-based polymer blend, where the first polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where the first blend has an MFR (ASTM D-1238 2.16 kg @ (230° C.) equal to or less than 50 dg/min, with a second propylene-based polymer blend, where the second polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where said second blend has an MFR (ASTM D-1238 2.16 kg @ 230° C.) greater than 50 dg/min, where the propylene-based elastomers comprise from about 5% to 35% by weight units derived from ethylene or non-propylene alpha-olefin and have a heat of fusion, as determined by DSC, of less than 80 J/g, and where the propylene-based thermoplastic resins have a heat of fusion, as determined by DSC, equal to or greater than 80 J/g.

    Abstract translation: 一种由通过组合第一基于丙烯的聚合物共混物制备的组合物制成的无纺织物，其中通过将基于丙烯的弹性体与丙烯类热塑性树脂组合制备第一聚合物共混物，其中第一共混物具有MFR ASTM D-1238 2.16kg @（230℃）等于或小于50dg / min，与第二丙烯基聚合物共混物，其中第二聚合物共混物通过将丙烯基弹性体与丙烯 - 其中所述第二共混物具有大于50dg / min的MFR（ASTM D-1238 2.16kg，230℃），其中丙烯类弹性体包含约5％至35％重量的衍生自 乙烯或非丙烯α-烯烃，并且通过DSC测定的熔融热小于80J / g，并且其中丙烯类热塑性树脂具有通过DSC测定的熔化热等于或等于 大于80J / g。

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