公开(公告)号：US08173309B2

公开(公告)日：2012-05-08

申请号：US12068858

申请日：2008-02-12

Applicant: Leonid Gorobinskiy ,  Ju-Yong Kim ,  Man-Seok Han ,  Yong-Kul Lee ,  Chan-Ho Lee ,  Jin-Goo Ahn ,  Jin-Kwang Kim ,  Sung-Chul Lee ,  Kie-Hyun Nam ,  Noboru Sato ,  Alexey Alexandrovichserov

Inventor： Leonid Gorobinskiy ,  Ju-Yong Kim ,  Man-Seok Han ,  Yong-Kul Lee ,  Chan-Ho Lee ,  Jin-Goo Ahn ,  Jin-Kwang Kim ,  Sung-Chul Lee ,  Kie-Hyun Nam ,  Noboru Sato ,  Alexey Alexandrovichserov

IPC: H01M8/06

CPC classification number: C01B3/384 ,  B01J23/42 ,  B01J23/83 ,  B01J27/053 ,  C01B2203/0233 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241 ,  H01M8/0618 ,  H01M8/241 ,  Y02P20/52

Abstract: A reformer for a fuel cell system includes a heating source for generating heat by a reaction of a fuel and an oxidant using an oxidizing catalyst, and a reforming reaction part for generating hydrogen by a reforming catalyst reaction. The oxidizing catalyst includes a solid acid, including a strong acid ion and an inorganic oxide, and a platinum-based metal. The reformer for a fuel cell system can start a fuel oxidation catalyst reaction at a low temperature with the heating source having a simplified structure.

Abstract translation: 用于燃料电池系统的重整器包括通过燃料和氧化剂与氧化剂的反应产生热的加热源，以及通过重整催化剂反应产生氢的重整反应部分。 氧化催化剂包括固体酸，包括强酸离子和无机氧化物，以及铂族金属。 用于燃料电池系统的重整器可以在低温下开始燃料氧化催化剂反应，其中加热源具有简化的结构。

公开(公告)号：US08017088B2

公开(公告)日：2011-09-13

申请号：US11528976

申请日：2006-09-27

Applicant: Sung-Chul Lee ,  Ju-Yong Kim ,  Chan-Ho Lee ,  Dong-Myung Suh ,  Jin-Kwang Kim ,  Jin-Goo Ahn ,  Man-Seok Han ,  Yong-Kul Lee ,  Dong-Uk Lee ,  Leonid Gorobinskiy

Inventor： Sung-Chul Lee ,  Ju-Yong Kim ,  Chan-Ho Lee ,  Dong-Myung Suh ,  Jin-Kwang Kim ,  Jin-Goo Ahn ,  Man-Seok Han ,  Yong-Kul Lee ,  Dong-Uk Lee ,  Leonid Gorobinskiy

IPC: B01J8/04

CPC classification number: B01J8/0285 ,  B01J8/0214 ,  B01J8/0221 ,  B01J8/0496 ,  B01J19/249 ,  B01J2208/00309 ,  B01J2208/00415 ,  B01J2219/2453 ,  B01J2219/2458 ,  B01J2219/2465 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1076 ,  C01B2203/1241 ,  C01B2203/1604 ,  C01B2203/82 ,  H01M8/0618 ,  H01M2008/1095

Abstract: A fuel reformer including a first pipe, a second pipe which is disposed in the first pipe, a main heat source, which includes an oxidation catalyst, filling the second pipe adapted to generate thermal energy with a predetermined temperature range through an oxidation reaction of a fuel using the oxidation catalyst; an auxiliary heat source which includes a torch connected to the second pipe to ignite and burn the gaseous fuel, thereby preheating the oxidation catalyst to within a reaction starting temperature range, and a reforming reaction unit which includes a reforming catalyst filling a space between the first and second pipes to generate a reforming gas containing hydrogen through the reforming reaction of the fuel using the reforming catalyst by using the thermal energy generated by the main heat source.

Abstract translation: 一种燃料重整器，包括第一管，布置在第一管中的第二管，包括氧化催化剂的主热源，填充适于通过氧化反应产生具有预定温度范围的热能的第二管 使用氧化催化剂的燃料; 辅助热源，其包括连接到第二管的炬，以点燃和燃烧气体燃料，从而将氧化催化剂预热到反应开始温度范围内;重整反应单元，其包括重整催化剂，其填充第一 以及第二管道，通过使用由主热源产生的热能通过使用重整催化剂的燃料的重整反应产生含氢的重整气体。

公开(公告)号：US08016900B2

公开(公告)日：2011-09-13

申请号：US11827946

申请日：2007-07-12

Applicant: Sung Chul Lee ,  Ju Yong Kim ,  Yong Kul Lee ,  Man Seok Han ,  Chan Ho Lee ,  Jin Kwang Kim ,  Jin Goo Ahn ,  Dong Uk Lee ,  Leonid Gorobinskiy

Inventor： Sung Chul Lee ,  Ju Yong Kim ,  Yong Kul Lee ,  Man Seok Han ,  Chan Ho Lee ,  Jin Kwang Kim ,  Jin Goo Ahn ,  Dong Uk Lee ,  Leonid Gorobinskiy

IPC: H01M8/04

CPC classification number: H01M8/0668 ,  C01B3/38 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0288 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1076 ,  C01B2203/1247 ,  C01B2203/1604 ,  C01B2203/1619 ,  C01B2203/1676 ,  C01B2203/1685 ,  C10K3/04 ,  H01M8/04022 ,  H01M8/04223 ,  H01M8/0618 ,  H01M8/2457 ,  H01M8/2483 ,  Y02P20/128

Abstract: Disclosed are a carbon monoxide remover and a fuel cell reformer including the same. In the reformer, a reformed gas produced from a reforming reaction unit when the reformer is initially driven is used as a fuel for a heat source unit supplying heat to a water gas shift reaction unit. The carbon monoxide remover is connected to the reforming reaction unit that changes fuel into reformed gas with hydrogen. The carbon monoxide remover lowers carbon monoxide contained in the reformed gas. The carbon monoxide remover includes a heat source unit employing the reformed gas as a fuel; and a water gas shift reaction unit provided with a shift catalyst using heat from the heat source unit. The shift catalyst lowers the concentration of carbon monoxide in the reformed gas through reaction between water and carbon monoxide.

Abstract translation: 公开了一种一氧化碳去除剂和包括其的燃料电池重整器。 在重整器中，当重整器最初被驱动时由重整反应单元产生的重整气体用作向水煤气变换反应单元供热的热源单元的燃料。 一氧化碳去除剂连接到用氢气将燃料转化为重整气体的重整反应单元。 一氧化碳去除剂降低重整气体中所含的一氧化碳。 一氧化碳去除剂包括采用重整气体作为燃料的热源单元; 以及使用来自热源单元的热量设置有换档催化剂的水煤气变换反应单元。 转移催化剂通过水和一氧化碳之间的反应降低重整气体中一氧化碳的浓度。

公开(公告)号：US07842260B2

公开(公告)日：2010-11-30

申请号：US11877562

申请日：2007-10-23

Applicant: Sung-chul Lee ,  Ju-yong Kim ,  Yong-kul Lee ,  Man-seok Han ,  Jun-sic Kim ,  Chan-ho Lee ,  Jin-goo Ahn

Inventor： Sung-chul Lee ,  Ju-yong Kim ,  Yong-kul Lee ,  Man-seok Han ,  Jun-sic Kim ,  Chan-ho Lee ,  Jin-goo Ahn

IPC: B01J8/02 ,  C01B3/02

CPC classification number: B01J19/249 ,  B01J23/40 ,  B01J2219/2455 ,  B01J2219/2459 ,  B01J2219/246 ,  B01J2219/2465 ,  B01J2219/2479 ,  B01J2219/2485

Abstract: Provided is a reaction vessel for a fuel cell, and more particularly to a reaction vessel exhibiting improved thermal efficiency, and a reaction device for a steam reforming reaction for a fuel cell. The reaction device includes a cylindrical reaction catalyst chamber on which a target reaction catalyst for a predetermined target reaction is disposed; and a tubular oxidation catalyst chamber surrounding the reaction catalyst chamber, comprising an oxidation reaction catalyst therein. The reaction device according features an increased contact area between catalyst and gas, and rapidly heating of the gas in contact with the catalyst to a desired reaction temperature.

Abstract translation: 提供一种用于燃料电池的反应容器，更具体地说，涉及一种表现出改善的热效率的反应容器，以及用于燃料电池的蒸汽重整反应的反应装置。 反应装置包括：圆筒状的反应催化剂室，配置有用于规定的目标反应的目标反应催化剂; 以及围绕反应催化剂室的管状氧化催化剂室，其中包含氧化反应催化剂。 反应装置的特征在于催化剂和气体之间的接触面积增加，并且将与催化剂接触的气体快速加热到所需的反应温度。

公开(公告)号：US07771676B2

公开(公告)日：2010-08-10

申请号：US12007362

申请日：2008-01-09

Applicant: In-hyuk Son ,  Hyun Kim ,  Chang-bong Lee ,  Min-jung Oh ,  Man-seok Han ,  Yong-kul Lee ,  Jin-goo Ahn ,  Chan-ho Lee ,  Ju-yong Kim

Inventor： In-hyuk Son ,  Hyun Kim ,  Chang-bong Lee ,  Min-jung Oh ,  Man-seok Han ,  Yong-kul Lee ,  Jin-goo Ahn ,  Chan-ho Lee ,  Ju-yong Kim

IPC: B01J8/02 ,  C01B3/26

CPC classification number: B01J8/025 ,  B01J8/0442 ,  B01J8/0457 ,  B01J2208/00061 ,  B01J2208/00194 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00716 ,  C01B3/32 ,  C01B3/34 ,  C01B3/583 ,  C01B2203/02 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1619 ,  C01B2203/169 ,  C01B2203/1695 ,  F28D1/024 ,  F28D1/05316 ,  F28D2021/0022 ,  F28F9/26 ,  F28F27/00

Abstract: A PROX reactor integrated with a heat exchanger and an operating method thereof capable of effectively controlling temperature of a preferential oxidation reactor so as to obtain optimal activation and yield. The PROX reactor integrated with a heat exchanger of the present invention includes a pipe having an inlet and an outlet, a heat exchanger cooling gas passing through the pipe, a catalyst part positioned at the rear end of the heat exchanger, upon considering the flow of gas, and shifting carbon monoxide contained in the gas into other substances; and a temperature sensor measuring the temperature of the gas coming out through the catalyst part.

Abstract translation: 一种与热交换器一体化的PROX反应器及其操作方法，其能够有效地控制优先氧化反应器的温度，以获得最佳的活化和产率。 与本发明的热交换器集成的PROX反应器包括具有入口和出口的管道，通过管道的热交换器冷却气体，位于热交换器后端的催化剂部件，考虑到 将气体中包含的一氧化碳转化为其他物质; 以及测量通过催化剂部分出来的气体的温度的温度传感器。

公开(公告)号：US20080268301A1

公开(公告)日：2008-10-30

申请号：US12068227

申请日：2008-02-04

Applicant: Sung-Chul Lee ,  Ju-Yong Kim ,  Yong-Kul Lee ,  Man-Seok Han ,  Jun-Sik Kim ,  Jin-Goo Ahn

Inventor： Sung-Chul Lee ,  Ju-Yong Kim ,  Yong-Kul Lee ,  Man-Seok Han ,  Jun-Sik Kim ,  Jin-Goo Ahn

IPC: H01M8/18 ,  H01M8/04

CPC classification number: B01J8/0214 ,  B01J8/0257 ,  B01J8/0285 ,  B01J8/0411 ,  B01J8/0465 ,  B01J8/0496 ,  B01J19/2485 ,  B01J2208/00203 ,  B01J2208/00309 ,  B01J2208/00398 ,  C01B3/384 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/0894 ,  C01B2203/1023 ,  C01B2203/1035 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1076 ,  H01M8/0618

Abstract: A fuel reforming apparatus includes an oxidation reaction unit in which an oxidation catalyst is formed, a reforming reaction unit in which a reforming catalyst is formed, and an ignition unit for igniting a hydrocarbon-containing fuel and an oxidant and preheating the oxidation catalyst in an early driving stage. The oxidation reaction unit has a first section and a second section respectively formed opposite to each other with the oxidation catalyst interposed therebetween and forms a stream of the fuel and the oxidant flowing to the second section through the oxidation catalyst from the first section, the ignition unit being located in the second section.

Abstract translation: 燃料重整装置包括其中形成氧化催化剂的氧化反应单元，其中形成重整催化剂的重整反应单元和用于点燃含烃燃料和氧化剂的点火单元，并将氧化催化剂预热到 早期驾驶阶段 氧化反应单元具有分别形成为彼此相对的第一部分和第二部分，其间介于氧化催化剂之间，并且形成通过氧化催化剂从第一部分流到第二部分的燃料和氧化剂流，点火 单元位于第二部分。

公开(公告)号：US20080241019A1

公开(公告)日：2008-10-02

申请号：US11877562

申请日：2007-10-23

Applicant: Sung-chul Lee ,  Ju-yong Kim ,  Yong-kul Lee ,  Man-seok Han ,  Jun-sic Kim ,  Chan-ho Lee ,  Jin-goo Ahn

Inventor： Sung-chul Lee ,  Ju-yong Kim ,  Yong-kul Lee ,  Man-seok Han ,  Jun-sic Kim ,  Chan-ho Lee ,  Jin-goo Ahn

IPC: B01J15/00 ,  B01J19/00

CPC classification number: B01J19/249 ,  B01J23/40 ,  B01J2219/2455 ,  B01J2219/2459 ,  B01J2219/246 ,  B01J2219/2465 ,  B01J2219/2479 ,  B01J2219/2485

Abstract: Provided is a reaction vessel for a fuel cell, and more particularly to a reaction vessel exhibiting improved thermal efficiency, and a reaction device for a steam reforming reaction for a fuel cell. The reaction device includes a cylindrical reaction catalyst chamber on which a target reaction catalyst for a predetermined target reaction is disposed; and a tubular oxidation catalyst chamber surrounding the reaction catalyst chamber, comprising an oxidation reaction catalyst therein. The reaction device according features an increased contact area between catalyst and gas, and rapidly heating of the gas in contact with the catalyst to a desired reaction temperature.

Abstract translation: 提供一种用于燃料电池的反应容器，更具体地说，涉及一种表现出改善的热效率的反应容器，以及用于燃料电池的蒸汽重整反应的反应装置。 反应装置包括：圆筒状的反应催化剂室，配置有用于规定的目标反应的目标反应催化剂; 以及围绕反应催化剂室的管状氧化催化剂室，其中包含氧化反应催化剂。 反应装置的特征在于催化剂和气体之间的接触面积增加，并且将与催化剂接触的气体快速加热到所需的反应温度。

公开(公告)号：US20080206613A1

公开(公告)日：2008-08-28

申请号：US12068858

申请日：2008-02-12

Applicant: Leonid Gorobinskiy ,  Ju-Yong Kim ,  Man-Seok Han ,  Yong-Kul Lee ,  Chan-Ho Lee ,  Jin-Goo Ahn ,  Jin-Kwang Kim ,  Sung-Chul Lee ,  Kie-Hyun Nam ,  Noboru Sato ,  Alexey Alexandrovichserov

Inventor： Leonid Gorobinskiy ,  Ju-Yong Kim ,  Man-Seok Han ,  Yong-Kul Lee ,  Chan-Ho Lee ,  Jin-Goo Ahn ,  Jin-Kwang Kim ,  Sung-Chul Lee ,  Kie-Hyun Nam ,  Noboru Sato ,  Alexey Alexandrovichserov

IPC: H01M8/06 ,  B01J7/00 ,  B01J19/00

CPC classification number: C01B3/384 ,  B01J23/42 ,  B01J23/83 ,  B01J27/053 ,  C01B2203/0233 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1235 ,  C01B2203/1241 ,  H01M8/0618 ,  H01M8/241 ,  Y02P20/52

Abstract: A reformer for a fuel cell system includes a heating source for generating heat by a reaction of a fuel and an oxidant using an oxidizing catalyst, and a reforming reaction part for generating hydrogen by a reforming catalyst reaction. The oxidizing catalyst includes a solid acid, including a strong acid ion and an inorganic oxide, and a platinum-based metal. The reformer for a fuel cell system can start a fuel oxidation catalyst reaction at a low temperature with the heating source having a simplified structure.

Abstract translation: 用于燃料电池系统的重整器包括通过燃料和氧化剂与氧化剂的反应产生热的加热源，以及通过重整催化剂反应产生氢的重整反应部分。 氧化催化剂包括固体酸，包括强酸离子和无机氧化物，以及铂族金属。 用于燃料电池系统的重整器可以在低温下开始燃料氧化催化剂反应，其中加热源具有简化的结构。

公开(公告)号：US20080166284A1

公开(公告)日：2008-07-10

申请号：US12007362

申请日：2008-01-09

Applicant: In-hyuk Son ,  Hyun Kim ,  Chang-bong Lee ,  Min-jung Oh ,  Man-seok Han ,  Yong-kul Lee ,  Jin-goo Ahn ,  Chan-ho Lee ,  Ju-yong Kim

Inventor： In-hyuk Son ,  Hyun Kim ,  Chang-bong Lee ,  Min-jung Oh ,  Man-seok Han ,  Yong-kul Lee ,  Jin-goo Ahn ,  Chan-ho Lee ,  Ju-yong Kim

IPC: B01D53/62 ,  B01J19/00

CPC classification number: B01J8/025 ,  B01J8/0442 ,  B01J8/0457 ,  B01J2208/00061 ,  B01J2208/00194 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00716 ,  C01B3/32 ,  C01B3/34 ,  C01B3/583 ,  C01B2203/02 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/1619 ,  C01B2203/169 ,  C01B2203/1695 ,  F28D1/024 ,  F28D1/05316 ,  F28D2021/0022 ,  F28F9/26 ,  F28F27/00

Abstract: A PROX reactor integrated with a heat exchanger and an operating method thereof capable of effectively controlling temperature of a preferential oxidation reactor so as to obtain optimal activation and yield. The PROX reactor integrated with a heat exchanger of the present invention includes a pipe having an inlet and an outlet, a heat exchanger cooling gas passing through the pipe, a catalyst part positioned at the rear end of the heat exchanger, upon considering the flow of gas, and shifting carbon monoxide contained in the gas into other substances; and a temperature sensor measuring the temperature of the gas coming out through the catalyst part.

Abstract translation: 一种与热交换器一体化的PROX反应器及其操作方法，其能够有效地控制优先氧化反应器的温度，以获得最佳的活化和产率。 与本发明的热交换器集成的PROX反应器包括具有入口和出口的管道，通过管道的热交换器冷却气体，位于热交换器后端的催化剂部件，考虑到 将气体中包含的一氧化碳转化为其他物质; 以及测量通过催化剂部分出来的气体的温度的温度传感器。

公开(公告)号：US07985506B2

公开(公告)日：2011-07-26

申请号：US12266451

申请日：2008-11-06

Applicant: Sung-Chul Lee ,  Ju-Yong Kim ,  Woo-Cheol Shin ,  Yong-Kul Lee ,  Sang-Jun Kong ,  In-Hyuk Son ,  Jin-Goo Ahn ,  Tae-Keun Kim

Inventor： Sung-Chul Lee ,  Ju-Yong Kim ,  Woo-Cheol Shin ,  Yong-Kul Lee ,  Sang-Jun Kong ,  In-Hyuk Son ,  Jin-Goo Ahn ,  Tae-Keun Kim

IPC: H01M8/18

CPC classification number: C01B3/323 ,  B01J4/002 ,  B01J8/062 ,  B01J8/065 ,  B01J8/067 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2219/00265 ,  C01B3/384 ,  C01B2203/0227 ,  C01B2203/066 ,  C01B2203/0811 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1241 ,  C01B2203/1247 ,  H01M8/0618

Abstract: A fuel cell system and a reformer for a fuel cell system prevents backfire and improves efficiency of heat transfer. The fuel cell system includes a reformer generating hydrogen gas from fuel including hydrogen by a catalytic chemical reaction using heat energy, and at least one electricity generating unit generating electrical energy by an electrochemical reaction between the hydrogen gas and oxygen. The reformer includes a case, a heat source, and a reforming reaction part. The case forms an external shape. The heat source is disposed in the case to generate heat energy by an oxidation reaction between fuel and a catalyst, and includes a mesh, an oxidation catalyst layer formed on a surface of the mesh, and at least one fuel injection nozzle supplying the fuel to the oxidation catalyst layer. The reforming reaction part is disposed in the case to generate hydrogen gas from fuel using the heat energy generated from the heat source.

Abstract translation: 燃料电池系统和用于燃料电池系统的重整器防止回火并提高传热效率。 燃料电池系统包括重整器，其通过使用热能的催化化学反应从包含氢的燃料中产生氢气，以及至少一个通过氢气和氧气之间的电化学反应产生电能的发电单元。 重整器包括壳体，热源和重整反应部件。 外壳形状为外形。 热源通过燃料和催化剂之间的氧化反应设置在壳体中以产生热能，并且包括网，形成在网的表面上的氧化催化剂层，以及至少一个燃料喷嘴，其将燃料供给到 氧化催化剂层。 重整反应部被配置在壳体中，利用从热源产生的热能从燃料产生氢气。