Decorative film, method for producing decorative film, and method for producing three-dimensional molded product provided with decorative film

    公开(公告)号:US11267232B2

    公开(公告)日:2022-03-08

    申请号:US17117567

    申请日:2020-12-10

    Applicant: AGC Inc.

    Abstract: To provide a decorative film in which swelling of a layer containing a fluorinated polymer is suppressed and adhesion of the layer containing the fluorinated polymer is excellent; and a method for producing a three-dimensional molded product provided with a decorative film. The decorative film is characterized by comprising a base film containing a plasticizer; a first layer containing at least one member selected from the group consisting of a polyvinylidene fluoride, a polymethyl methacrylate and a polyurethane; and a second layer containing a fluorinated polymer comprising units based on a fluoroolefin and units based on at least one type of non-fluorinated monomer selected from the group consisting of a vinyl ether, a vinyl ester, an allyl ether and an allyl ester, in this order; wherein the water contact angle of the surface on the first layer side of the second layer is larger than the water contact angle on the second layer side of the first layer, and the difference between the water contact angle of the surface on the first layer side of the second layer and the water contact angle of the surface on the second layer side of the first layer is more than 0° and at most 50°.

    Process for producing coated article

    公开(公告)号:US11135615B2

    公开(公告)日:2021-10-05

    申请号:US16254641

    申请日:2019-01-23

    Applicant: AGC INC.

    Abstract: To provide a process for producing a coated article, capable of producing a coated article having a coating film excellent in weather resistance, using a powder coating material.
    A process for producing a coated article having a substrate, comprising:
    applying a curable powder coating material containing a curable polymer containing no fluorine atom, a curing agent and a pigment to a surface of a substrate, to form a first coating layer composed of the curable powder coating material, then
    applying a powder coating material containing a fluorinated polymer and containing no pigment to a surface of the first coating layer, to form a second coating layer composed of the powder coating material, and
    heating the first coating layer and the second coating layer simultaneously to form a coating film on the surface of the substrate.

    Powder coating material
    14.
    发明授权

    公开(公告)号:US11046861B2

    公开(公告)日:2021-06-29

    申请号:US16598466

    申请日:2019-10-10

    Applicant: AGC Inc.

    Abstract: A powder coating material which has excellent blocking resistance and can form coating films excellent in water repellency is provided.
    The powder coating material of the present invention comprises a fluorinated polymer comprising from 20 to 80 mol % of units based on at least one species selected from the group consisting of CF3—CH═CHF and CF3—CF═CH2, from 18 to 60 mol % of units based on a monomer represented by the formula X1—Z1 (wherein X1 is a specific monovalent polymerizable group, and Z1 is a specific alkyl group, a specific cycloalkyl group or a specific aryl group) and units having a crosslinkable group.

    Anti-biofouling coating material
    15.
    发明授权

    公开(公告)号:US11015065B2

    公开(公告)日:2021-05-25

    申请号:US16282396

    申请日:2019-02-22

    Applicant: AGC Inc.

    Abstract: The present invention has an object to provide an anti-biofouling coating material which is capable of forming a coating film excellent in anti-biofouling properties and adhesiveness. Further, the present invention has another object to provide a ship, etc. and an article to be used in a humid or wetted environment, having, on its surface, a coating film formed by using the above anti-biofouling coating material. Further, the present invention has other objects to provide a method for preventing adhesion of organisms to a ship, etc. and to provide a method for preventing adhesion of fungi or algae to the surface of an article to be used in a humid or wetted environment, by using the above anti-biofouling coating material. The anti-biofouling coating material of the present invention is an anti-biofouling coating material to be applied to the surface of an article in order to prevent adhesion of organisms, which comprises a polymer F being a fluorinated polymer containing units based on a fluoroolefin, and a polymer G being a polymer containing units based on a (meth)acrylate having a polyoxyalkylene chain.

    Powder coating material, method for producing substrate provided with coating film, coated article and fluorinated polymer

    公开(公告)号:US11130870B2

    公开(公告)日:2021-09-28

    申请号:US16502375

    申请日:2019-07-03

    Applicant: AGC Inc.

    Abstract: To provide a powder coating material capable of forming a coating film excellent in impact resistance, flexibility and adhesion to substrate and excellent in surface smoothness even when formed under low temperature film-forming conditions.
    The powder coating material of the present invention is a powder coating material comprising a fluorinated polymer having units based on a fluoroolefin, units based on a monomer represented by the formula X—Z and units based on a monomer represented by the formula CHR21═CR22 (CH2)nCOOH, wherein the content of the units based on a monomer represented by the formula X—Z is from 5 to 20 mol % to all units in the fluorinated polymer, and the fluorinated polymer has a melt viscosity at 170° C. of from 20 to 100 Pa·s (in the formulae, X is a specific monovalent polymerizable group, Z is a specific alkyl group, a specific cycloalkyl group or a specific aryl group, R21 and R22 are each independently a hydrogen atom or a specific alkyl group, and n is an integer of from 0 to 12.

    Powder coating material, method for producing substrate provided with coating film and coated article

    公开(公告)号:US10723825B2

    公开(公告)日:2020-07-28

    申请号:US16040040

    申请日:2018-07-19

    Applicant: AGC Inc.

    Abstract: A powder coating material capable of forming a coating film that is excellent in weather resistance, processability and impact resistance and that improves corrosion resistance of a substrate (in particular, a substrate made of aluminum or of an aluminum alloy), wherein the powder coating material contains a powder of a resin composition, wherein the resin composition contains a fluorinated polymer (A) having a number average molecular weight of from 10,000 to 50,000 and a fluorine content of at least 10 mass %, a resin (B) having a fluorine content of less than 10 mass % or containing no fluorine atom, a curing agent, a plasticizer having a melting point of from 50 to 150° C. and core-shell particles, and wherein the absolute value of the difference between the melting point of the plasticizer and the glass transition temperature of a polymer of a shell portion in the core-shell particles is within 30° C. and the content of the plasticizer is from 5 to 25 parts by mass based on 100 parts by mass of the fluorinated polymer (A).

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