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54 条记录 (耗时 0.044 秒)

    Process for producing block copolymer resin
    11.
    发明授权
    Process for producing block copolymer resin 失效
    制备嵌段共聚物树脂的方法

    公开(公告)号：US4377665A

    公开(公告)日：1983-03-22

    申请号：US316420

    申请日：1981-10-29

    申请人： Toshinori Shiraki ,  Akio Yamori ,  Hideo Morita

    发明人： Toshinori Shiraki ,  Akio Yamori ,  Hideo Morita

    IPC分类号： C08F2/00 ,  C08F297/00 ,  C08F297/04

    CPC分类号： C08F297/04

    摘要： In producing a block copolymer resin having vinyl aromatic hydrocarbon polymer blocks such as of styrene and polymer blocks primarily composed of conjugated diene such as of butadiene successively through living polymers using an organolithium compound as a catalyst in an aliphatic solvent, the vinyl aromatic hydrocarbon monomer for forming the vinyl aromatic hydrocarbon polymer block is added at a controlled rate, at the stage when the vinyl aromatic hydrocarbon content in the polymer formed has reached a certain value, higher than the polymerization rate of the vinyl aromatic hydrocarbon monomer at the polymerization temperature but at a rate which can maintain the solubility parameter of the liquid phase portion in the polymerization system at 7.7 or less, whereby a block copolymer resin with good transparency and impact strength can be produced with good productivity.

    摘要翻译： 在通过使用有机锂化合物作为催化剂的活性聚合物在脂肪族溶剂中生产具有乙烯基芳族烃聚合物嵌段如苯乙烯和主要由共轭二烯如丁二烯组成的聚合物嵌段的嵌段共聚物树脂时，乙烯基芳族烃单体 在所形成的聚合物中的乙烯基芳族烃含量达到一定值，高于乙烯基芳族烃单体在聚合温度下的聚合速率的时候，以可控制的速率加入形成乙烯基芳烃聚合物嵌段 可以将聚合体系中的液相部分的溶解度参数保持在7.7以下的速度，从而可以以良好的生产率制造具有良好透明性和冲击强度的嵌段共聚物树脂。

    Hydrogenated copolymer and composition containing the same
    13.
    发明申请
    Hydrogenated copolymer and composition containing the same 有权
    氢化共聚物和含有它们的组合物

    公开(公告)号：US20080188580A1

    公开(公告)日：2008-08-07

    申请号：US12078570

    申请日：2008-04-01

    申请人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeki Takayama ,  Shigeru Sasaki ,  Katsumi Suzuki ,  Takahiro Hisasue ,  Kazuo Moritou

    发明人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeki Takayama ,  Shigeru Sasaki ,  Katsumi Suzuki ,  Takahiro Hisasue ,  Kazuo Moritou

    IPC分类号： C08F236/10 ,  C08F8/04 ,  C08L9/06

    CPC分类号： C08F8/04 ,  C08F297/04

    摘要： A hydrogenated copolymer obtained by hydrogenating an unhydrogenated copolymer comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated copolymer containing at least one hydrogenated copolymer block (B) which is obtained by hydrogenating an unhydrogenated random copolymer block comprised of conjugated diene monomer units and vinyl aromatic monomer units, wherein the hydrogenated copolymer has the following characteristics: the hydrogenated copolymer has a content of the vinyl aromatic monomer units of from more than 40% by weight to less than 95% by weight; at least one peak of loss tangent (tan δ) is observed at −10 to 80° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer; and substantially no crystallization peak ascribed to the copolymer block (B) is observed at −20 to 80° C. in a differential scanning calorimetry (DSC) chart obtained with respect to the hydrogenated copolymer.

    摘要翻译： 通过氢化包含共轭二烯单体单元和乙烯基芳族单体单元的未氢化共聚物获得的氢化共聚物，所述氢化共聚物含有至少一个氢化共聚物嵌段（B），其通过氢化由共轭二烯单体单元组成的未氢化无规共聚物嵌段和 乙烯基芳族单体单元，其中氢化共聚物具有以下特征：氢化共聚物的乙烯基芳族单体单元的含量大于40重量％至小于95重量％; 在相对于氢化共聚物获得的动态粘弹性光谱中，在-10〜80℃观察到损耗角正切（tanδ）的至少一个峰值。 在相对于氢化共聚物获得的差示扫描量热法（DSC）图中，在-20〜80℃观察到基本上不归属于共聚物嵌段（B）的结晶峰。

    Modified block copolymer
    16.
    发明申请
    Modified block copolymer 有权
    改性嵌段共聚物

    公开(公告)号：US20060128891A1

    公开(公告)日：2006-06-15

    申请号：US11345286

    申请日：2006-02-02

    申请人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    发明人： Nobuaki Kubo ,  Yasuhiro Kusanose ,  Shigeo Nakajima ,  Takaaki Matsuda ,  Shigeki Takayama ,  Toshinori Shiraki

    IPC分类号： C08L53/00 ,  C08F8/30

    CPC分类号： C08F8/00 ,  C08F297/04 ,  C08L53/02 ,  C08L53/025 ,  C08L95/00 ,  C08L2666/02 ,  C09J7/22 ,  C09J7/38 ,  C09J7/387 ,  C09J153/02 ,  C09J153/025 ,  C09J2453/00 ,  C08L2666/24

    摘要： A second order modified block copolymer which can be obtained by reacting a first order modified block copolymer with a second order modifier, wherein the first order modified block copolymer comprises a base block copolymer and a functional group-containing first order modifier group bonded to the base block co-polymer, wherein the base block copolymer comprises at least one polymer block comprised mainly of vinyl aromatic hydrocarbon monomer units and at least one polymer block comprised mainly of conjugated diene monomer units, and wherein the second order modifier has a specific functional group which is reactive to the functional group of the first order modifier group of the first order modified block copolymer. A second order modified block copolymer containing polymer composition comprising the second order modified block copolymer as well as a thermoplastic resin and/or a rubbery polymer.

    摘要翻译： 一种二阶改性嵌段共聚物，其可以通过使一级改性嵌段共聚物与二级改性剂反应而得到，其中一级改性嵌段共聚物包含与碱结合的碱嵌段共聚物和含官能团的一级改性基团 嵌段共聚物，其中所述碱嵌段共聚物包含至少一种主要由乙烯基芳族烃单体单元和至少一个主要由共轭二烯单体单元组成的聚合物嵌段的聚合物嵌段，并且其中所述二级改性剂具有特定官能团， 与一级改性嵌段共聚物的一级改性基团的官能团反应。 含有二级改性嵌段共聚物的聚合物组合物的二阶改性嵌段共聚物以及热塑性树脂和/或橡胶状聚合物。

    Asphalt composition containing hydrogenated conjugated diene copolymer
    17.
    发明申请
    Asphalt composition containing hydrogenated conjugated diene copolymer 审中-公开
    含有氢化共轭二烯共聚物的沥青组合物

    公开(公告)号：US20050107521A1

    公开(公告)日：2005-05-19

    申请号：US10968241

    申请日：2004-10-20

    申请人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeo Nakajima

    发明人： Masahiro Sasagawa ,  Toshinori Shiraki ,  Shigeo Nakajima

    IPC分类号： F16F15/08 ,  C08F8/04 ,  C08F297/04 ,  C08J3/00 ,  C08L53/02 ,  C08L95/00 ,  C08L101/00 ,  C09D121/00 ,  C09D153/02 ,  C09D201/00 ,  C09J153/02 ,  C09K3/00

    CPC分类号： C08L95/00 ,  C08L53/02 ,  C08L53/025 ,  C08L53/00 ,  C08L2666/24

    摘要： An asphalt composition comprising from 0.5 to 50 parts by weight of a hydrogenated conjugated diene copolymer (a) and 100 parts by weight of asphalt (b), wherein the hydrogenated conjugated diene copolymer (a) comprises a polymer block (A) comprising vinyl aromatic monomer units and at least one hydrogenated copolymer block (B) obtained by hydrogenation of a non-hydrogenated random copolymer block comprising conjugated diene monomer units and vinyl aromatic monomer units, the hydrogenated conjugated diene copolymer (a) having the following characteristics (1) to (5): (1) the content of the vinyl aromatic monomer units is more than 30% and not more than 60% by weight per weight of the hydrogenated conjugated diene copolymer; (2) the content of the polymer block (A) is from 5% to 50% by weight per weight of the hydrogenated copolymer; (3) the weight average molecular weight is from 30,000 to 500,000; (4) the percentage of hydrogenation of the double bonds in the conjugated diene monomer units is from 60% to 100%; and (5) at least one peak of the loss tangent (tan δ) is present in the range of from −40° C. to less than −10° C. in a dynamic viscoelastic spectrum obtained with respect to the hydrogenated copolymer.

    摘要翻译： 1.一种沥青组合物，其包含0.5〜50重量份的氢化共轭二烯共聚物（a）和100重量份的沥青（b），其中，所述氢化共轭二烯共聚物（a）包含含有乙烯基芳族化合物 单体单元和至少一种通过氢化包含共轭二烯单体单元和乙烯基芳族单体单元的非氢化无规共聚物嵌段获得的氢化共聚物嵌段（B），具有以下特征（1）至 （5）：（1）乙烯基芳族单体单元的含量相对于氢化共轭二烯共聚物的重量为30重量％以上且60重量％以下。 （2）聚合物嵌段（A）的含量为氢化共聚物重量的5〜50重量％ （3）重均分子量为30,000〜500,000; （4）共轭二烯单体单元中的双键氢化率为60〜100％。 和（5）在相对于氢化共聚物获得的动态粘弹性谱中，损耗角正切（tanδ）的至少一个峰值在-40℃至小于-10℃的范围内。

    Modified block copolymer composition
    18.
    发明授权
    Modified block copolymer composition 失效

    公开(公告)号：US5272209A

    公开(公告)日：1993-12-21

    申请号：US825788

    申请日：1992-01-21

    申请人： Toshinori Shiraki ,  Fusakazu Hayano ,  Hideo Morita

    发明人： Toshinori Shiraki ,  Fusakazu Hayano ,  Hideo Morita

    IPC分类号： C08F8/46 ,  C08F287/00 ,  C08L51/00 ,  C08L77/00 ,  C08L53/02

    CPC分类号： C08F287/00 ,  C08F8/04 ,  C08L51/006 ,  C08L77/00 ,  C08F2810/20 ,  Y10S525/94

    摘要： A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, adrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.

    Modified block copolymer and a process for producing the same
    19.
    发明授权
    Modified block copolymer and a process for producing the same 失效
    改性嵌段共聚物及其制备方法

    公开(公告)号：US5183857A

    公开(公告)日：1993-02-02

    申请号：US443188

    申请日：1989-11-30

    申请人： Toshinori Shiraki ,  Fusakazu Hayano ,  Hideo Morita

    发明人： Toshinori Shiraki ,  Fusakazu Hayano ,  Hideo Morita

    IPC分类号： C08F8/46 ,  C08F287/00 ,  C08L51/00 ,  C08L77/00

    CPC分类号： C08F287/00 ,  C08F8/04 ,  C08F8/46 ,  C08L51/006 ,  C08L77/00 ,  C08F2810/20

    摘要： A modified block copolymer composition comprising a thermoplastic polymer and a modified block copolymer consisting essentially of a base block copolymer of a monovinyl substituted aromatic hydrocarbon polymer block and an olefin compound polymer block having an ethylenic unsaturation degree not exceeding 20%, the base block copolymer having a molecular unit containing a carboxylic acid group and/or a group derived therefrom grafted thereto. The modified block copolymer composition of the present invention is a resinous composition excellent in impact resistance, adhesion, paint adhesion, weatherability, resistance to thermal deterioration, transparency and gloss or a rubbery or leather-like composition excellent in heat resistance, adrasion resistance, compression set resistance, adhesion, transparency, oil resistance, weatherability and resistance to heat aging.