公开(公告)号：US08030333B2

公开(公告)日：2011-10-04

申请号：US12771486

申请日：2010-04-30

申请人： Akira Fujishima ,  Isao Aoki ,  Keiji Kamiyama

发明人： Akira Fujishima ,  Isao Aoki ,  Keiji Kamiyama

IPC分类号： A61K31/04 ,  C07D215/38

CPC分类号： C07D401/12 ,  A61K31/4439 ,  C07B2200/13

摘要： A novel crystal of (R)-2-[[[3-methyl-4-(2,2,2-trifluoroethoxy)-2-pyridinyl]methyl]sulfinyl]-1H-benzimidazole or a salt thereof of the present invention is useful for an excellent antiulcer agent.

摘要翻译： （R）-2 - [[3-甲基-4-（2,2,2-三氟乙氧基）-2-吡啶基]甲基]亚磺酰基] -1H-苯并咪唑或其盐的新结晶为 适用于优秀的抗溃疡剂。

公开(公告)号：US07737282B2

公开(公告)日：2010-06-15

申请号：US12393409

申请日：2009-02-26

申请人： Akira Fujishima ,  Isao Aoki ,  Keiji Kamiyama

发明人： Akira Fujishima ,  Isao Aoki ,  Keiji Kamiyama

IPC分类号： C07D215/38

CPC分类号： C07D401/12 ,  A61K31/4439 ,  C07B2200/13

摘要： A novel crystal of (R)-2-[[[3-methyl-4-(2,2,2-trifluoroethoxy)-2-pyridinyl]methyl]sulfinyl]-1H-benzimidazole or a salt thereof of the present invention is useful for an excellent antiulcer agent.

摘要翻译： （R）-2 - [[3-甲基-4-（2,2,2-三氟乙氧基）-2-吡啶基]甲基]亚磺酰基] -1H-苯并咪唑或其盐的新结晶为 适用于优秀的抗溃疡剂。

公开(公告)号：US20100062281A1

公开(公告)日：2010-03-11

申请号：US12226827

申请日：2007-01-31

申请人： Christopher Cordonier ,  Tetsuya Shichi ,  Takafumi Numata ,  Kenichi Katsumata ,  Akimasa Nakamura ,  Yasuhiro Katsumata ,  Teruo Komine ,  Kenichirou Amemiya ,  Makoto Yamashita ,  Akira Fujishima

发明人： Christopher Cordonier ,  Tetsuya Shichi ,  Takafumi Numata ,  Kenichi Katsumata ,  Akimasa Nakamura ,  Yasuhiro Katsumata ,  Teruo Komine ,  Kenichirou Amemiya ,  Makoto Yamashita ,  Akira Fujishima

IPC分类号： B32B9/04 ,  B05D5/12 ,  H01B1/12

CPC分类号： C01G23/053 ,  B01J21/066 ,  B01J37/0219 ,  C01P2002/84 ,  C09C1/3607 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/1279 ,  Y10T428/31678

摘要： The present invention provides a technology related to a conductive film which is high in transparency, conductivity, and adhesiveness to a base plate. The present invention also provides a coating liquid including metal materials reacting with a ligand represented by Chemical Formula 1 and including indium (In), tin (Sn), or both thereof. Each of R21—R24 in the Chemical Formula 1 is one of the followings (1)-(11) and X11 and X12 is either hetero atoms or carboxylic acid. (1) a group represented by ClH2l+1 (aforementioned l is an integral number of 0 to 4), (2) a group represented by CmH2m (aforementioned m is an integral number of 2 to 4), (3) a group represented by CnH2n−1 (aforementioned n is an integral number of 2 to 4), (4) a group represented by COOR (aforementioned R is CpH2p+1 (aforementioned p is an integral number of 0 to 4) or a group represented by R═C6H5), (5) a group represented by aldehyde, ketones, COCqH2q+1 (aforementioned q is an integral number of 0 to 4), or benzophenone, (6) hydroxyl (OH) or ethers, (7) amine (NH2) or alkylamine, (8) amide (9) halogens (10) nitrile (CN) (11) nitro (NO2)

摘要翻译： 本发明提供了与基板的透明性，导电性和粘合性高的导电膜相关的技术。 本发明还提供了包含与由化学式1表示的配体反应并包括铟（In），锡（Sn）或其二者的金属材料的涂布液。 化学式1中的R 21 -R 24各自为以下（1） - （11）之一，X 11和X 12为杂原子或羧酸。 （1）由ClH2l + 1表示的基团（上述l为0〜4的整数），（2）由CmH2m表示的基团（上述m为2〜4的整数），（3）表示的基团 由CnH2n-1（上述n为2〜4的整数），（4）由COOR表示的基团（上述R为CpH2p + 1（上述p为0〜4的整数）或由R ≡C6H5），（5）由醛，酮，COCqH2q + 1（上述q为0〜4的整数）表示的基团，或二苯甲酮，（6）羟基（OH）或醚，（7）胺（NH 2 ）或烷基胺，（8）酰胺（9）卤素（10）腈（CN）（11）硝基（NO 2）

公开(公告)号：US07187733B2

公开(公告)日：2007-03-06

申请号：US10413652

申请日：2003-04-15

申请人： Akira Fujishima ,  Kenji Adachi ,  Hirotoshi Takeuchi ,  Yasuo Oba ,  Ippei Kanno ,  Hiroaki Ozeki

发明人： Akira Fujishima ,  Kenji Adachi ,  Hirotoshi Takeuchi ,  Yasuo Oba ,  Ippei Kanno ,  Hiroaki Ozeki

IPC分类号： H04L27/08

CPC分类号： H03G3/3068

摘要： A high-frequency signal receiver includes a variable gain amplifier for amplifying a high frequency signal input thereto, a local oscillator, a mixer for mixing a signal output from the variable gain amplifier and a signal output from the local oscillator, a filter for receiving a signal output from the mixer, a gain controller for outputting a voltage according to the signal output from the mixer; and a weighting circuit for weighting and summing a control voltage and the signal output from the gain controller for controlling the gain of the variable gain amplifier. The high-frequency signal receiver hence creates a small amount of signal error even when the input signal includes a large interference signal adjacent to a desired signal.

摘要翻译： 高频信号接收机包括用于放大输入到其中的高频信号的可变增益放大器，本地振荡器，用于混合从可变增益放大器输出的信号和从本地振荡器输出的信号的混频器，用于接收 来自混频器的信号输出;增益控制器，用于根据从混频器输出的信号输出电压; 以及用于对控制电压进行加权和求和并从增益控制器输出的信号用于控制可变增益放大器的增益的加权电路。 因此，即使当输入信号包括与期望信号相邻的大的干扰信号时，高频信号接收器也产生少量的信号误差。

公开(公告)号：US06737145B1

公开(公告)日：2004-05-18

申请号：US09807904

申请日：2001-06-08

申请人： Toshiya Watanabe ,  Kazuhito Hashimoto ,  Akira Fujishima ,  Kazuyuki Takami ,  Norihiro Nakayama ,  Taro Suzuki ,  Naoki Tanaka ,  Eisuke Tachibana ,  Tatsuhiko Adachi

发明人： Toshiya Watanabe ,  Kazuhito Hashimoto ,  Akira Fujishima ,  Kazuyuki Takami ,  Norihiro Nakayama ,  Taro Suzuki ,  Naoki Tanaka ,  Eisuke Tachibana ,  Tatsuhiko Adachi

IPC分类号： B32B514

CPC分类号： C08F8/42 ,  Y10T428/31504 ,  Y10T428/31855 ,  Y10T428/31935

摘要： The present invention is concerned with an organic-inorganic composite graded material containing a composite material formed by chemically bonding an organic polymer compound and a metallic compound and having a component graded structure in which the content of the metallic compound continuously changes in the depth direction from the material surface, a process for the production of the above organic-inorganic composite graded material by forming a coating layer composed of a specific coating solution for forming the organic-inorganic composite film on an organic substrate and drying the coating layer under heat, a coating agent composed of the above organic-inorganic composite graded material for forming a coating film, and an article coated with the above coating agent.

摘要翻译： 本发明涉及含有通过化学键合有机高分子化合物和金属化合物形成的复合材料的有机 - 无机复合分级材料，并且具有其中金属化合物的含量在深度方向上连续变化的组分渐变结构 材料表面，通过在有机基材上形成有机无机复合膜的特定涂布溶液形成涂层并在加热下干燥涂层来生产上述有机 - 无机复合分级材料的方法， 由上述用于形成涂膜的有机 - 无机复合分级材料组成的涂布剂和涂覆有上述涂布剂的制品。

公开(公告)号：US6106955A

公开(公告)日：2000-08-22

申请号：US5584

申请日：1998-01-12

申请人： Takatoshi Ogawa ,  Toshio Saito ,  Sadatoshi Ohno ,  Atsumichi Kushibe ,  Fumio Kamikubo ,  Tatsuya Yasunaga ,  Takashi Kato ,  Yoshimasa Ito ,  Akira Fujishima ,  Kazuhito Hashimoto

发明人： Takatoshi Ogawa ,  Toshio Saito ,  Sadatoshi Ohno ,  Atsumichi Kushibe ,  Fumio Kamikubo ,  Tatsuya Yasunaga ,  Takashi Kato ,  Yoshimasa Ito ,  Akira Fujishima ,  Kazuhito Hashimoto

IPC分类号： B01J35/00 ,  B01J37/02 ,  C25D11/26 ,  B32B9/04 ,  C07G1/00 ,  C09C1/36

CPC分类号： B01J37/0244 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0226 ,  C25D11/26 ,  Y10T428/252

摘要： A metal material having a photocatalytic activity which comprises an anodized layer and a thin layer containing titanium oxide powder which are heat treated are sequentially laminated on the surface of a substrate comprising metal material including titanium. By anodically oxidizing the metal material including titanium, an anodized layer is formed on the surface thereof. A thin layer containing titanium oxide powder is further coated on this surface, and heat treatment is carried out before and/or after forming this thin layer containing titanium oxide powder.

摘要翻译： 具有光催化活性的金属材料，其包含阳极氧化层和包含经过热处理的氧化钛粉末的薄层依次层压在包含钛的金属材料的基材的表面上。 通过阳极氧化包括钛的金属材料，在其表面上形成阳极氧化层。 在该表面上进一步涂布含有氧化钛粉末的薄层，在形成含有氧化钛粉末的薄层之前和/或之后进行热处理。

公开(公告)号：US6099695A

公开(公告)日：2000-08-08

申请号：US910207

申请日：1997-08-13

申请人： Akira Fujishima ,  Kazuhito Hashimoto ,  Shuzo Moroto ,  Masao Ando ,  Masako Sakai

发明人： Akira Fujishima ,  Kazuhito Hashimoto ,  Shuzo Moroto ,  Masao Ando ,  Masako Sakai

IPC分类号： B01D53/86 ,  B01J23/60 ,  B01J33/00 ,  C01B13/14 ,  C01B31/20

CPC分类号： B01D53/864 ,  B01D53/86 ,  B01J23/60

摘要： A ZnO--Pd composite catalyst wherein Pd is dispersed and fixed on the surface of ZnO is produced by ion adsorption process having the steps of soaking ZnO in an acid solution of Pd to adsorb Pd ions (Pd.sup.2+) onto the surface of ZnO; and reducing the adsorbed Pd ions to metallic Pd particles so that the metallic Pd particles are substantially evenly deposited on the surface of ZnO. The ZnO--Pd composite catalyst provides a stable and continuing CO oxidizing capability, without light irradiation, even when the air to be treated contains sulfur compounds such as H.sub.2 S and SOx.

摘要翻译： 通过离子吸附法制备了Pd分散固定在ZnO表面的ZnO-Pd复合催化剂，其工序有：将ZnO浸入Pd的酸性溶液中，将Pd离子（Pd2 +）吸附到ZnO的表面上; 并将吸附的Pd离子还原成金属Pd颗粒，使得金属Pd颗粒基本上均匀地沉积在ZnO的表面上。 即使待处理的空气含有硫化合物如H 2 S和SO x，ZnO-Pd复合催化剂提供了稳定且持续的CO氧化能力，而不需要光照射。

公开(公告)号：US6090489A

公开(公告)日：2000-07-18

申请号：US91692

申请日：1998-06-19

申请人： Makoto Hayakawa ,  Eiichi Kojima ,  Keiichiro Norimoto ,  Mitsuyoshi Machida ,  Atsushi Kitamura ,  Toshiya Watanabe ,  Makoto Chikuni ,  Akira Fujishima ,  Kazuhito Hashimoto

发明人： Makoto Hayakawa ,  Eiichi Kojima ,  Keiichiro Norimoto ,  Mitsuyoshi Machida ,  Atsushi Kitamura ,  Toshiya Watanabe ,  Makoto Chikuni ,  Akira Fujishima ,  Kazuhito Hashimoto

IPC分类号： C03C17/23 ,  C03C17/25 ,  C09K3/18 ,  G02B1/10 ,  B32B9/00 ,  B05D3/04

CPC分类号： G02B1/105 ,  C03C17/23 ,  C03C17/256 ,  C09K3/18 ,  C03C2217/212 ,  C03C2217/229 ,  C03C2217/71 ,  C03C2218/113 ,  C03C2218/32 ,  Y10T428/31

摘要： A method for hydrophilifying the surface of a substrate by taking advantage of photocatalytic action. The substrate has a photocatalytic titania coating (10). The surface of the photocatalytic coating (10) bears the solid acid that increases a hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy in the solid/gas interface of the coating. Photoexcitation of the photocatalyst enhances the hydrogen bond component (.gamma..sub.S.sup.h) in the surface energy of the photocatalytic coating (10), accelerating the physical adsorption of molecules of water in the atmosphere through a hydrogen bond (16) onto hydrogen atoms in a terminal OH group (12), bonded to a titanium atom, and a bridge OH group (14) on the surface of the coating. This results in the formation of a high density, physically adsorbed water layer (18) on the surface of the photocatalytic coating (10), thus permitting the surface of the substrate to be easily hydrophilified. The method is applicable to antifogging, antifouling, selfcleaning and cleaning of articles.

摘要翻译： 利用光催化作用亲水化底物表面的方法。 该基底具有光催化二氧化钛涂层（10）。 光催化涂层（10）的表面承载增加涂层固体/气体界面中表面能的氢键成分（γSh）的固体酸。 光催化剂的光激发增强了光催化涂层（10）的表面能中的氢键成分（γSh），通过氢键（16）加速了大气中的水分子在末端OH中的氢原子的物理吸附 与钛原子键合的基团（12）和涂层表面上的桥羟基（14）。 这导致在光催化涂层（10）的表面上形成高密度，物理吸附的水层（18），从而允许基底的表面容易亲水化。 该方法适用于防雾，防污，自清洁和清洁物品。

公开(公告)号：US5939194A

公开(公告)日：1999-08-17

申请号：US987670

申请日：1997-12-09

申请人： Kazuhito Hashimoto ,  Akira Fujishima ,  Toshiya Watanabe ,  Mitsuhide Shimohigoshi ,  Makoto Hayakawa

发明人： Kazuhito Hashimoto ,  Akira Fujishima ,  Toshiya Watanabe ,  Mitsuhide Shimohigoshi ,  Makoto Hayakawa

IPC分类号： C03C17/245 ,  C03C17/25 ,  C09K3/18 ,  G02B1/10 ,  B32B9/04

CPC分类号： C03C17/256 ,  C03C17/2456 ,  C09K3/18 ,  G02B1/105 ,  C03C2217/212 ,  C03C2217/23 ,  C03C2217/71 ,  C03C2218/113 ,  C03C2218/151 ,  Y10T428/31504

摘要： A method for highly hydrophilifying the surface of an article by photoexcitation of a semiconductor photocatalyst and maintaining the hydrophilicity is disclosed. A layer containing a photocatalyst is formed on a substrate. Onto the surface of the layer are fixed a hydroxyl group upon photoexcitation of the photocatalyst and a physically adsorbed water molecule in the vicinity of the hydroxyl group upon photoexcitation of the photocatalyst. Thus, the surface is highly hydrophilified. Further, this surface, simultaneously with the hydrophilification, exhibits higher hydrophobicity.

公开(公告)号：US5851990A

公开(公告)日：1998-12-22

申请号：US231894

申请日：1994-04-22

申请人： Akira Fujishima ,  Tsunehiko Fukuda

发明人： Akira Fujishima ,  Tsunehiko Fukuda

IPC分类号： A61K38/00 ,  A61K38/22 ,  A61P7/02 ,  A61P9/10 ,  A61P17/00 ,  A61P17/02 ,  A61P43/00 ,  C07K14/50 ,  C07K14/52 ,  C12N1/21 ,  C12N15/09 ,  C12N15/18 ,  C12P21/02 ,  C12R1/19 ,  A61K38/18

CPC分类号： C07K14/503 ,  A61K38/00

摘要： A mutein resulting from substitution of cysteins for at least one of the constitutional amino acids has a high stability, and can serve well as a pharmaceutical, such as a healing promoting agent for wounds.

摘要翻译： 由至少一种结构氨基酸取代半胱氨酸而产生的突变蛋白具有高稳定性，可作为药物如伤口愈合促进剂起作用。