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    Process for the preparation of stable ionic dispersions
    11.
    发明授权
    Process for the preparation of stable ionic dispersions 失效
    制备稳定离子分散体的方法

    公开(公告)号：US4310448A

    公开(公告)日：1982-01-12

    申请号：US804842

    申请日：1977-06-08

    Applicant: Artur Reischl

    Inventor： Artur Reischl

    IPC: C08G18/08 ,  C08G18/12 ,  C08G18/40 ,  C08G18/84 ,  C08F8/30 ,  C08K5/05 ,  C08L25/12 ,  C08L75/04

    CPC classification number: C08G18/84 ,  C08G18/08 ,  C08G18/0804 ,  C08G18/12 ,  C08G18/409

    Abstract: The present invention relates to a process for the "in situ" preparation of stable dispersions of polyisocyanate polyaddition products in hydroxyl containing compounds as dispersing agents which comprises reacting1. organic polyisocyanates with2. compounds having primary and/or secondary amino groups and/or primary hydroxyl groups in3. compounds having at least one hydroxyl group, compounds 3 having secondary hydroxyl groups if compounds 2 have primary hydroxyl groups and at least one of the components 1 or 2 having ionic groups and/or groups capable of salt formation, in the presence of from 2 to 50% by weight of water, based on the total quantity of reaction mixture, the improvement which comprises carrying out the polyisocyanate polyaddition reaction in the presence of a polymer latex or the solution of an ionic polyurethane. The invention also relates to the use of the stable dispersions made by the above process in making polyurethane resins.

    Abstract translation: 本发明涉及一种在含羟基化合物中作为分散剂“原位”制备多异氰酸酯加聚产物的稳定分散体的方法，该方法包括使有机多异氰酸酯与具有伯和/或仲氨基和/或 具有至少一个羟基的化合物中的伯羟基，如果化合物2具有伯羟基，化合物3具有仲羟基，并且具有离子基团和/或能够形成盐的基团的组分1或2中的至少一个在 基于反应混合物的总量，存在2至50重量％的水，其改进包括在聚合物胶乳或离子型聚氨酯溶液的存在下进行多异氰酸酯加聚反应。 本发明还涉及通过上述方法制备的稳定分散体在制备聚氨酯树脂中的用途。

    Process for the preparation of stable ionic dispersions of polyisocyanate-polyaddition products in hydroxyl containing compounds
    12.
    发明授权
    Process for the preparation of stable ionic dispersions of polyisocyanate-polyaddition products in hydroxyl containing compounds 失效
    在含羟基化合物中制备聚异氰酸酯加成产物的稳定离子分散体的方法

    公开(公告)号：US4305858A

    公开(公告)日：1981-12-15

    申请号：US175989

    申请日：1980-08-07

    Applicant: Artur Reischl

    Inventor： Artur Reischl

    IPC: C08G18/08 ,  C08G18/12 ,  C08G18/84 ,  C08L75/04 ,  C08G18/38

    CPC classification number: C08G18/84 ,  C08G18/08 ,  C08G18/0804 ,  C08G18/12 ,  Y10S264/05 ,  Y10S524/923

    Abstract: This invention relates to a process for the preparation of finely divided, stable and relatively low viscosity dispersions of ionic polyisocyanate polyaddition products in compounds having hydroxyl groups by reacting(1) organic polyisocyanate with(2) compounds having primary and/or secondary amino groups and/or primary hydroxyl groups in(3) compounds having at least one hydroxyl group,with the proviso that compounds (3) have secondary hydroxyl groups if compounds with primary hydroxyl groups are used as compound (2), and further characterized in that at least one of the components (1) or (2) has groups which are ionic and/or capable of salt formation.

    Abstract translation: 本发明涉及通过使（1）有机聚异氰酸酯与（2）具有伯氨基和/或仲氨基的化合物反应制备具有羟基的化合物中的离子多异氰酸酯加聚产物的细分散，稳定和相对低粘度的分散体的方法，以及 （3）具有至少一个羟基的化合物中的/或伯羟基，条件是如果使用具有伯羟基的化合物作为化合物（2），则化合物（3）具有仲羟基，其特征还在于至少 组分（1）或（2）中的一种具有离子和/或能够形成盐的基团。

    Process for the improved working up of effluent
    13.
    发明授权
    Process for the improved working up of effluent 失效
    改善污水处理工艺

    公开(公告)号：US4287069A

    公开(公告)日：1981-09-01

    申请号：US146919

    申请日：1980-05-05

    Applicant: Artur Reischl ,  Kurt Mack ,  Friedhelm Sahlmen

    Inventor： Artur Reischl ,  Kurt Mack ,  Friedhelm Sahlmen

    IPC: B01D21/01 ,  C02F1/54 ,  C02F3/12 ,  C02F11/12 ,  C02F11/14

    CPC classification number: C02F1/54 ,  C02F11/12 ,  Y10S210/919

    Abstract: The instant invention is directed to a process for the separation of aqueous sludges in the purification of effluents in purification plants, comprising:(a) mixing organic and/or inorganic aqueous sludges with ground monomer-free tolylene diisocyanate (TDI) distillation residues having a mean particle size of less than 2 mm;(b) removing the water from the resulting purified sludges; and(c) disposing of the purified sludges.

    Abstract translation: 本发明涉及一种用于在净化装置中净化污水中的水性污泥分离的方法，其包括：（a）将有机和/或无机水性污泥与研磨的无单体的甲苯二异氰酸酯（TDI）蒸馏残余物混合， 平均粒径小于2mm; （b）从所产生的净化污泥中除去水; 和（c）处理纯化的污泥。

    Foam-containing polyurethane(urea) compositions and process for the preparation thereof
    15.
    发明授权
    Foam-containing polyurethane(urea) compositions and process for the preparation thereof 失效
    含泡沫聚氨酯（尿素）组合物及其制备方法

    公开(公告)号：US4801621A

    公开(公告)日：1989-01-31

    申请号：US141735

    申请日：1988-01-11

    Applicant: Artur Reischl

    Inventor： Artur Reischl

    IPC: C08G18/00 ,  B01D17/02 ,  B01D39/04 ,  C02F3/10 ,  C08G18/08 ,  C08G18/10 ,  C08G18/65 ,  C08G18/66 ,  C08J9/00 ,  C08J9/33 ,  C08L75/00 ,  C12N11/08

    CPC classification number: C12N11/08 ,  B01D17/0202 ,  B01D39/04 ,  C02F3/10 ,  C08G18/0814 ,  C08G18/10 ,  Y02W10/15 ,  Y10S521/905

    Abstract: This invention relates to polyurethane(urea) compositions which contain foam and which are preferably cationically modified, contain non-abrasively bonded fillers and have a very high water absorbability (WAF).Production is effected by reacting isocyanate-terminated prepolymers with a quantity of water far exceeding the stoichiometric quantity in the presence of foams in particle or film form. The reaction mixture may also contain lignite powder and/or peat, other inorganic and organic fillers and/or biomasses (living cells, living bacteria, enzymes).The polyurethane(urea) compositions contain up to 95% by weight of foam particles and may contain further fillers (preferably lignite and/or peat). The compositions are swollen and have a high water content during production. Their water absorbability (WAF) when suspended in water is 33 to 97% by weight of water. They can be used as carriers in microbic synthesis processes for the production of complicated organic compounds (when they have incorporated biomasses) as special carriers for the growth of plants, as filter agents or as adsorbents for non water-soluble liquids [for example, crude oil or petrol].

    Abstract translation: 本发明涉及包含泡沫并且优选阳离子改性的聚氨酯（脲）组合物，其含有非磨蚀性粘结的填料并且具有非常高的吸水性（WAF）。 通过异氰酸酯封端的预聚物与在存在颗粒或膜形式的泡沫存在下远远超过化学计量的水的反应来进行生产。 反应混合物还可以含有褐煤粉和/或泥炭，其它无机和有机填料和/或生物质（活细胞，活细菌，酶）。 聚氨酯（脲）组合物含有高达95重量％的泡沫颗粒，并且可以含有另外的填料（优选褐煤和/或泥炭）。 组合物在生产过程中膨胀并具有高含水量。 它们在水中悬浮时的吸水率（WAF）为33〜97重量％。 它们可以用作微生物合成过程中的载体，用于生产复杂的有机化合物（当它们已经加入生物质时）作为植物生长的特殊载体，作为过滤剂或作为非水溶性液体的吸附剂[例如粗品 油或汽油]。

    Foam-containing polyurethane(urea) compositions and process for the preparation thereof
    16.
    发明授权
    Foam-containing polyurethane(urea) compositions and process for the preparation thereof 失效
    含泡沫聚氨酯（尿素）组合物及其制备方法

    公开(公告)号：US4734439A

    公开(公告)日：1988-03-29

    申请号：US926770

    申请日：1986-11-04

    Applicant: Artur Reischl

    Inventor： Artur Reischl

    IPC: C08G18/00 ,  B01D17/02 ,  B01D39/04 ,  C02F3/10 ,  C08G18/08 ,  C08G18/10 ,  C08G18/65 ,  C08G18/66 ,  C08J9/00 ,  C08J9/33 ,  C08L75/00 ,  C12N11/08 ,  C08J9/42

    CPC classification number: C12N11/08 ,  B01D17/0202 ,  B01D39/04 ,  C02F3/10 ,  C08G18/0814 ,  C08G18/10 ,  Y02W10/15 ,  Y10S521/905

    Abstract: This invention relates to polyurethane(urea) compositions which contain foam and which are preferably cationically modified, contain non-abrasively bonded fillers and have a very high water absorbability (WAF).Production is effected by reacting isocyanate-terminated prepolymers with a quantity of water far exceeding the stoichiometric quantity in the presence of foams in particle or film form. The reaction mixture may also contain lignite powder and/or peat, other inorganic and organic fillers and/or biomasses (living cells, living bacteria, enzymes).The polyurethane(urea) compositions contain up to 95% by weight of foam particles and may contain further fillers (preferably lignite and/or peat). The compositions are swollen and have a high water content during production. Their water absorbability (WAF) when suspended in water is 33 to 97% by weight of water. They can be used as carriers in microbic synthesis processes for the production of complicated organic compounds (when they have incorporated biomasses) as special carriers for the growth of plants, as filter agents or as adsorbents for non water-soluble liquids [for example, crude oil or petrol].

    Abstract translation: 本发明涉及包含泡沫并且优选阳离子改性的聚氨酯（脲）组合物，其含有非磨蚀性粘结的填料并且具有非常高的吸水性（WAF）。 通过异氰酸酯封端的预聚物与在存在颗粒或膜形式的泡沫存在下远远超过化学计量的水的反应来进行生产。 反应混合物还可以含有褐煤粉和/或泥炭，其它无机和有机填料和/或生物质（活细胞，活细菌，酶）。 聚氨酯（脲）组合物含有高达95重量％的泡沫颗粒，并且可以含有另外的填料（优选褐煤和/或泥炭）。 组合物在生产过程中膨胀并具有高含水量。 它们在水中悬浮时的吸水率（WAF）为33〜97重量％。 它们可以用作微生物合成过程中的载体，用于生产复杂的有机化合物（当它们已经加入生物质时）作为植物生长的特殊载体，作为过滤剂或作为非水溶性液体的吸附剂[例如粗品 油或汽油]。

    Process for the preparation of stable dispersions
    19.
    发明授权
    Process for the preparation of stable dispersions 失效
    制备稳定分散体的方法

    公开(公告)号：US4310449A

    公开(公告)日：1982-01-12

    申请号：US804843

    申请日：1977-06-08

    Applicant: Artur Reischl

    Inventor： Artur Reischl

    IPC: C08G18/08 ,  C08G18/12 ,  C08G18/30 ,  C08G18/84 ,  C08F8/30 ,  C08K5/05 ,  C08L25/12 ,  C08L75/04

    CPC classification number: C08G18/84 ,  C08G18/08 ,  C08G18/0804 ,  C08G18/12 ,  C08G18/302

    Abstract: The present invention relates to a process for the in situ preparation of stable dispersions of polyisocyanate polyaddition products in hydroxyl-containing compounds as dispersing agents, by a process which comprises reacting1. organic polyisocyanates with2. compounds having primary and/or secondary amino groups and/or primary hydroxyl groups and/or ammonia in3. compounds having at least one hydroxyl group,compounds 3 having secondary hydroxyl groups if compounds 2 have primary hydroxyl groups and wherein the starting components are reacted together in the presence of more than 4% by weight of water, based on the reaction mixture including water, the process being characterized in that the polyisocyanate polyaddition reaction is carried out in the presence of a polymer latex or in the solution of an ionic, linear polyurethane. If desired, the water is subsequently removed in known manner. The invention also relates to the use of the dispersions made by this process in preparing polyurethane resins.

    Abstract translation: 本发明涉及一种在含羟基化合物作为分散剂中原位制备多异氰酸酯加聚产物的稳定分散体的方法，该方法包括使有机多异氰酸酯与具有伯和/或仲氨基的化合物反应 和/或具有至少一个羟基的化合物中的/或伯羟基和/或氨;如果化合物2具有伯羟基，化合物3具有仲羟基，并且其中起始组分在大​​于4％ 的水，基于包括水的反应混合物，该方法的特征在于多异氰酸酯加聚反应在聚合物胶乳的存在下或在离子型线性聚氨酯的溶液中进行。 如果需要，随后以已知的方式除去水。 本发明还涉及通过该方法制备的分散体在制备聚氨酯树脂中的用途。

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