Abstract:
An aqueous dispersion comprising at least one copolymer, the copolymer being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane, where a water-soluble initiator is used, the metered addition of the olefinically unsaturated monomers is effected in such a way that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers, in the reaction solution is not exceeded over the entire duration of the reaction, and the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer. The invention further relates to the use of the aqueous dispersion for production of coating materials, to a process for producing the aqueous dispersion, to a basecoat comprising the aqueous dispersion, and to the use of the basecoat for coating of automobile bodies and/or parts for installation on automobile bodies.
Abstract:
Disclosed herein is a pigmented aqueous coating composition including at least one binder, at least one mono-, di- and/or triglyceride, and at least one silica compound. Further disclosed herein is a method for producing a multicoat paint system by producing a basecoat or two or more directly consecutive basecoats directly on a substrate optionally coated with a first coat, producing a clearcoat directly on the basecoat or on the topmost of the two or more basecoats, and then jointly curing the one or more basecoats and the clearcoat. At least one of the basecoat materials includes the aqueous coating composition disclosed herein. Additionally disclosed herein is a multicoat paint system obtainable by the disclosed method.
Abstract:
A pigmented aqueous basecoat material that includes a dimer fatty acid/polyesterdiol reaction product which is preparable by reacting (a) dimer fatty acids with (b) at least one polyesterdiol of the general structural formula (I) where: R is a divalent radical including 2-10 carbon atoms; R1 and R2 are independently straight-chain or branched alkylene radicals having 2-10 carbon atoms; X and Y are independently O, S or NR3, where R3 is hydrogen or an alkyl radical having 1-6 carbon atoms; and m and n are selected accordingly such that the polyesterdiol possesses a number-average molecular weight of 450-2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting dimer fatty acid/polyesterdiol reaction product possesses a number-average molecular weight of 1200-5000 g/mol and an acid number
Abstract:
The present invention relates to a reaction product preparable by reacting (a) dimer fatty acids with (b) at least one compound (b) of the general structural formula (I) where R is a C3 to C6 alkylene radical and n correspondingly is selected such that the compound (b) possesses a number-average molecular weight of 120 to 445 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.6/1.7, and the resulting reaction product possesses a number-average molecular weight of 600 to 4000 g/mol and an acid number of less than 10 mg KOH/g. The invention further relates to a pigmented aqueous basecoat material which comprises this reaction product, and to the use of the reaction product in pigmented aqueous basecoat materials for improving adhesion. The present invention further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method.
Abstract:
The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, the polyurethane-polyurea particles comprising, in each case in reacted form, (Z.1.1) at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, and (Z.1.2) at least one polyamine comprising two primary amino groups and one or two secondary amino groups, and the dispersion (PD) consisting to an extent of at least 90 wt % of the polyurethane-polyurea particles and water. The present invention also relates to basecoat materials comprising the dispersion (PD), and to multicoat paint systems produced using the basecoat materials.
Abstract:
The present invention relates to a method for producing a multicoat paint system on a metallic substrate, in which a basecoat or a plurality of directly successive basecoats are produced directly on a metallic substrate coated with a cured electrocoat, a clearcoat is produced directly on the one basecoat or the uppermost of the plurality of basecoats, and then the one or more basecoats and the clearcoat are jointly cured, and wherein at least one basecoat material used for production of the basecoats comprises at least one linear hydroxy-functional reaction product (R) having an acid number of less than 20 mg KOH/g, the preparation of which involves using at least one compound (v) containing two functional groups (v.1) and an aliphatic or araliphatic hydrocarbyl radical (v.2) which is arranged between the functional groups and has 12 to 70 carbons atoms.
Abstract:
The present invention relates to an aqueous coating composition comprising at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by (i) initially charging an aqueous dispersion of at least one polyurethane, and then (ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which (a) a water-soluble initiator is used, (b) the olefinically unsaturated monomers are metered in such that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers used for polymerization, in the reaction solution is not exceeded over the entire reaction time, and (c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer and at least one linear hydroxy-functional reaction product (R) having an acid number less than 20 mg KOH/g, the preparation of which involves using at least one compound (v) containing two functional groups (v.a) and an aliphatic or araliphatic hydrocarbyl radical (v.b) which is arranged between the functional groups and has 12 to 70 carbon atoms. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat coating thus produced.
Abstract:
Disclosed herein are a method of screening coating material compositions for development of new coating formulations in the automotive field, the method making use of measuring, selecting and improving at least one property of a coating material composition or of a wet coating film obtained therefrom, and a method for investigating the influence of certain constituents of coating material compositions on their properties or on the properties of resulting wet coating films obtained therefrom.
Abstract:
Disclosed herein are a method of screening coating material compositions for development of new coating formulations in the automotive field, the method making use of measuring, selecting and improving at least one property of the cured coating films obtained by the disclosed method, and a method for investigating the influence of certain constituents of coating material compositions on the properties of the resulting cured coating films obtained from applying and curing said coating material compositions onto optionally pre-coated surfaces of substrates.
Abstract:
Disclosed herein is a computer-implemented method for training a data-driven model for predicting properties of a chemical mixture. The method includes the steps of obtaining data including history and/or calibration data of a plurality of chemical mixture recipes and properties of each chemical mixture recipe, with each chemical mixture recipe including two or more ingredients, assigning at least one ingredient in each chemical mixture recipe to one of pre-defined substance clusters, each pre-defined substance cluster representing one ingredient or a group of ingredients having similar chemistry, revising each chemical mixture recipe by replacing the at least one ingredient with the assigned pre-defined substance cluster, and providing the revised chemical mixture recipes, together with the properties of the chemical mixture recipes, to a machine learning process in order to train a data-driven model, which is usable for predicting characteristics of properties of a new chemical mixture.