公开(公告)号：US20120177555A1

公开(公告)日：2012-07-12

申请号：US13366461

申请日：2012-02-06

申请人： Bruce A. Keiser ,  Jitendra T. Shah ,  John V. Meier ,  Paul J. Zinn ,  Jianwei Yuan ,  Raul Espinosa ,  Rebecca L Stiles ,  Richard Mimna ,  Wayne M. Carlson

发明人： Bruce A. Keiser ,  Jitendra T. Shah ,  John V. Meier ,  Paul J. Zinn ,  Jianwei Yuan ,  Raul Espinosa ,  Rebecca L Stiles ,  Richard Mimna ,  Wayne M. Carlson

IPC分类号： B01D53/46 ,  B01D53/50

CPC分类号： B01D53/507 ,  B01D53/64 ,  B01D2252/204 ,  B01D2252/2056 ,  B01D2257/602

摘要： A method and composition for the reduction of the emission of selenium into the environment from the burning of fossil fuels with the use of two chemistries, either individually or in combination with each other. The method uses polydithiocarbamic compounds, including polydithiocarbamic compounds derived from a polymer produced from acrylic-x and alkylamine in conjunction with a scrubber process to capture selenium and reduce its emission in aqueous phase blowdown. The method and composition also helps reduce corrosion in the scrubber process.

摘要翻译： 一种方法和组合物，用于通过使用两种化学物质，分别或彼此组合，从化石燃料的燃烧中将硒的排放量减少到环境中。 该方法使用聚二硫代氨基甲酸酯化合物，包括衍生自由丙烯酸x和烷基胺生产的聚合物的聚二硫代氨基甲酸酯化合物与洗涤器方法结合捕获硒并减少其在水相排污中的排放。 该方法和组合物还有助于减少洗涤器过程中的腐蚀。

公开(公告)号：US20110046238A1

公开(公告)日：2011-02-24

申请号：US12546284

申请日：2009-08-24

申请人： Bruce A. Keiser ,  Timothy S. Keizer ,  Brett M. Showalter ,  Tiffany Bohnsack ,  James H. Adair ,  Mylisa Parette ,  Amy Knupp ,  Andrei S. Zelenev ,  Jason R. Burney

发明人： Bruce A. Keiser ,  Timothy S. Keizer ,  Brett M. Showalter ,  Tiffany Bohnsack ,  James H. Adair ,  Mylisa Parette ,  Amy Knupp ,  Andrei S. Zelenev ,  Jason R. Burney

IPC分类号： C09K3/00 ,  C07F9/06 ,  A01N25/00 ,  D06P1/00

CPC分类号： A01N25/08 ,  D06P1/67366

摘要： The present invention relates to a method for forming a calcium-based carrier particle consisting of the calcium-based material, an active, with or without a surface modification, a stabilizing agent, and the related composition. The calcium-based particle is illustrated by the general formula Cax(PO4)y(OH)zR and may also include a silica or silica oxide substituent. R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, sulfates, and water soluble agents and, as needed, a surface modification, S, which may be either organic or inorganic. A stabilizing agent may be necessary to maintain dispersion of the particles in aqueous media. Examples of a surface modifying material and stabilizing agents are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers. As such, the particle can be used in a variety of applications including any of a variety of high temperature, at acidic, neutral, or basic pH, or pressure environments. The carrier particles have applications as diverse as papermaking, water treatment, chemical tracing, personal care, microbiological control, oil recovery, delivery of polymers, for example.

公开(公告)号：US06372089B1

公开(公告)日：2002-04-16

申请号：US09504319

申请日：2000-02-14

申请人： Bruce A. Keiser ,  Maureen B. Nunn ,  Cheng-Sung Huang ,  Dennis I. MacDonald

发明人： Bruce A. Keiser ,  Maureen B. Nunn ,  Cheng-Sung Huang ,  Dennis I. MacDonald

IPC分类号： D21H1768

CPC分类号： C01B33/1435 ,  C01B33/143 ,  D21H17/29 ,  D21H17/68 ,  D21H21/10

摘要： Disclosed are stable, aqueous colloidal silicas having surface area of greater than 700 m2/g and S-values of from 20-50. These colloidal silicas do not require treatment with surface treatment agents such as aluminum to achieve stability. These colloidal silica aquasols can be produced and stored at concentrations of greater than 7 percent by weight SiO2 solids, and even as high as 15 percent by weight solids or higher, and remain stable at room temperature for at least 30 days compared to art-known silica aquasols. These colloidal silica sols demonstrate advantageously improved performance over art-known colloidal silica sols in applications such as in drainage and retention in papermaking processes. Also disclosed are processes for making aqueous colloidal silicas of the invention and the use of such colloidal silicas in papermaking processes.

摘要翻译： 公开了表面积大于700m 2 / g且S值为20-50的稳定的水性胶体二氧化硅。 这些胶体二氧化硅不需要用表面处理剂如铝处理以达到稳定性。 这些胶体二氧化硅水溶胶可以以大于7重量％的SiO 2固体，甚至高达15重量％固体或更高的浓度生产和储存，并且在室温下保持稳定至少30天，与本领域已知的 二氧化硅水溶胶。 这些胶体二氧化硅溶胶在本领域已知的胶体二氧化硅溶胶的应用中，例如在造纸方法中的排水和保留方面，显示出有利地提高的性能。还公开了制备本发明的水性胶体二氧化硅的方法以及这种胶体二氧化硅在造纸方法中的用途。

公开(公告)号：US06361653B1

公开(公告)日：2002-03-26

申请号：US09839017

申请日：2001-04-22

申请人： Bruce A. Keiser ,  James E. Whitten

发明人： Bruce A. Keiser ,  James E. Whitten

IPC分类号： D21H1768

摘要： The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculent and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.

公开(公告)号：US06358364B2

公开(公告)日：2002-03-19

申请号：US09839016

申请日：2001-04-22

申请人： Bruce A. Keiser ,  James E. Whitten

发明人： Bruce A. Keiser ,  James E. Whitten

IPC分类号： D21H1768

CPC分类号： C01B35/10 ,  D21H17/68 ,  D21H21/10

摘要： The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.

摘要翻译： 本发明包括硼硅酸盐助留剂组合物和通过加入硼硅酸盐来改善纸的生产的方法。 硼硅酸盐可以与高分子量合成絮凝剂和/或淀粉结合使用，有或没有添加阳离子凝结剂。 硼硅酸盐材料优选为胶态硼硅酸盐。 公开了制备硼硅酸盐材料的方法。

公开(公告)号：US06310104B1

公开(公告)日：2001-10-30

申请号：US09444622

申请日：1999-11-22

申请人： Bruce A. Keiser ,  James E. Whitten

发明人： Bruce A. Keiser ,  James E. Whitten

IPC分类号： C01B3320

CPC分类号： C01B35/10 ,  D21H17/68 ,  D21H21/10

摘要： The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.

摘要翻译： 本发明包括硼硅酸盐助留剂组合物和通过加入硼硅酸盐来改善纸的生产的方法。 硼硅酸盐可以与高分子量合成絮凝剂和/或淀粉结合使用，有或没有添加阳离子凝结剂。 硼硅酸盐材料优选为胶态硼硅酸盐。 公开了制备硼硅酸盐材料的方法。

公开(公告)号：US4563298A

公开(公告)日：1986-01-07

申请号：US509745

申请日：1983-06-30

申请人： Bruce A. Keiser

发明人： Bruce A. Keiser

IPC分类号： B01J13/00 ,  C04B35/624 ,  C09C1/00 ,  G11B5/708 ,  C04B35/14

CPC分类号： G11B5/708 ,  B01J13/0013 ,  C04B35/624 ,  C09C1/0081 ,  C01P2004/82 ,  C01P2006/22 ,  C01P2006/40 ,  C01P2006/80

摘要： A stable aqueous alkaline metal oxide/silica sol is obtained by adding a water-soluble amine to an acidic metal oxide/silica sol which contains from 5-40% by weight SiO.sub.2, from 1-10.5% by weight of metal oxide, and a water-soluble anionic stabilizing compound selected from the group consisting of water-soluble anionic surfactants having an HLB greater than 8 and water-soluble carboxylic acid polymers with the ratio of metal oxide to water-soluble anionic stabilizing compound being within the range of 0.3:1 to 15:1.

摘要翻译： 通过向含有5-40重量％SiO 2的1-10重量％的金属氧化物的酸性金属氧化物/二氧化硅溶胶中加入水溶性胺得到稳定的碱性金属氧化物/硅溶胶， 选自HLB大于8的水溶性阴离子表面活性剂和金属氧化物与水溶性阴离子稳定化合物的比例的水溶性羧酸聚合物的水溶性阴离子稳定化合物在0.3〜 1到15：1。

公开(公告)号：US09017649B2

公开(公告)日：2015-04-28

申请号：US11389756

申请日：2006-03-27

申请人： Bruce A. Keiser ,  Raymond D. Miller, Jr. ,  Linda S. Strysik ,  David A. Grattan

发明人： Bruce A. Keiser ,  Raymond D. Miller, Jr. ,  Linda S. Strysik ,  David A. Grattan

IPC分类号： A61K8/89 ,  A61K8/81 ,  C01B33/148 ,  C09C1/30 ,  D21H17/68 ,  D21H21/10

CPC分类号： C01B33/1485 ,  C01P2006/12 ,  C09C1/3072 ,  C09C1/309 ,  D21H17/68 ,  D21H21/10

摘要： A method of stabilizing silica-containing anionic microparticles upon mixing of the silica-containing anionic microparticles with hard water comprising adding one or more hardness-abating additives to the hard water prior to mixing of the hard water and the silica-containing anionic microparticles; or adding an effective stabilizing amount of one or more hardness-abating agents to the silica-containing anionic microparticles prior to mixing of the hard water with the silica-containing anionic microparticles and a stabilized composition comprising silica-containing anionic microparticles and an effective stabilizing amount of one or more hardness-abating additives.

摘要翻译： 在含有二氧化硅的阴离子微粒与硬水混合的同时稳定含二氧化硅的阴离子微粒的方法，包括在混合硬水和含二氧化硅的阴离子微粒之前向硬水中加入一种或多种减硬添加剂; 或者在将硬水与含二氧化硅的阴离子性微粒混合之前，向含二氧化硅的阴离子性微粒中添加有效稳定量的一种或多种减硬剂，以及含有二氧化硅的阴离子性微粒和稳定化的组合物， 的一种或多种降低硬度的添加剂。

公开(公告)号：US08936772B2

公开(公告)日：2015-01-20

申请号：US12756548

申请日：2010-04-08

申请人： Bruce A. Keiser ,  Nicholas S. Ergang ,  Richard Mimna

发明人： Bruce A. Keiser ,  Nicholas S. Ergang ,  Richard Mimna

IPC分类号： C01B33/18 ,  C01B33/12 ,  B01J37/03 ,  A23L2/80 ,  B01J21/08 ,  B01J21/12 ,  B01J35/10 ,  B82Y30/00 ,  C09D1/02

CPC分类号： B01J37/03 ,  A23L2/80 ,  B01J21/08 ,  B01J21/12 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B82Y30/00 ,  C01B33/12 ,  C01B33/18 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C09D1/02

摘要： A silica containing composition is disclosed. The silica composition comprising a compound having the following formula (SiO2)x(OH)yMzOaF: wherein M optionally exists and said M is at least one of the following metal or metalloid cations: boron, magnesium, aluminum, calcium, titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, palladium, silver, cadmium, tin, platinum, gold, and bismuth; wherein F optionally exists and said F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of 0.01-100%; and wherein the molar ratio of y/x is equal to 0.01-0.5, the molar ratio of x/z is equal to 0.1-300, and the molar ratio of a/z is dependent on the nature of the metal oxide formed.

摘要翻译： 公开了含二氧化硅的组合物。 二氧化硅组合物包含具有下式（SiO 2）x（OH）y M z O a F的化合物：其中M任选存在，并且所述M是以下金属或准金属阳离子中的至少一种：硼，镁，铝，钙，钛，钒， 锰，铁，钴，镍，铜，锌，锆，钼，钯，银，镉，锡，铂，金和铋; 其中F任选存在并且所述F是以下至少一种：表面积覆盖率为0.01-100％的官能化有机硅烷，含硫有机硅烷，含胺的有机硅烷和含烷基的有机硅烷; 并且其中y / x的摩尔比等于0.01-0.5，x / z的摩尔比等于0.1-300，并且a / z的摩尔比取决于形成的金属氧化物的性质。

公开(公告)号：US08333835B2

公开(公告)日：2012-12-18

申请号：US13242599

申请日：2011-09-23

申请人： Nicholas S. Ergang ,  Bruce A. Keiser ,  Richard Mimna

发明人： Nicholas S. Ergang ,  Bruce A. Keiser ,  Richard Mimna

IPC分类号： C01B33/00 ,  C01B33/113 ,  C01B17/00 ,  C09D1/00

CPC分类号： C09C1/28 ,  C01P2002/54 ,  C01P2006/12 ,  C01P2006/14 ,  C08K3/36 ,  C09C1/3045 ,  C09D7/61 ,  C09D7/69

摘要： A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.

摘要翻译： 公开了含二氧化硅的组合物。 组合物包含具有下式的化合物：（SiO 2）x（OH）yMzSaF。 M包括至少一种金属或准金属阳离子S是任选存在的基于硫的物质，F是以下至少一种：官能化的有机硅烷，含硫有机硅烷，含胺的有机硅烷和含烷基的有机硅烷 在约0.01至约100％的表面积覆盖范围内。 y / x的摩尔比等于约0.01至约0.5，x / z的摩尔比等于约0.5至约300或约0.5至约100，并且a / z的摩尔比为约0.5 至约5。