公开(公告)号：US10787292B2

公开(公告)日：2020-09-29

申请号：US15656721

申请日：2017-07-21

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Andrei Gennadyevich Fadeev ,  James Patrick Hamilton ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Robert Anthony Schaut ,  Susan Lee Schiefelbein ,  Christopher Lee Timmons

IPC: A61J1/14 ,  C03C3/087 ,  C03C21/00 ,  B65D23/08 ,  B65D1/40 ,  C08G73/10 ,  C03C17/34 ,  C03C17/00 ,  C03C17/42 ,  C09D179/08 ,  C03C17/30 ,  C03C17/32 ,  B32B17/06 ,  B65D25/14

Abstract: Disclosed herein are delamination resistant glass pharmaceutical containers which may include an aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to ISO 720-1985 testing standard. The glass containers may also have a compressive stress layer with a depth of layer of greater than 25 μm. A surface compressive stress of the glass containers may be greater than or equal to 350 MPa. The delamination resistant glass pharmaceutical containers may be ion exchange strengthened and the ion exchange strengthening may include treating the delamination resistant glass pharmaceutical container in a molten salt bath for a time less than or equal to 5 hours at a temperature less than or equal to 450° C.

公开(公告)号：US10351469B2

公开(公告)日：2019-07-16

申请号：US15656800

申请日：2017-07-21

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Shandon Dee Hart ,  Guangli Hu ,  Robert George Manley ,  Prantik Mazumder ,  Chandan Kumar Saha

IPC: C03C17/34 ,  C03C23/00 ,  B32B17/06 ,  C03C3/083 ,  C03C15/00 ,  C03C21/00 ,  C03C17/245 ,  C03C17/36 ,  G06F3/041 ,  C03C17/22

Abstract: One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article has an improved average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. In one or more embodiments, the interface exhibits an effective adhesion energy of about less than about 4 J/m2. In some embodiments, the interface is modified by the inclusion of a crack mitigating layer containing an inorganic material between the glass substrate and the film.

公开(公告)号：US20180318169A1

公开(公告)日：2018-11-08

申请号：US16024824

申请日：2018-06-30

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  C03C17/30 ,  B65D23/08 ,  B65D25/34 ,  C03C17/00 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08 ,  B65D65/42

CPC classification number: A61J1/00 ,  A61J1/1468 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Coated pharmaceutical packages are disclosed. The coated pharmaceutical packages may include a glass body formed from one of a borosilicate glass composition that meets Type 1 criteria according to USP or an alkali aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to the ISO 720-1985 testing standard. A low-friction coating may be positioned on at least a portion of the first surface of the glass body the low-friction coating may include a polymer and a coupling agent disposed between the polymer and the first surface of the glass body. A coefficient of friction of the portion of the coated pharmaceutical package with the low-friction coating is at least 20% less than a coefficient of friction of a surface of an uncoated pharmaceutical package formed from the same glass composition.

公开(公告)号：US20170320771A1

公开(公告)日：2017-11-09

申请号：US15656800

申请日：2017-07-21

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Shandon Dee Hart ,  Guangli Hu ,  Robert George Manley ,  Prantik Mazumder ,  Chandan Kumar Saha

IPC: C03C17/34 ,  C03C23/00 ,  B32B17/06 ,  C03C3/083 ,  C03C15/00 ,  C03C21/00 ,  C03C17/245 ,  C03C17/36 ,  G06F3/041 ,  C03C17/22

CPC classification number: C03C17/3452 ,  B32B17/064 ,  C03C3/083 ,  C03C15/00 ,  C03C17/22 ,  C03C17/245 ,  C03C17/3417 ,  C03C17/3435 ,  C03C17/36 ,  C03C17/3607 ,  C03C17/3621 ,  C03C21/002 ,  C03C23/0055 ,  C03C2217/213 ,  C03C2217/214 ,  C03C2217/241 ,  C03C2217/425 ,  C03C2217/78 ,  C03C2217/948 ,  C03C2218/153 ,  C03C2218/17 ,  C03C2218/31 ,  C03C2218/32 ,  G06F3/041 ,  Y10T428/24983

Abstract: One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article has an improved average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. In one or more embodiments, the interface exhibits an effective adhesion energy of about less than about 4 J/m2. In some embodiments, the interface is modified by the inclusion of a crack mitigating layer containing an inorganic material between the glass substrate and the film.

公开(公告)号：US09428302B2

公开(公告)日：2016-08-30

申请号：US14057697

申请日：2013-10-18

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Paul Stephen Danielson ,  Melinda Ann Drake ,  Robert Michael Morena ,  Kaveh Adib ,  James Patrick Hamilton ,  Susan Lee Schiefelbein

IPC: B28B11/00 ,  B28B21/00 ,  A47G19/22 ,  B65D23/08 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C17/00 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C08G73/10 ,  C09D179/08

CPC classification number: B65D23/0814 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C3/087 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C08G73/105 ,  C08G73/1071 ,  C09D179/08 ,  C08K5/544

Abstract: Delamination resistant glass containers with heat-tolerant coatings are disclosed. In one embodiment, a glass container may include a glass body having an interior surface, an exterior surface and a wall thickness extending from the exterior surface to the interior surface. At least the interior surface of the glass body is delamination resistant. The glass container may further include a heat-tolerant coating positioned on at least a portion of the exterior surface of the glass body. The heat-tolerant coating may be thermally stable at temperatures greater than or equal to 260° C. for 30 minutes.

Abstract translation: 公开了具有耐热涂层的耐剥落玻璃容器。 在一个实施例中，玻璃容器可以包括具有内表面，外表面和从外表面延伸到内表面的壁厚的玻璃体。 至少玻璃体的内表面具有防分层性。 玻璃容器还可以包括位于玻璃体的外表面的至少一部分上的耐热涂层。 耐热涂层可以在大于或等于260℃的温度下热稳定30分钟。

公开(公告)号：US20150329416A1

公开(公告)日：2015-11-19

申请号：US14812902

申请日：2015-07-29

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: C03C17/30 ,  A61J1/00 ,  C03C17/32 ,  B65D65/42 ,  C03C17/00 ,  C03C17/42

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Coated pharmaceutical packages are disclosed. In embodiments, a coated pharmaceutical package includes a glass body comprising a first surface. A low-friction coating may be positioned on at least a portion of the first surface of the glass body. The low-friction coating may include a polymer chemical composition. A light transmission through the coated pharmaceutical package may be greater than or equal to about 55% of a light transmission through an uncoated pharmaceutical package for wavelengths from about 400 nm to about 700 nm. The low-friction coating may have a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute.

Abstract translation: 公开了涂覆的药物包装。 在实施方案中，涂覆的药物包装包括包含第一表面的玻璃体。 低摩擦涂层可以位于玻璃体的第一表面的至少一部分上。 低摩擦涂层可以包括聚合物化学组成。 通过涂覆的药物包装的透光率可以大于或等于通过用于波长为约400nm至约700nm的未涂覆药物包装的透光率的约55％。 当以约10℃/分钟的升温速度从150℃升温至350℃时，低摩擦涂层的质量损失小于其质量的约5％。

公开(公告)号：US20150074974A1

公开(公告)日：2015-03-19

申请号：US14547456

申请日：2014-11-19

Applicant: Corning Incorporated

Inventor： Jonathan David Pesansky ,  Chandan Kumar Saha ,  Trevor E. Wilantewicz

IPC: C03C3/097 ,  C03C3/083 ,  C03C21/00 ,  C03C3/087 ,  C03C4/18 ,  C03C3/091 ,  C03C3/085

CPC classification number: C03C3/097 ,  C03C3/083 ,  C03C3/085 ,  C03C3/087 ,  C03C3/091 ,  C03C3/093 ,  C03C21/002 ,  Y10T29/49863 ,  Y10T428/315

Abstract: Disclosed are alkali aluminosilicate glasses having unexpected resistance to indentation cracking. The glasses obtain this high resistance as a result of a high level of surface compression accompanied by a shallow depth of layer. The advantaged glasses show greater resistance to radial crack formation from Vickers indentation than glasses with the same compressive stress, but higher depths of layer.

Abstract translation: 公开了具有意想不到的压痕开裂性的碱性硅铝酸盐玻璃。 由于伴随着浅层深度的高水平表面压缩，玻璃获得了这种高电阻。 有利的眼镜显示出比维氏压痕的径向裂纹形成更大的阻力，而不是具有相同压缩应力的玻璃，但是层的深度更高。

公开(公告)号：US11737951B2

公开(公告)日：2023-08-29

申请号：US17213859

申请日：2021-03-26

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  B65D23/08 ,  C03C17/32 ,  C03C21/00 ,  C03C17/30 ,  C03C17/42 ,  C03C17/00

CPC classification number: A61J1/1468 ,  B65D23/0821 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  Y10T428/1321 ,  Y10T428/24926 ,  Y10T428/265

Abstract: Coated pharmaceutical packages may comprise a glass body formed from a borosilicate glass composition having a Type 1 chemical durability according to USP 660, the glass body having an interior surface and an exterior surface and a wall extending therebetween. A low-friction thermally stable coating having a thickness of ≤1 μm may be positioned on at least a portion of the exterior surface. The low-friction coating may comprise a silane. The portion of the exterior surface of the coated pharmaceutical package may have a coefficient of friction that is at least 20% less than an uncoated pharmaceutical package formed from the same borosilicate glass composition.

公开(公告)号：US20230132277A1

公开(公告)日：2023-04-27

申请号：US18087234

申请日：2022-12-22

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Andrei Gennadyevich Fadeev ,  James Patrick Hamilton ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Robert Anthony Schaut ,  Susan Lee Schiefelbein ,  Christopher Lee Timmons

IPC: C03C3/087 ,  B65D1/40 ,  A61J1/14 ,  C08G73/10 ,  C03C17/34 ,  C03C17/00 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08 ,  C03B23/047 ,  C08K5/544 ,  B65D23/08 ,  C03C17/30 ,  C03C17/32 ,  B32B17/06 ,  B65D25/14

Abstract: Disclosed herein are delamination resistant glass pharmaceutical containers which may include a glass body having a Class HGA1 hydrolytic resistance when tested according to the ISO 720:1985 testing standard. The glass body may have an interior surface and an exterior surface. The interior surface of the glass body does not comprise a boron-rich layer when the glass body is in an as-formed condition. A heat-tolerant coating may be bonded to at least a portion of the exterior surface of the glass body. The heat-tolerant coating may have a coefficient of friction of less than about 0.7 and is thermally stable at a temperature of at least 250° C. for 30 minutes.

公开(公告)号：US20210221733A1

公开(公告)日：2021-07-22

申请号：US17199728

申请日：2021-03-12

Applicant: Corning Incorporated

Inventor： Heather Bossard Decker ,  Shandon Dee Hart ,  Guangli Hu ,  Fei Li ,  James Joseph Price ,  Chandan Kumar Saha

IPC: C03C17/34 ,  C03C17/36 ,  C03C21/00 ,  G06F3/03 ,  C03C17/42 ,  C03C17/38

Abstract: One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article retains its average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. The bridging of a crack from one of the film or the glass substrate into the other of the film or the glass substrate can be prevented by inserting a crack mitigating layer between the glass substrate and the film.