Method and apparatus for top-charging solid waste into a molten metal
bath
    13.
    发明授权
    Method and apparatus for top-charging solid waste into a molten metal bath 失效
    用于将固体废物顶部充入熔融金属浴的方法和装置

    公开(公告)号:US5571486A

    公开(公告)日:1996-11-05

    申请号:US442024

    申请日:1995-05-16

    摘要: A method and apparatus for top-charging a solid waste into a molten metal bath to form a dissociation product are disclosed. The method includes introducing the waste into the molten metal bath through a refractory tube disposed in a reactor, containing the molten metal bath, through which the refractory tube extends. A gas outlet is disposed above the molten metal bath. The refractory tube has a submergible end which is immersed in the molten metal bath and which defines a lower opening at the terminal end of the refractory tube and an elevated opening, whereby a portion of the molten metal bath enters the refractory tube through the lower opening to allow the molten metal bath to remain within the refractory tube while at least partially dissociating the waste to form the dissociation product in the molten metal bath. An oxidizing agent can be directed into the molten metal bath at a rate sufficient to form an gaseous oxygenated product which is discharged from the reactor.

    摘要翻译: 公开了一种用于将固体废物顶部充入熔融金属浴以形成解离产物的方法和装置。 该方法包括通过设置在包含熔融金属浴的反应器中的耐火管将熔融金属浴引入熔融金属浴中,耐火管延伸通过熔融金属浴。 气体出口设置在熔融金属浴池的上方。 耐火管具有浸没在熔融金属浴中的潜水端,并且在耐火管的末端限定了一个下开口和一个升高的开口,从而一部分熔融金属浴通过下开口进入耐火管 以允许熔融金属浴保持在耐火管内,同时至少部分地将废物解离以在熔融金属浴中形成解离产物。 氧化剂可以以足以形成从反应器排出的气态氧化产物的速率引入熔融金属浴中。

    Method for producing a non-radioactive product from a radioactive waste
    14.
    发明授权
    Method for producing a non-radioactive product from a radioactive waste 失效
    从放射性废物生产非放射性物质的方法

    公开(公告)号:US5489734A

    公开(公告)日:1996-02-06

    申请号:US46016

    申请日:1993-04-12

    摘要: A method is disclosed for producing a non-radioactive product from a radioactive waste composition that includes a radioactive component and a non-radioactive component. The method includes directing the radioactive waste into a molten metal bath. A separation agent is directed in the molten metal bath which reacts with a component of the radioactive waste composition to form a reaction product which separates from the remaining component, thereby forming a non-radioactive product. The separation reagent can be, for example, an oxidant, a metal-ligand exchange reagent, or a reducing agent. The non-radioactive product can be a gas, a liquid, or a precipitate.

    摘要翻译: 公开了一种从包括放射性成分和非放射性成分的放射性废物组合物制备非放射性物质的方法。 该方法包括将放射性废物引入熔融金属浴中。 分离剂被引导到熔融金属浴中,其与放射性废物组合物的组分反应形成与剩余组分分离的反应产物,从而形成非放射性产物。 分离试剂可以是例如氧化剂,金属 - 配体交换试剂或还原剂。 非放射性产物可以是气体,液体或沉淀物。

    Method of indirect chemical reduction of metals in waste
    15.
    发明授权
    Method of indirect chemical reduction of metals in waste 失效
    废物中金属间接化学还原的方法

    公开(公告)号:US5358549A

    公开(公告)日:1994-10-25

    申请号:US033846

    申请日:1993-03-19

    摘要: An environmentally sound process is described for the remediation of waste materials that allows the separation, recovery and decontamination of metals. The method includes chemically reducing essentially all of a reducible toxic and potentially hazardous metal-containing component of a waste composition. The waste is directed into a molten metal bath, including a first reducing agent which, under the operating conditions of the molten metal bath, chemically reduces a metal of the metal-containing component to form a dissolved intermediate. A second reducing agent is directed into the molten metal bath. The second reducing agent, under the operations of the molten metal bath, chemically reduces the metal of the dissolved intermediate. The rate at which the second reducing agent is directed into the molten metal bath, relative to the rate at which the component of the waste is directed into the molten metal bath, is sufficient to cause essentially all metal-containing intermediate formed to dissolve in the molten metal bath, thereby indirectly chemically reducing the component of the waste. This indirect reduction technology can remediate a variety of materials, including ash metal-contaminated municipal waste, vitreous slag-like materials and spent metal catalysts, while allowing the recovery of remediable metals.

    摘要翻译: 描述了一种无害环境的过程,用于修复允许金属分离,回收和去污的废料。 该方法包括化学还原废物组合物中所有可还原的有毒和潜在危险的含金属成分。 将废物引入熔融金属浴中,包括第一还原剂,其在熔融金属浴的操作条件下化学还原含金属组分的金属以形成溶解的中间体。 将第二还原剂引入熔融金属浴中。 第二种还原剂在熔融金属浴的作用下化学还原溶解的中间体的金属。 将第二还原剂引入熔融金属浴中的速率相对于废物的成分被引入熔融金属浴的速度足以使基本上所有形成的含金属中间体溶解在 熔融金属浴,从而间接地化学还原废物的成分。 这种间接还原技术可以补救各种材料,包括灰渣金属污染的城市废物,玻璃状炉渣样物料和废金属催化剂,同时允许回收可补救金属。