Polyimide-co-polybenzoxazole copolymer, preparation method thereof, and gas separation membrane comprising the same
    14.
    发明授权
    Polyimide-co-polybenzoxazole copolymer, preparation method thereof, and gas separation membrane comprising the same 有权
    聚酰亚胺 - 共聚苯并恶唑共聚物,其制备方法和包含该聚合物的气体分离膜

    公开(公告)号:US08821617B2

    公开(公告)日:2014-09-02

    申请号:US12920268

    申请日:2008-03-06

    摘要: Disclosed herein are a polyimide-polybenzoxazole copolymer, a method for preparing thereof and a gas separation membrane comprising the same. More specifically, provided are a polyimide-polybenzoxazole copolymer simply prepared through thermal-rearrangement performed by thermally treating a polyimide-poly (hydroxyimide) copolymer as a precursor, a method for preparing the same, and a gas separation membrane comprising the same. The copolymer shows superior gas permeability and gas selectivity, thus being suitable for use in gas separation membranes in various forms such as films, fibers or hollow fibers. The gas separation membrane thus prepared can advantageously endure even harsh conditions such as long operation time acidic conditions and high humidity due to the rigid polymer backbone present in the copolymer.

    摘要翻译: 本文公开了聚酰亚胺 - 聚苯并恶唑共聚物,其制备方法和包含其的气体分离膜。 更具体地,提供了通过热处理作为前体的聚酰亚胺 - 聚(羟基酰亚胺)共聚物,其制备方法和包含该聚酰亚胺 - 聚(羟基酰亚胺)共聚物的前驱体的热重排简单制备的聚酰亚胺 - 聚苯并恶唑共聚物。 该共聚物具有优异的气体渗透性和气体选择性,因此适用于各种形式的气体分离膜,例如膜,纤维或中空纤维。 由此制备的气体分离膜可有利地承受由共聚物中存在的刚性聚合物骨架导致的恶劣条件,例如长时间的酸性条件和高湿度。

    POLYIMIDE-CO-POLYBENZOXAZOLE COPOLYMER, PREPARATION METHOD THEREOF, AND GAS SEPARATION MEMBRANE COMPRISING THE SAME
    15.
    发明申请
    POLYIMIDE-CO-POLYBENZOXAZOLE COPOLYMER, PREPARATION METHOD THEREOF, AND GAS SEPARATION MEMBRANE COMPRISING THE SAME 有权
    聚酰亚胺 - 聚苯并噻唑共聚物,其制备方法和包含其的气体分离膜

    公开(公告)号:US20110065823A1

    公开(公告)日:2011-03-17

    申请号:US12920268

    申请日:2008-03-06

    IPC分类号: C08G73/10 C08J9/00

    摘要: Disclosed herein are a polyimide-polybenzoxazole copolymer, a method for preparing thereof and a gas separation membrane comprising the same. More specifically, provided are a polyimide-polybenzoxazole copolymer simply prepared through thermal-rearrangement performed by thermally treating a polyimide-poly (hydroxyimide) copolymer as a precursor, a method for preparing the same, and a gas separation membrane comprising the same. The copolymer shows superior gas permeability and gas selectivity, thus being suitable for use in gas separation membranes in various forms such as films, fibers or hollow fibers. The gas separation membrane thus prepared can advantageously endure even harsh conditions such as long operation time acidic conditions and high humidity due to the rigid polymer backbone present in the copolymer.

    摘要翻译: 本文公开了聚酰亚胺 - 聚苯并恶唑共聚物,其制备方法和包含其的气体分离膜。 更具体地,提供了通过热处理作为前体的聚酰亚胺 - 聚(羟基酰亚胺)共聚物,其制备方法和包含该聚酰亚胺 - 聚(羟基酰亚胺)共聚物的前驱体的热重排简单制备的聚酰亚胺 - 聚苯并恶唑共聚物。 该共聚物具有优异的气体渗透性和气体选择性,因此适用于各种形式的气体分离膜,例如膜,纤维或中空纤维。 由此制备的气体分离膜可有利地承受由共聚物中存在的刚性聚合物骨架导致的恶劣条件,例如长时间的酸性条件和高湿度。

    PREPARATION METHOD OF POLYBENZOXAZOLES BY THERMAL REARRANGEMENT, POLYBENZOXAZOLES PREPARED THEREBY, AND GAS SEPARATION MEMBRANE COMPRISING THE SAME
    16.
    发明申请
    PREPARATION METHOD OF POLYBENZOXAZOLES BY THERMAL REARRANGEMENT, POLYBENZOXAZOLES PREPARED THEREBY, AND GAS SEPARATION MEMBRANE COMPRISING THE SAME 有权
    通过热解制备聚苯并噻唑的制备方法,制备的聚苯并噻唑和包含其的气体分离膜

    公开(公告)号:US20110009506A1

    公开(公告)日:2011-01-13

    申请号:US12921980

    申请日:2008-03-13

    IPC分类号: C08G69/48 C08G69/08

    摘要: Disclosed herein are a method for preparing a benzoxazole-based polymer by thermal rearrangement, the benzoxazole-based polymer prepared by the method and a gas separation membrane comprising the polymer. More specifically, provided are a method for preparing a benzoxazole-based polymer by subjecting poly(hydroxyamide) as an intermediate to thermal treatment involving dehydration, the benzoxazole-based polymer obtained thereby and gas separation membrane comprising the polymer. The benzoxazole-based polymer of the present invention can be simply prepared by thermally rearrangement via thermal treatment at low temperatures, and thus exhibits superior mechanical and morphological properties and has well-connected microcavities. Due to showing excellent permeability and selectivity for various gases, the benzoxazole-based polymer is suited for application to gas separation membranes, in particular, gas separation membranes for small gases.

    摘要翻译: 本文公开了通过热重排制备苯并恶唑类聚合物的方法,通过该方法制备的苯并恶唑类聚合物和包含聚合物的气体分离膜。 更具体地说,提供了通过使作为中间体的聚(羟基酰胺)作为中间体进行脱水的热处理,由此获得的苯并恶唑类聚合物和包含该聚合物的气体分离膜来制备苯并恶唑类聚合物的方法。 本发明的苯并恶唑类聚合物可以通过在低温下热处理的热重排简单地制备,因此表现出优异的机械和形态特性,并具有良好连接的微腔。 由于显示出优异的各种气体的渗透性和选择性,所以基于苯并恶唑的聚合物适用于气体分离膜,特别是用于小气体的气体分离膜。

    Preparation method of polybenzoxazoles by thermal rearrangement, polybenzoxazoles prepared thereby, and gas separation membrane comprising the same
    17.
    发明授权
    Preparation method of polybenzoxazoles by thermal rearrangement, polybenzoxazoles prepared thereby, and gas separation membrane comprising the same 有权
    通过热重排制备聚苯并恶唑的方法,由其制备的聚苯并恶唑,以及包含其的气体分离膜

    公开(公告)号:US08618244B2

    公开(公告)日:2013-12-31

    申请号:US12921980

    申请日:2008-03-13

    摘要: Disclosed herein are a method for preparing a benzoxazole-based polymer by thermal rearrangement, the benzoxazole-based polymer prepared by the method and a gas separation membrane comprising the polymer. More specifically, provided are a method for preparing a benzoxazole-based polymer by subjecting poly(hydroxyamide) as an intermediate to thermal treatment involving dehydration, the benzoxazole-based polymer obtained thereby and gas separation membrane comprising the polymer. The benzoxazole-based polymer of the present invention can be simply prepared by thermally rearrangement via thermal treatment at low temperatures, and thus exhibits superior mechanical and morphological properties and has well-connected microcavities. Due to showing excellent permeability and selectivity for various gases, the benzoxazole-based polymer is suited for application to gas separation membranes, in particular, gas separation membranes for small gases.

    摘要翻译: 本文公开了通过热重排制备苯并恶唑类聚合物的方法,通过该方法制备的苯并恶唑类聚合物和包含聚合物的气体分离膜。 更具体地说,提供了通过使作为中间体的聚(羟基酰胺)作为中间体进行脱水的热处理,由此获得的苯并恶唑类聚合物和包含该聚合物的气体分离膜来制备苯并恶唑类聚合物的方法。 本发明的苯并恶唑类聚合物可以通过在低温下热处理的热重排简单地制备,因此表现出优异的机械和形态特性,并具有良好连接的微腔。 由于显示出优异的各种气体的渗透性和选择性,所以基于苯并恶唑的聚合物适用于气体分离膜,特别是用于小气体的气体分离膜。