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11.发明授权
公开(公告)号：US5780703A
公开(公告)日：1998-07-14
申请号：US513107
申请日：1995-08-09
Applicant: Clarence D. Chang , Stuart D. Hellring , David O. Marler , Jose G. Santiesteban , James C. Vartuli
Inventor： Clarence D. Chang , Stuart D. Hellring , David O. Marler , Jose G. Santiesteban , James C. Vartuli
IPC: B01J23/30 , B01J23/882 , B01J23/888 , B01J37/03 , C07C2/58 , C07C5/27 , C10G50/00 , C10G35/04
CPC classification number: C10G50/00 , B01J23/30 , B01J23/882 , B01J23/888 , C07C2/58 , C07C5/2772 , B01J37/03 , C07C2521/06 , C07C2523/30
Abstract: A process for converting at least one olefin and at least one isoparaffin to a diesel fuel blending component comprising the steps of contacting the olefin and the isoparaffin with a catalyst comprising an acidic solid comprising a Group IVB metal oxide modified with an oxyanion of a Group VIB metal to provide a diesel fuel. Process conditions can be varied to favor the formation of gasoline, distillate, lube range products or mixtures thereof.
Abstract translation: 一种将至少一种烯烃和至少一种异链烷烃转化为柴油燃料共混组分的方法，包括以下步骤：使烯烃和异链烷烃与包含酸性固体的催化剂接触，所述酸性固体包含用VIB族氧基反应改性的IVB族金属氧化物 金属提供柴油。 工艺条件可以变化以有利于形成汽油，馏出物，润滑剂产品或其混合物。
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公开(公告)号：US5211935A
公开(公告)日：1993-05-18
申请号：US771716
申请日：1991-10-04
Applicant: Clarence D. Chang , Stuart D. Hellring , Randy F. Striebel
Inventor： Clarence D. Chang , Stuart D. Hellring , Randy F. Striebel
CPC classification number: C01B39/265 , B01J29/04 , B01J29/20
Abstract: This invention relates to a new form of crystalline material identified as mordenite-type, to a new and useful method for synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
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公开(公告)号：US5190736A
公开(公告)日：1993-03-02
申请号：US779550
申请日：1991-10-18
Applicant: Stuart D. Hellring , Clarence D. Chang , John D. Lutner
Inventor： Stuart D. Hellring , Clarence D. Chang , John D. Lutner
CPC classification number: B01J29/65 , B01J29/04 , C01B39/445
Abstract: This invention relates to a new form of crystalline material identified as having the structure of ZSM-35, to a new and useful method for synthesizing said crystalline material using 1,4-diaminocyclohexane as directing agent, and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g., hydrocarbon compound, conversion.
Abstract translation: 本发明涉及一种鉴定为具有ZSM-35结构的新形式的结晶材料，涉及使用1,4-二氨基环己烷作为引导剂合成所述结晶材料的新的和有用的方法，以及使用所制备的所述结晶材料 作为有机化合物的催化剂，例如烃化合物，转化。
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公开(公告)号：US4724270A
公开(公告)日：1988-02-09
申请号：US944629
申请日：1986-12-19
Applicant: Clarence D. Chang , Stuart D. Hellring , Richard F. Socha
Inventor： Clarence D. Chang , Stuart D. Hellring , Richard F. Socha
CPC classification number: B01J29/40 , C07C1/20 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/40
Abstract: The acidity of a zeolite catalyst is reduced by calcination in an essentially water-free atmosphere at temperatures above 700.degree. C., preferably from 725.degree. to 800.degree. C., to reduce the alpha value to less than 10 percent of its original value. The low acidity catalysts produced in this way may be used for conversions requiring low acidity, shape selective catalysis, including conversion of oxygenates to hydrocarbons. The calcined, low acidity catalysts exhibit improved selectivity to certain desired products.
Abstract translation: 通过在高于700℃，优选725℃至800℃的温度下在基本上无水的气氛中煅烧来降低沸石催化剂的酸度，以将α值降低到其原始值的10％以下。 以这种方式生产的低酸性催化剂可用于需要低酸度，形状选择性催化的转化，包括将含氧化合物转化为烃。 煅烧的低酸度催化剂表现出对某些所需产物的改进的选择性。
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公开(公告)号：US5453555A
公开(公告)日：1995-09-26
申请号：US158172
申请日：1993-11-22
Applicant: Clarence D. Chang , Stuart D. Hellring
Inventor： Clarence D. Chang , Stuart D. Hellring
CPC classification number: C07C2/864 , C07C2529/40 , C07C2529/70
Abstract: There is provided a process for reacting a 2-arylethanol, such as 2-phenethanol, with an aromatic compound, such as toluene, to produce a 1,2-diarylethane, such as 2-phenethyltoluene. The reaction involves the use of a catalyst comprising an acidic solid oxide, such as ZSM-5, zeolite Beta, MCM-22 or ZSM-12.
Abstract translation: 提供了使2-苯乙醇如2-苯乙醇与芳族化合物如甲苯反应的方法，以制备1,2-二氨基乙烷如2-苯乙基甲苯。 该反应涉及使用包含酸性固体氧化物如ZSM-5，沸石β，MCM-22或ZSM-12的催化剂。
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Patent Agency Ranking
公开(公告)号：US5174977A
公开(公告)日：1992-12-29
申请号：US771572
申请日：1991-10-04
Applicant: Clarence D. Chang , Stuart D. Hellring , Randy F. Striebel
Inventor： Clarence D. Chang , Stuart D. Hellring , Randy F. Striebel
CPC classification number: C01B39/40 , B01J29/40 , Y10S423/22
Abstract: This invention relates to a new form of crystalline material identified as zeolite ZSM-5-type, to a new and useful method for synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
Abstract translation: 本发明涉及一种鉴定为沸石ZSM-5型的新形式的结晶材料，涉及合成所述结晶材料的新的和有用的方法，以及使用根据本文制备的所述结晶材料作为有机化合物的催化剂。 烃化合物，转化。
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公开(公告)号：US5143876A
公开(公告)日：1992-09-01
申请号：US501977
申请日：1990-03-30
Applicant: Clarence D. Chang , Stuart D. Hellring
Inventor： Clarence D. Chang , Stuart D. Hellring
CPC classification number: C01B39/026 , B01J29/40 , B01J29/7007 , B01J29/7011 , B01J29/7415 , B01J29/7423 , B01J2229/12 , B01J2229/16 , B01J2229/32 , B01J2229/36
Abstract: Zeolites (e.g. ZSM-5 and zeolite beta) enriched with hydroxyl groups are prepared by ammonia treatment of sieves which have suffered loss of tetrahedral aluminum from framework positions followed by careful calcination (200.degree.-450.degree. C.). The hydroxyl group created by this method are stable only to 500.degree. C.
Abstract translation: 富含羟基的沸石（例如ZSM-5和沸石β）通过氨处理从框架位置损失四面体铝的筛子制备，然后仔细地煅烧（200-450℃）。 该方法生成的羟基仅在500℃下稳定。
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公开(公告)号：US4760154A
公开(公告)日：1988-07-26
申请号：US789607
申请日：1985-10-21
Applicant: Clarence D. Chang , Stuart D. Hellring
Inventor： Clarence D. Chang , Stuart D. Hellring
IPC: C07D319/12
CPC classification number: C07D319/12
Abstract: A catalyzed conversion of diethylene glycol to 1,4-dioxane, undertaken over zeolites, ZSM-5, ZSM-23, ZSM-48 and zeolite beta, is characterized by high selectivity.
Abstract translation: 在沸石，ZSM-5，ZSM-23，ZSM-48和β沸石上进行的二乙二醇转化为1,4-二恶烷的催化转化具有高选择性。
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公开(公告)号：US06224748B1
公开(公告)日：2001-05-01
申请号：US08169107
申请日：1993-12-20
Applicant: Clarence D. Chang , Scott Han , Daniel J. Martenak , Jose G. Santiesteban , Dennis E. Walsh
Inventor： Clarence D. Chang , Scott Han , Daniel J. Martenak , Jose G. Santiesteban , Dennis E. Walsh
IPC: C10G4702
CPC classification number: C07C5/2724 , B01J21/06 , B01J21/066 , B01J23/24 , B01J23/28 , B01J23/30 , B01J23/652 , B01J23/6527 , C01G25/02 , C01P2002/54 , C07C5/2791 , C10G2400/10 , C07C9/00 , C07C9/16
Abstract: A process for hydrocracking heavy, high aromatic content feeds, such as cycle oil, using a catalyst composition containing a hydrogenation/dehydrogenation component, such as a noble metal, and an acidic solid component including a Group IVB metal oxide modified with an oxyanion of a Group VIB metal.
Abstract translation: 使用包含氢化/脱氢组分如贵金属的催化剂组合物和包含用氧阴离子改性的IVB族金属氧化物的酸性固体组分加氢裂化重质，高芳族化合物进料如循环油的方法， VIB族金属。
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公开(公告)号：US6162757A
公开(公告)日：2000-12-19
申请号：US357546
申请日：1999-07-20
Applicant: Clarence D. Chang , Scott Han , Scott A. Stevenson , James C. Vartuli
Inventor： Clarence D. Chang , Scott Han , Scott A. Stevenson , James C. Vartuli
CPC classification number: B01J37/03 , B01J21/066 , B01J23/10 , C07C5/2705 , C07C2521/06 , C07C9/00
Abstract: A novel synthesis composition of a solid acid containing zirconium, in addition to a rare earth element, such as cerium, has the potential for catalytic conversions of hydrocarbons, especially for isomerization of paraffins, ring opening of cyclics, hydrocracking, alkylation, hydrogenation of polynuclear aromatics, selective catalytic reduction of nitrogen oxides, and oligomerization of light olefins.
Abstract translation: 含有锆的固体酸的新型合成组合物除了稀土元素如铈之外，具有烃的催化转化的潜力，特别是对于链烷烃的异构化，环化开环，加氢裂化，烷基化，多核氢化 芳族化合物，氮氧化物的选择性催化还原和轻质烯烃的低聚。
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