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    Polymeric silanes and siloxanes containing oxetane groups
    13.
    发明授权
    Polymeric silanes and siloxanes containing oxetane groups 失效
    含有氧杂环丁烷基团的聚合硅烷和硅氧烷

    公开(公告)号：US3240754A

    公开(公告)日：1966-03-15

    申请号：US29724263

    申请日：1963-07-24

    Applicant: DOW CORNING

    Inventor： PLUEDDEMANN EDWIN P

    IPC: C07F7/08 ,  C07F7/18 ,  C08G77/00 ,  C08G77/48

    CPC classification number: C07F7/182 ,  C07F7/0852 ,  C08G77/00 ,  C08G77/48

    Abstract: Silanes and polymers of the general or unit general formula wherein R is a divalent consisting of C and H atoms, or C, H and O atoms, any O in R being present as OH radicals or ether and/or ester linkages, the radical R being bonded to Si through a C-Si bond, R11 is H or a hydrocarbon, halohydrocarbon, hydrocarbonoxy or acyloxy radical and a is 0, 1, 2 or 3, can be made by various methods, e.g. by any one of the following reactions:- Copolymers can be made by co-hydrolysis and co-condensation of the appropriate silanes or by equilibration of the corresponding siloxanes. Examples are given. Uses.-The products (in solution form) can be used to cast protective coatings on glass and metals, or the products can be cured with BF3 or other Lewis acids to form cured mouldings, castings or films.ALSO:Diolefinic oxetanes can be made by the following series of reactrons; wherein R1 is an alkyl group and n is O or an integer: Example (1) describes the preparation of 3,3-bis-(allyloxymethyl) oxetane and 3-allyloxymethyl-3-chloromethyl-oxetane, The following reactions are also disclosed

    Abstract translation: 其中R是由C和H原子或C，H和O原子构成的二价烷基的通式或单元通式的甲硅烷和聚合物，R中的任何O作为OH基团或醚存在 和/或酯键，基团R通过C-Si键与Si键合，R 11是H或烃，卤代烃，烃氧基或酰氧基，a是0,1,2或3可以通过各种方法制备 ，例如 可以通过以下任何一种反应： - 可以通过合适的硅烷的共水解和共缩合或通过相应的硅氧烷的平衡来制备共聚物。 给出了例子。 用途 - 产品（溶液形式）可用于在玻璃和金属上铸造保护涂层，或产品可用BF3或其他路易斯酸固化，形成固化的模制品，铸件或薄膜。还可以制备二烯类氧杂环丁烷 由以下系列的反应物; 其中R 1是烷基，n是O或整数：实施例（1）描述了3,3-双 - （烯丙氧基甲基）氧杂环丁烷的制备，形式为：1011578 / C2 / 2> 和3-烯丙氧基甲基-3-氯甲基 - 氧杂环丁烷，＆lt;形式：1011578 / C2 / 3＆gt;还公开了以下反应：

    Hydroxyether organosilicon compounds
    15.
    发明授权
    Hydroxyether organosilicon compounds 失效
    羟醚有机硅化合物

    公开(公告)号：US3057901A

    公开(公告)日：1962-10-09

    申请号：US2886160

    申请日：1960-05-13

    Applicant: DOW CORNING

    Inventor： PLUEDDEMANN EDWIN P

    IPC: C07F7/08 ,  C07F7/18 ,  C08G77/00 ,  C08G77/46

    CPC classification number: C07F7/182 ,  C07F7/0834 ,  C07F7/0852 ,  C07F7/0896 ,  C08G77/00 ,  C08G77/46 ,  Y10S516/01

    Abstract: Organosilicon compounds containing hydroxy ether groups are silanes and siloxanes of the general formula wherein each R11 is a monovalent atom or radical selected from the hydrogen atom and hydrocarbonoxy, hydrocarbon, halohydrocarbon and halohydrocarbonoxy radicals; y is 0, 1, 2, or 3; R1 is an alkylene radical, preferably containing 2, 3 or 4 carbon atoms; m is an integer of at least 4; B is a monovalent atom or radical selected from the hydrogen atom and hydrocarbon, hydrocarbonoxyhydrocarbonyl, halohydrocarbon and halohydrocarbonoxyhydrocarbonyl radicals and Y is a divalent radical of the general formula -CH2CHOHRa-or of the general formula where R is a divalent or trivalent radical bonded to the silicon by a C-Si linkage and selected from hydrocarbon and halohydrocarbon radicals and radicals composed of carbon, hydrogen and oxygen in the form of an ether linkage, R being a divalent radical and a being 0 or 1 when Y is acyclic, and R being a trivalent radical and a being 1 when Y is cyclic. The siloxanes may also be copolymers of from 0.001 to 99.999 mol. per cent of siloxane units of the general formula wherein B, R1, Y, R11 and m are as hereinbefore defined and y is 0, 1 or 2 with from 0.001 to 99.999 mol. per cent of siloxane units of the general formula in which A is selected from the hydrogen atom and the following monovalent radicals: hydrocarbon, halohydrocarbon, hydrocarbonoxyhydrocarbonyl and halohydrocarbonoxyhydrocarbonyl radicals and groups of the general formulae DSiA13 and DSiOSiA13 in which D is a divalent hydrocarbon radical and A1 is the same as A and x has a value from 0 to 3 inclusive. The organosilicon compounds, polymers and copolymers may be prepared by reacting the corresponding epoxides containing units of the general formulae and with alcohols of the general formula H(OR1)mOB in the presence of a Lewis acid such as SnCl4, AlCl3, BF3 etherate and FeCl3 at a temerature below 100 DEG C. Many radicals R11, R, R1, B, Y and A are specified, some of which are unsaturated. Many examples are given of the preparation of the silanes, siloxanes (including disiloxanes) and co-polysiloxanes containing hydroxyether groups. The products are useful as surfactants in th preparation of polyurethane foams, as emulsifying agents for organosiloxane liquids and as lubricating agents. An epoxyorganopolysiloxane is prepared in Example 1 by equilibrating octamethylcyclotetrasiloxane with tetramethyldisiloxane and reacting the product with excess allyl glycidyl ether in the presence of a butanol solution of chloroplatinic acid Epoxyorganosiloxanes are prepared in Example 4 by (1) reacting tetramethyldisiloxane with allyl glycidyl ether to give and (2) reacting the product of (1) with vinyl-pentamethyldisiloxane to give Specifications 834,326 and 983,850 are referred to.

    Cationic unsaturated amine-functional silane coupling agents
    16.
    发明授权
    Cationic unsaturated amine-functional silane coupling agents 失效
    阳离子不饱和胺官能硅烷偶联剂

    公开(公告)号：US3884886A

    公开(公告)日：1975-05-20

    申请号：US45794374

    申请日：1974-04-04

    Applicant: DOW CORNING

    Inventor： PLUEDDEMANN EDWIN P

    IPC: C07F7/18 ,  C08F230/08 ,  C08F246/00 ,  C08J5/08 ,  C09D4/00 ,  C08F3/16 ,  C08F11/04

    CPC classification number: C08J5/08 ,  C07F7/1804 ,  C07F7/182 ,  C07F7/1892 ,  C08F230/08 ,  C08F246/00 ,  C09D4/00 ,  C08G77/26

    Abstract: MOIETY, Z being bonded to the nitrogen atom by a C-N bond; R'' is independently selected from the group consisting of the hydrogen atom, lower alkyl radical or a heterocyclic organic compound containing the nitrogen atom as a ring member; M IS AN INTEGER OF 1 OR 2; R'''' is the hydrogen atom or a lower alkyl radical; and Y is an acid anion; are polymerized with vinylic monomers to produce organosilicon-containing polymers having utility as elastomers and coating compositions.

    GROUPS OR NITROGEN IN THE FORM OF GROUPS; Z is a divalent organic radical having a double bond conjugated with the

    IN WHICH Q is a divalent hydrocarbon radical or a divalent hydrocarbon radical containing oxygen in the form of

    Organosilicon compounds of the formula

    Abstract translation: 式III的有机硅化合物其中Q是二价烃基或二氧代烃基，其含有以组或氮在形式中的氧的氧; Z是具有与MOIETY共轭的双键的二价有机基团，Z通过C-N键与氮原子键合; R'独立地选自氢原子，低级烷基或含有氮原子作为环成员的杂环有机化合物; M为1或2的整数; R“是氢原子或低级烷基; Y为酸性阴离子; 与乙烯基单体聚合以产生用作弹性体和涂料组合物的含有机硅的聚合物。

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