公开(公告)号：US3160639A

公开(公告)日：1964-12-08

申请号：US3008560

申请日：1960-05-19

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  HEATH CARL E ,  VICTOR KEVORKIAN

IPC: C07C45/40 ,  C07D301/22 ,  C07D303/04 ,  C07D303/08

CPC classification number: C07D303/08 ,  C07C45/40 ,  C07D301/22 ,  C07D303/04

公开(公告)号：US3154480A

公开(公告)日：1964-10-27

申请号：US67960057

申请日：1957-08-22

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  LUCCHESI PETER J

IPC: C10G53/08

CPC classification number: C10G32/04 ,  C10G53/08

公开(公告)号：US3081312A

公开(公告)日：1963-03-12

申请号：US82443059

申请日：1959-07-01

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  ROSENBLATT THEODORE M

IPC: C07C29/141 ,  C07C29/86

CPC classification number: C07C29/141 ,  C07C29/86 ,  C07C31/04 ,  C07C31/08

公开(公告)号：US3055818A

公开(公告)日：1962-09-25

申请号：US60099556

申请日：1956-07-30

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： MCARTHUR DONALD S ,  LUCCHESI PETER J ,  LONG ROBERT B

IPC: B01J19/08 ,  C10G15/10

CPC classification number: B01J19/082 ,  C10G15/10 ,  Y10S204/90

公开(公告)号：US2959530A

公开(公告)日：1960-11-08

申请号：US59298656

申请日：1956-06-21

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  LUCCHESI PETER J ,  TARMY BARRY L ,  READ CHESTER L

IPC: C10G45/04

CPC classification number: C10G45/04 ,  Y10S204/903 ,  Y10S204/904

公开(公告)号：US2935464A

公开(公告)日：1960-05-03

申请号：US47922854

申请日：1954-12-31

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： DUDLEY RICHARD H ,  LONG ROBERT B ,  ROHRER JAMES C ,  STRICKLAND BARNEY R

IPC: C10G35/06

CPC classification number: C10G35/06

公开(公告)号：US3651159A

公开(公告)日：1972-03-21

申请号：US3651159D

申请日：1968-09-03

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  CARUSO FRED A ,  FEO RICHARD J DE ,  WALKER DAVID G

IPC: B01J20/00 ,  C01B32/40 ,  C07F1/08 ,  C07F5/06 ,  C07C7/00 ,  B01J11/22 ,  C07C11/00

CPC classification number: C07F5/064 ,  B01J20/00 ,  C01B32/40 ,  C07F1/08

Abstract: BIMETALIC SALTS, HAVING THE GENERIC FORMULA MM''XN WHEREIN M IS A GROUP I-B METAL, M'' IS A GROUP III-A METAL, X IS A HALIDE AND N IS EQUAL TO THE SUM OF THE VALENCES OF M AND M'', ARE PREPARED BY REACTING THE HALOGEN SALTS OF THE INDIVIDUAL METALS, M AND M'', IN A SUITABLE SOLVENT. THE BIMETALLIC SALT FORMED THEREBY IS A DISCRETE MONOMERIC SPECIES AND CAN BE UTILIZED IN THE SEPARATION AND RECOVERY OF VARIOUS LIGANDS, BY PREFERENTIAL COMPLEXATION. COMPLEXATION CAN BE CONDUCTED WITH THE BIMETALLIC

SALT IN THE SOLID STATE, IN SOLUTION, OR AS A SLURRY, AND WITH THE COMPLEXIBLE LIGAND IN THE GASES OR LIQUID STATE. THE LIGAND IS RECOVERED BY DECOMPLEXATION OF THE BIMETALLIC SALT-LIGAND COMPLEX OR BY DISPLACEMENT OF THE COMPLEXED LIGAND WITH ANOTHER LIGAND.

公开(公告)号：US3592865A

公开(公告)日：1971-07-13

申请号：US3592865D

申请日：1968-09-03

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  LONGWELL JOHN P ,  CARUSO FRED A ,  DEFEO RICHARD J

IPC: B01J20/00 ,  C01B32/40 ,  C07F1/08 ,  C07F5/06 ,  C07C7/00 ,  B01J11/22 ,  C07C11/00

CPC classification number: C07F5/064 ,  B01J20/00 ,  C01B32/40 ,  C07F1/08

Abstract: COMPLEXIBLE LIGANDS CONTAINED IN A FEED STREAM ARE COMPLEXED WITH A LIQUID SORBENT SOLUTION OF CUPROUS ALUMINUM HALIDE. THE COMPLXED COMPLEXIBLE LIGANDS ARE THEN SEPARATED BY A LIGAND EXCHANGE OPERATIONS GENERALLY REQUIRING N-1 LIGAND EXCHANGE OPERATIONS FOR N COMPLEXED COMPLEXIBLE LIGANDS TO BE SEPARATED. THE SEPARATION IN EACH LIGAND EXCHANGE OPERATION IS EFFECTED BY CONTACTING THE SEVERAL COMPLEXED COMPLEXIBLE LIGANDS WITH A STRIPPING LIGAND WHICH FORMS A MORE STABLE COMPLEX WITH THE SORBENT THAT THE COMPLEXIBLE LIGAND OR LIGANDS TO BE SEPARATED AND RECOVERED, AND EXCHANGING THE STRILPPING LIGAND FOR THE COMPLEXIBLE LIGAND OR LIGANDS IN THE SORBENT COMPLEX.

公开(公告)号：US3565965A

公开(公告)日：1971-02-23

申请号：US3565965D

申请日：1968-11-26

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： WALKER DAVID G ,  LONG ROBERT B

IPC: C07C7/10

CPC classification number: C07C7/10 ,  C07C15/02 ,  C07C15/24

Abstract: A SOLVENT EXTRACTION PROCESS FOR SEPARATING COMPONENTS OF A FEEDSTREAM CONPRISING ISOMERIC C8-C20 ALKYL BENZENE AND NAPHTHALENE OR MIXTURES THEREOF IN WHICH THE FEEDSTREAM IS CONTACTED WITH A TERNARY COMPOUND, SAID TERNARY COMPOUND COMPRISING R:HX:2AIX3 WHEREIN R IS SELECTED FROM THE GROUP CONSISTING OF C8-C20 ALKYL BENZENES AND NAPHTHALENES AND IS AT LEAST AS BASIC AS THE MATERIAL TO BE SEPARATED, AND X IS SELECTED FROM THE GROUP CONSISTING OF CHLORINE AND BROMINE, IN THE PRESENCE OF A HYDROGEN HALIDE.

公开(公告)号：US3409692A

公开(公告)日：1968-11-05

申请号：US48557465

申请日：1965-09-07

Applicant: EXXON RESEARCH ENGINEERING CO

Inventor： LONG ROBERT B ,  BAEDER DONALD L

IPC: C07C7/152 ,  C07C7/156

CPC classification number: C07C7/152 ,  C07C7/156 ,  C07C11/00