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11.发明授权Moving bed catalytic cracking process with platinum group metal or rhenium supported directly on the cracking catalyst 失效用铂族金属或铼直接负载在裂化催化剂上的移动床催化裂解过程
公开(公告)号：US4473658A
公开(公告)日：1984-09-25
申请号：US524103
申请日：1983-08-17
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： B01J29/061 , B01J29/90 , B01J38/22
摘要： An improved moving bed continuous catalytic cracking process for cracking hydrocarbon feedstocks, such as gas oil, in the absence of added hydrogen, which includes the use of a minute amount of dispersed platinum supported directly on a cracking catalyst. The trace of platinum induces a substantial increase in the heat efficiency with which coke on catalyst is converted to CO.sub.2 in the regenerator section with minimal or no detriment to the cracking reaction.
摘要翻译： 一种改进的移动床连续催化裂化方法，用于在没有加入氢气的情况下裂化烃原料如瓦斯油，其包括使用微量的分散的铂直接负载在裂化催化剂上。 铂的痕迹导致热效率的显着增加，在该热效率下，催化剂上的焦炭在再生器部分中转化为CO 2，同时对裂解反应的影响最小或没有损害。
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公开(公告)号：US4174272A
公开(公告)日：1979-11-13
申请号：US869079
申请日：1978-01-13
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： B01J29/061 , C10G11/05 , C10G11/18
摘要： Non-hydrogenative endothermic catalytic cracking of hydrocarbon, particularly petroleum, fractions at relatively low pressures and high temperatures in a system where the endothermic heat required for cracking is supplied by catalyst as the heat transfer medium, which catalyst has been heated by burning coke deposited on the catalyst during cracking; and wherein a decomposable compound of platinum, palladium, ruthenium, iridium, osmium, rhodium or rhenium, is introduced into contact with the cracking catalyst during said process.
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公开(公告)号：US4093535A
公开(公告)日：1978-06-06
申请号：US806713
申请日：1977-06-15
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： C10G11/18 , Y10S208/01
摘要： A catalytic process for cracking of gas oil is disclosed, wherein trace amounts of metals of Periods 5 and 6 of Group VIII or rhenium is added to the total catalyst inventory so as to enhance significant conversion of the CO in the regenerator while maintaining the efficiency of the cracking reaction at high levels.
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公开(公告)号：US4868146A
公开(公告)日：1989-09-19
申请号：US236414
申请日：1988-08-25
申请人： Pochen Chu , Albert B. Schwartz
发明人： Pochen Chu , Albert B. Schwartz
CPC分类号： C10G50/00 , B01J29/40 , B01J29/90 , C07C2/12 , B01J2229/123 , B01J2229/16 , B01J2229/32 , C07C2529/40 , C07C2529/70 , Y02P20/584
摘要： A surface-inactive shape selective metallosilicate catalyst, useful for the conversion of lower molecular weight olefins to liquid hydrocarbons such as gasoline, distillate, and high viscosity lube oils, is prepared by forming a silica shell on a medium pore metallosilicate core by crystallizing silica in the presence of fluoride ion onto the surface of the core.A novel catalyst composition is provided comprising an inner core portion and an outer portion disposed as a porous shell around the inner portion, wherein the inner portion consists essentially of metallosilicate zeolite having a medium pore structure, such as ZSM-5 or ZSM-23, and the outer portion comprising a fluoride-containing crystalline shell consisting essentially of silica substantially free of acid sites and having substantially the same crystalline structure as the inner core portion.
摘要翻译： 通过在中孔金属硅酸盐芯上通过使二氧化硅结晶形成二氧化硅壳来制备可用于将低分子量烯烃转化为液体烃如汽油，馏出物和高粘度润滑油的表面活性形状选择性金属硅酸盐催化剂 氟离子存在于芯的表面上。 提供了一种新颖的催化剂组合物，其包括内芯部分和围绕内部部分设置为多孔壳体的外部部分，其中内部部分基本上由具有中孔结构的金属硅酸盐沸石如ZSM-5或ZSM-23组成， 并且外部部分包含基本上由基本上不含酸性部位的二氧化硅组成并且具有与内芯部分基本相同的晶体结构的含氟化物结晶壳。
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15.发明授权Process for the production of high viscosity index lubricating oils from olefins 失效从烯烃生产高粘度指数润滑油的方法
公开(公告)号：US4517399A
公开(公告)日：1985-05-14
申请号：US639529
申请日：1984-08-09
CPC分类号： B01J29/40 , C10G50/02 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： An improved process for the production of high viscosity lubricating oils obtained by reacting olefins over ZSM-5 type zeolites at elevated temperatures and pressures in order to obtain a liquid product and thereafter recovering a lube oil fraction from said liquid product is disclosed. The improvement resides in the use of large crystal ZSM-5 which has been found to enhance the viscosity index of lubes produced from olefins.
摘要翻译： 公开了一种用于生产高粘度润滑油的改进方法，所述高粘度润滑油通过使ZSM-5型沸石在高温和高压下反应以获得液体产物，然后从所述液体产物中回收润滑油馏分而使烯烃反应获得。 改进在于使用已经发现可以提高由烯烃生产的润滑油的粘度指数的大型晶体ZSM-5。
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公开(公告)号：US4298695A
公开(公告)日：1981-11-03
申请号：US120243
申请日：1980-02-11
IPC分类号： B01J23/745 , B01J29/46 , C07C9/14 , C10G2/00 , C07C1/00
CPC分类号： B01J23/745 , B01J29/46 , C10G2/334 , B01J2229/26 , B01J2229/42 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2529/46 , Y10S208/95
摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from finely divided iron powder or iron oxide. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
摘要翻译： 公开了一种方法，用于使用由细碎铁粉或氧化铁制备的新型催化剂，以90％塔顶转化合成气至沸点范围小于400°F的液体烃产物。 该新方法包括使合成气与含铁的单一颗粒催化剂接触，二氧化硅与氧化铝之比至少为12的结晶酸性硅铝酸盐沸石，孔径大于约5埃单位，约束指数约为1 到12，和矩阵。 催化剂不含助催化剂。
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公开(公告)号：US4265787A
公开(公告)日：1981-05-05
申请号：US897077
申请日：1978-04-17
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
摘要： Operation of regenerators of commercial equipment for catalytic cracking of hydrocarbon feedstock, such as gas oil, in the absence of added hydrogen is improved considerably by use of a cracking catalyst which contains a minute amount, as low as fractions of a part per million (ppm), of a metal from periods 5 and 6 of Group VIII of the Periodic Table or rhenium. These powerful dehydrogenation metals, in the amounts here used, do not have serious adverse effect on the cracking operation and reduce CO content of flue gases from the regenerator to negligible amounts.
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公开(公告)号：US4159239A
公开(公告)日：1979-06-26
申请号：US872851
申请日：1978-01-27
申请人： Albert B. Schwartz
发明人： Albert B. Schwartz
CPC分类号： B01J29/061
摘要： The operation of a fluid catalytic cracking unit having a regenerator designed to completely combust carbon monoxide to carbon dioxide thermally is improved by circulating a trace amount of at least one metal of the group consisting of platinum, palladium, iridium, osmium, rhodium, ruthenium and rhenium with the circulating inventory of solid acidic cracking catalyst.
摘要翻译： 通过循环微量的至少一种由铂，钯，铱，锇，铑，钌等金属组成的组中的一种金属，具有设计成将一氧化碳完全燃烧成二氧化碳的再生器的流化催化裂化装置的操作得到改善， 铼与循环库存的固体酸性裂化催化剂。
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公开(公告)号：US4933069A
公开(公告)日：1990-06-12
申请号：US250802
申请日：1988-09-29
摘要： A process for increasing the volume of feed throughput to the FCC by decreasing coke make under catalytic cracking conditions including a temperature of 950.degree. F. to about 1150.degree. F., a catalyst to feed ratio of 3:1 to 10:1 and a catalyst contact time of from about 1 to about 20 seconds in the presence of catalyst comprising framework silicon enriched ZSM-20.
摘要翻译： 一种通过在催化裂解条件（包括950°F至约1150°F的温度，3:1至10:1的催化剂与进料比之间）减少焦炭生成来增加FCC的进料通量的方法，以及 在催化剂存在下，催化剂接触时间为约1至约20秒，所述催化剂包含骨架硅富集的ZSM-20。
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公开(公告)号：US4788374A
公开(公告)日：1988-11-29
申请号：US137223
申请日：1987-12-23
CPC分类号： B01J29/40 , B01J29/90 , C07C2/12 , C10G50/00 , B01J2229/123 , B01J2229/16 , B01J2229/32 , C07C2529/40 , C07C2529/70 , Y02P20/584
摘要： A surface-inactive shape selective metallosilicate catalyst, useful for the conversion of lower molecular weight olefins to liquid hydrocarbons such as gasoline, distillate, and high viscosity lube oils, is prepared by a process comprising forming a silica shell on a metallosilicate core by crystallizing silica in the presence of fluoride ion onto the surface of the core.
摘要翻译： 通过包括通过使二氧化硅结晶在金属硅酸盐芯上形成二氧化硅壳的方法制备用于将低分子量烯烃转化为液体烃如汽油，馏出物和高粘度润滑油的表面活性形状选择性金属硅酸盐催化剂 在氟化物离子存在的情况下在核心的表面上。
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