Abstract:
An energy storage device comprises a positive electrode, a negative electrode, a separator arranged between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The negative electrode has a negative substrate layer, and a negative composite layer arranged on the surface of the negative substrate layer. The separator has a separator substrate layer. The negative composite layer contains a non-graphitizable carbon having a particle diameter D50 of 2.0 μm or more and 6.0 μm or less. A corrected negative electrode density, which is defined as a value obtained by dividing, by a thickness of the separator substrate layer, a value obtained by multiplying a density of the negative composite layer by a thickness of the negative composite layer, is 1.2 (g/cm3) or more and 5.1 (g/cm3) or less.
Abstract:
The present embodiment provides a lithium ion secondary battery including a positive electrode containing LiaNixCoyMzO2 (0.9≤a≤1.2, 0.3≤x≤0.8, 0.2≤y+z≤0.7, where M is a metal element other than Li, Ni, and Co) as a positive active material, and a negative electrode containing non-graphitic carbon as a negative active material. In this lithium ion secondary battery, at a portion where the positive electrode and the negative electrode face each other, a basis weight (P) of the positive active material and a basis weight (N) of the negative active material satisfy a relational expression of 0.65≤P/N≤1.05.
Abstract:
An energy storage device includes a positive electrode, a negative electrode, and an insulating layer arranged between these electrodes to electrically insulate these electrodes. The negative electrode includes a composite layer containing active material particles. The composite layer of the negative electrode, and the positive electrode are arranged to face each other across the insulating layer. The insulating layer contains electrically insulating particles, and is made porous by a gap between these particles. The composite layer of the negative electrode is made porous by a gap between the active material particles, and “−0.8≦Log B−Log A≦1.0” is satisfied in which in a pore distribution of the composite layer, a pore peak diameter is represented by A (μm), and in a pore distribution of the insulating layer, a peak diameter is represented by B (μm).
Abstract:
A method including: a placing step of placing an electrode assembly including a positive electrode that contains a positive active material and a negative electrode that contains a negative active material, and an electrolyte solution containing an additive in a container; a charging step of charging the electrode assembly placed in the container; and a hermetically sealing step of hermetically sealing the container after the charging step. When starting charging in the charging step, the electrolyte solution contains 1.0 mass % or less of lithium difluoro bis(oxalate)phosphate as the additive. The charge voltage in the charging step is 4.0 V or more.
Abstract:
There is provided an energy storage device including an electrode assembly having a pair of electrodes overlapped with each other. At least one of the electrodes includes a current collecting substrate, an active material layer arranged on the current collecting substrate, an intermediate layer arranged between the current collecting substrate and the active material layer, and an insulating layer arranged on the current collecting substrate. The active material layer contains an active material and a first binder. The intermediate layer contains a carbonaceous material and a second binder. The insulating layer contains an insulating material and a third binder. The second binder is a nonaqueous binder. The third binder is an aqueous binder.
Abstract:
A battery includes a positive electrode, a negative electrode including a negative active material layer containing hardly-graphitizable carbon as a negative active material and an aqueous binder, a separator disposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The negative active material layer has a density of not less than 0.81 g/cc and not more than 1.01 g/cc. The negative active material has a particle size D90 of not less than 1.9 μm and not more than 11.5 μm, the particle size D90 being a particle size at which the cumulative volume is 90% in the particle size distribution.
Abstract:
An electric storage device includes: an electrode assembly in which electrodes are wound such that paired curved portions and a straight portion connecting the paired curved portions are formed; a case which houses the electrode assembly, the case comprising a convex part protruding toward the straight portion of the electrode assembly to support the straight portion; and a support portion which supports the curved portion toward an inside of the electrode assembly.
Abstract:
An electric storage device having a positive electrode, a negative electrode, a separator located between the positive electrode and the negative electrode, and a nonaqueous electrolyte. The positive electrode has a positive substrate layer, a positive composite layer containing a positive active material, and an undercoat layer located between the positive substrate layer and the positive composite layer. A density of the positive composite layer is 2.1 g/cm3 or more and 2.7 g/cm3 or less. The positive electrode has the rate of increase in sheet resistance after a solvent immersion test of 30% or less. The undercoat layer contains a binder selected from the group consisting of chitosan derivatives, cellulose derivatives and acrylic acid derivatives.
Abstract translation:具有正极,负极,位于正极和负极之间的隔膜的非蓄电装置以及非水电解质。 该正电极具有正的衬底层,含有正极活性材料的正性复合层,以及位于正性衬底层和正性复合层之间的底涂层。 正极复合层的密度为2.1g / cm 3以上且2.7g / cm 3以下。 正极在溶剂浸渍试验后的薄层电阻增加率为30%以下。 底涂层含有选自壳聚糖衍生物,纤维素衍生物和丙烯酸衍生物的粘合剂。
Abstract:
One aspect of the present invention is an energy storage device including a negative electrode including a negative electrode substrate and a negative active material layer stacked directly or indirectly on at least one surface of the negative electrode substrate, the negative active material layer containing a negative active material, the negative active material containing hollow graphite particles having a median diameter D1 and solid graphite particles having a median diameter D2 smaller than the median diameter of the hollow graphite particles.
Abstract:
An energy storage device is provided in which a decrease in power caused by repetitive charge-discharge in a high-temperature environment is suppressed. In the present embodiment, an energy storage device and a method for manufacturing the energy storage device are provided, the energy storage device including an electrode which includes: an active material layer including a particulate active material; and a conductive layer layered on the active material layer and including a conduction aid. An average secondary particle diameter of the active material is 2.5 μm or more and 6.0 μm or less. A surface roughness Ra of the conductive layer on a side on the active material layer is 0.17 μm or more and 0.50 μm or less.