公开(公告)号：US07671132B1

公开(公告)日：2010-03-02

申请号：US12336773

申请日：2008-12-17

申请人： Georges Marcel Victor Thielen ,  Frank Schmitz ,  Nicola Costantini

发明人： Georges Marcel Victor Thielen ,  Frank Schmitz ,  Nicola Costantini

IPC分类号： C08L23/04 ,  C08L25/10

CPC分类号： C08L9/00 ,  B60C1/0016 ,  C08L9/06 ,  C08L23/02 ,  C08L25/06 ,  C08L25/16 ,  C08L2666/02

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising from 30 to 70 parts by weight, per 100 parts by weight of s first elastomer (phr) having a glass transition temperature Tg ranging from about −40° C. to about −10° C. and a solubility parameter ranging from about 4.1 MPa1/2 to about 4.5 MPa1/2; from 70 to 30 phr of a second elastomer having a Tg ranging from about −105° C. to about −30° C. and a solubility parameter ranging from about 3.7 MPa1/2 to about 4.1 MPa1/2; from 1 to 40 phr of a first plasticizer having a solubility parameter ranging from 3.4 MPa1/2 to 3.8 MPa1/2; from 1 to 20 phr of a second plasticizer having a solubility parameter ranging from 4.3 MPa1/2 to 4.7 MPa1/2; and from 30 to 150 phr of silica.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含30至70重量份，相对于每100重量份的第一弹性体（phr），其玻璃化转变温度Tg范围为 约-40℃至约-10℃，溶解度参数为约4.1MPa1 / 2至约4.5MPa1 / 2; 70至30phr的Tg范围为约-105℃至约-30℃的第二弹性体，溶解度参数为约3.7MPa 1/2至约4.1MPa 1/2; 1〜40phr的溶解度参数为3.4MPa·2〜3.8MPa·1/2的第一增塑剂; 1至20phr的溶解度参数范围为4.3MPa1 / 2至4.7MPa1 / 2的第二增塑剂; 和30至150phr的二氧化硅。

公开(公告)号：US07476708B2

公开(公告)日：2009-01-13

申请号：US11643148

申请日：2006-12-21

申请人： Georges Marcel Victor Thielen ,  Frank Schmitz

发明人： Georges Marcel Victor Thielen ,  Frank Schmitz

IPC分类号： C08L83/04

CPC分类号： C08K5/5419 ,  B60C1/0016 ,  C08L33/26 ,  C08L83/04 ,  Y10T152/10 ,  C08L9/06 ,  C08L35/06 ,  C08L83/00

摘要： A tire with a rubber containing component compound of a copolymer rubber having pendant hydroxyl groups; and a non-sulfur containing silane.

摘要翻译： 一种具有橡胶的轮胎，其含有具有侧基羟基的共聚物橡胶的组分化合物; 和不含硫的硅烷。

公开(公告)号：US20140336330A1

公开(公告)日：2014-11-13

申请号：US13892578

申请日：2013-05-13

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz ,  Jerome Joel Daniel Delville ,  Christian Jean-Marie Kaes

IPC分类号： C08L9/06

CPC分类号： B60C1/0016 ,  C08K3/36 ,  C08L9/00 ,  C08L9/06 ,  C08L2205/02 ,  C08L2205/03

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising a solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight and a vinyl 1,2 content of less than 25 percent by weight; optionally, at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; at least one secondary accelerator selected from the group consisting of guanidines, dithiocarbamates and thiurams; and an α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkane; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn metal.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含具有至少36重量％的结合苯乙烯含量的溶液聚合的丁苯橡胶和乙烯基1,2含量少 超过25％; 任选地，至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 选自鸟苷，二硫代氨基甲酸盐和秋兰姆的至少一种二级促进剂; 和α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃; 其中，相对于Zn金属100重量份的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。

公开(公告)号：US20100144946A1

公开(公告)日：2010-06-10

申请号：US12328212

申请日：2008-12-04

申请人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz

发明人： Nicola Costantini ,  Georges Marcel Victor Thielen ,  Frank Schmitz

IPC分类号： C08K3/22 ,  B60C1/00

CPC分类号： C08K3/22 ,  B60C1/0016 ,  C08K3/011 ,  C08K5/0025 ,  C08K5/39 ,  C08K5/40 ,  C08K5/44 ,  C08L9/06 ,  C08L2666/08

摘要： The present invention is directed to a pneumatic tire comprising a ground contacting tread, the tread comprising a rubber composition comprising a solution polymerized styrene-butadiene rubber having a bound styrene content of at least 36 percent by weight and a vinyl 1,2 content of less than 25 percent by weight; optionally, at least one additional diene based rubber; silica; a sulfur donor; a sulfenamide accelerator; at least one secondary accelerator selected from the group consisting of guanidines, dithiocarbamates and thiurams; and an α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkane; wherein the zinc content of the rubber composition is less than 0.5 parts by weight, per 100 parts by weight of elastomer (phr) as Zn metal.

摘要翻译： 本发明涉及一种充气轮胎，其包括接地胎面，所述胎面包含橡胶组合物，所述橡胶组合物包含具有至少36重量％的结合苯乙烯含量的溶液聚合的丁苯橡胶和乙烯基1,2含量少 超过25％; 任选地，至少一种另外的二烯基橡胶; 二氧化硅 硫供体; 亚磺酰胺促进剂; 选自鸟苷，二硫代氨基甲酸盐和秋兰姆的至少一种二级促进剂; 和α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃; 其中，相对于Zn金属100重量份的弹性体（phr），橡胶组合物的锌含量小于0.5重量份。

公开(公告)号：US20090088520A1

公开(公告)日：2009-04-02

申请号：US12332452

申请日：2008-12-11

申请人： Georges Marcel Victor Thielen ,  Frank Schmitz

发明人： Georges Marcel Victor Thielen ,  Frank Schmitz

IPC分类号： C08L31/02

CPC分类号： C08K5/5419 ,  B60C1/0016 ,  C08L33/26 ,  C08L83/04 ,  Y10T152/10 ,  C08L9/06 ,  C08L35/06 ,  C08L83/00

摘要： A tire with a rubber containing component compound of a copolymer rubber having pendant hydroxyl groups; and a non-sulfur containing silane.

摘要翻译： 一种具有橡胶的轮胎，其含有具有侧基羟基的共聚物橡胶的组分化合物; 和不含硫的硅烷。

公开(公告)号：US09156932B2

公开(公告)日：2015-10-13

申请号：US13332837

申请日：2011-12-21

申请人： Ralf Mruk ,  Frank Schmitz ,  Robert Fokko Roskamp ,  Alexandra Hermann ,  Rudolf Wilhelm Zentel

发明人： Ralf Mruk ,  Frank Schmitz ,  Robert Fokko Roskamp ,  Alexandra Hermann ,  Rudolf Wilhelm Zentel

IPC分类号： C08F220/56

CPC分类号： C08F220/56

摘要： A method of making a graft copolymer, comprising the steps of obtaining a first polymer comprising at least one carbon-carbon double bond, the first polymer derived from at least one first monomer, the at least one first monomer comprising a conjugated diene monomer; obtaining a second polymer, the second polymer capable of exhibiting a lower critical solution temperature (LCST) and comprising a terminal functional group capable of reacting with the carbon-carbon double bond; and reacting the second polymer with the first polymer to form a graft copolymer, the graft copolymer comprising a backbone derived from the first polymer and sidechains derived from the second polymer.

摘要翻译： 一种制备接枝共聚物的方法，包括以下步骤：获得包含至少一个碳 - 碳双键的第一聚合物，衍生自至少一种第一单体的第一聚合物，至少一种包含共轭二烯单体的第一单体; 获得第二聚合物，所述第二聚合物能够表现出较低临界溶解温度（LCST），并且包含能够与碳 - 碳双键反应的末端官能团; 并使所述第二聚合物与所述第一聚合物反应以形成接枝共聚物，所述接枝共聚物包含衍生自所述第一聚合物的主链和衍生自所述第二聚合物的侧链。

公开(公告)号：US20120152424A1

公开(公告)日：2012-06-21

申请号：US13403089

申请日：2012-02-23

申请人： Ralf Mruk ,  Serge Julien Auguste Imhoff ,  Julia Martin Francoise Claudine Tahon ,  Annette Lechtenboehmer ,  Frank Schmitz

发明人： Ralf Mruk ,  Serge Julien Auguste Imhoff ,  Julia Martin Francoise Claudine Tahon ,  Annette Lechtenboehmer ,  Frank Schmitz

IPC分类号： B60C15/06

CPC分类号： B60C15/06 ,  B60C2015/0614 ,  C08L23/30 ,  C08L79/04 ,  Y10T152/10513 ,  Y10T152/10819 ,  Y10T152/10828 ,  Y10T152/10846

摘要： The present invention is directed to a pneumatic tire comprising at least one component selected from the group consisting of apexes, flippers and chippers, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer (phr), of a polybenzobisoxazole (PBO) short fiber having a length ranging from 0.5 to 20 mm having a thickness ranging from 10 to 30 microns, and from 1 to 50 phr of an epoxidized polyisoprene having a number-average molecular weight of 5000 to 100000.

摘要翻译： 本发明涉及一种充气轮胎，该充气轮胎包括至少一种选自顶点，脚蹼和切片的组分，所述至少一种组分包含橡胶组合物，所述橡胶组合物包含二烯基弹性体和1至30份 的每100重量份的弹性体（phr），长度为0.5至20毫米的聚苯并双恶唑（PBO）短纤维，其厚度范围为10至30微米，1至50phr的环氧化物 数均分子量为5000〜100000的聚异戊二烯。

公开(公告)号：US07694708B2

公开(公告)日：2010-04-13

申请号：US11881540

申请日：2007-07-27

申请人： Giorgio Agostini ,  Filomeno Gennaro Corvasce ,  Christian Kaes ,  Marc Weydert ,  Frank Schmitz ,  Anne Therese Peronnet-Paquin ,  Mercedes Maria Diaz-Scharfe

发明人： Giorgio Agostini ,  Filomeno Gennaro Corvasce ,  Christian Kaes ,  Marc Weydert ,  Frank Schmitz ,  Anne Therese Peronnet-Paquin ,  Mercedes Maria Diaz-Scharfe

IPC分类号： B60C1/00 ,  B60C17/00 ,  B60C17/04

CPC分类号： B60C17/0009 ,  B60C15/0607 ,  B60C17/0027 ,  B60C2001/0033 ,  Y10T152/10495 ,  Y10T152/10819 ,  Y10T152/10864

摘要： A pneumatic tire including a circumferential tread, two spaced apart beads, and sidewalls connecting said beads and tread, wherein said tire sidewall contains at least one internal annular sidewall insert including at least two annular segments, the at least two annular segments including first and second adjacent annular segments; wherein said first and second annular segments are disposed with an interface therebetween; wherein each of the at least two annular segments includes a rubber composition comprising at least one diene based rubber and at least one vulcanization modifier selected from the group consisting of α,ω-bis(N,N′-dihydrocarbylthiocarbamamoyldithio)alkanes, bismaleimides, and biscitraconimides; and wherein the concentration of vulcanization modifier in the first annular segment is less than the concentration of vulcanization modifier in the second annular segment.

摘要翻译： 一种充气轮胎，包括周向胎面，两个间隔开的胎圈和连接所述胎圈和胎面的侧壁，其中所述轮胎侧壁包含至少一个内部环形侧壁插入件，其包括至少两个环形段，所述至少两个环形段包括第一和第二 相邻环形段; 其中所述第一和第二环形段设置有它们之间的界面; 其中所述至少两个环形段中的每一个包括橡胶组合物，其包含至少一种二烯基橡胶和至少一种选自α，ω-双（N，N'-二烃基硫代氨基甲酰基二硫代）烷烃，双马来酰亚胺和 双嘧啶酰胺 并且其中所述第一环形区段中的硫化改性剂的浓度小于所述第二环形区段中的硫化改性剂的浓度。

公开(公告)号：US20090305535A1

公开(公告)日：2009-12-10

申请号：US12308317

申请日：2007-06-22

申请人： Frank Schmitz

发明人： Frank Schmitz

IPC分类号： H01R12/20

CPC分类号： H01R12/7029 ,  H01R12/585 ,  H05K3/308

摘要： A component (30) is to be attached by means of a plug connector (10) in a hole (53) of a base plate (50). To this end, the plug connector (10) has a shaft (15) with a flat profile. When the plug is inserted in the socket, the shaft end (20) projects out of the hole (53) on the rear side of the circuit board (52). The shaft end (20) is followed by a shaft section (13), broadened relative to the hole width (54), which has an opening (14). By means of the opening (14), the shaft section (13) is split into two legs (11, 12), which are sprung against each another and which hold the shaft (15) in the hole (53) of the circuit board (50) when the plug is inserted in the socket. To improve the holding effect, the two legs (11, 12) are constructed differently one from the other, wherein one leg (11) has a greater longitudinal extension (21) than the other (12). This means that the broadened shaft section (13) splits into a long (11) and a short leg (12). Both legs (11, 12) taper into an undercut head (40) on the shaft end (20). When the plug is inserted in the socket, the head (40) engages with the hole-edge of the circuit board (50).

摘要翻译： 组件（30）将通过插头连接器（10）连接到基板（50）的孔（53）中。 为此，插头连接器（10）具有平坦轮廓的轴（15）。 当插头插入插座时，轴端（20）从电路板（52）后侧的孔（53）突出。 轴端（20）之后是轴部（13），相对于具有开口（14）的孔宽度（54）变宽。 通过开口（14），轴部分（13）被分成两个彼此悬挂的腿部（11,12），并将轴（15）保持在电路板的孔（53）中 （50）当插头插入插座时。 为了提高保持效果，两个腿部（11,12）被构造成彼此不同，其中一个腿部（11）具有比另一个腿部（12）更大的纵向延伸部（21）。 这意味着加宽的轴部分（13）分裂成长（11）和短腿（12）。 两个腿部（11,12）在轴端（20）上锥形成一个底切头部（40）。 当插头插入插座时，头部（40）与电路板（50）的孔缘接合。

公开(公告)号：US07468153B2

公开(公告)日：2008-12-23

申请号：US11095449

申请日：2005-03-31

申请人： Marc Weydert ,  Frank Schmitz ,  Rene Jean Zimmer ,  Bernd Fuchs

发明人： Marc Weydert ,  Frank Schmitz ,  Rene Jean Zimmer ,  Bernd Fuchs

IPC分类号： B29C33/52 ,  B29D30/52 ,  B60C11/12

CPC分类号： B29D30/0662 ,  B29C33/52 ,  B29C37/0003 ,  B29D30/0606 ,  B29D2030/0613 ,  B29L2030/002 ,  B60C11/00 ,  B60C11/12 ,  Y10S152/03 ,  Y10S264/44

摘要： A degradable sipe blade for forming sipes in a tire tread, where the degradable material may be removed by exposure to water. A tire curing apparatus is also provided having a plurality of degradable sipe blades affixed to the mold surface within the tread pattern. In addition, a cured tire is provided having the degradable sipe blades embedded in the tread elements of the tire tread after removal of the cured tire from a curing mold. Further provided is a method for forming sipes in a tire tread using degradable blading.

摘要翻译： 用于在轮胎胎面中形成刀槽花纹的可降解刀槽花纹刀片，其中可通过暴露于水中去除可降解材料。 还提供一种轮胎硫化装置，其具有在胎面花纹内固定到模具表面的多个可降解刀槽花刀片。 此外，提供了一种固化轮胎，其在从固化模具中除去硫化轮胎之后，将可降解的刀槽花纹刀片嵌入轮胎胎面的胎面元件中。 还提供了一种使用可降解叶片在轮胎胎面中形成刀槽花纹的方法。