摘要:
Cross-linked macromolecular products having the structure of perfluoropolyethers in which the cross-linking is due to C--C links between carbon atoms of different perfluoropolyether chains, said cross-linked products being obtained by treatment by means of U.V. radiations of the corresponding perfluoropolyethers containing at least three groups: ##STR1## arranged along the chain and at one or at both ends; the C--C link of cross-linking coming from the removal of two groups: ##STR2## of different perfluoropolyether chains.
摘要:
Vulcanizable compositions of fluoroelastomers based on vinylidene fluoride with one or more monomers containing an ethylene unsaturation and at least one fluorine atom, having improved processability and improved chemical stability, and comprising, as a processing coadjuvant, a mono- or dihydroxypolyfluoroether having a means molecular weight higher than or equal to 400 for the monohydroxypolyfluoroethers and higher than or equal to 2500 for the dihydroxypolyfluoroethers.
摘要:
New products having the structure of arylphosphines or of derivatives of arylphosphines with an oxygen or sulphur atom directly bonded to the phosphorus atom, containing perfluoroalkylether chains, characterized in that such chains are bonded to the benzene ring through a non-perfluorinated bridge, and are obtained by a process substantially decreasing their production costs, and suitable to be used as stabilizers of perfluoropolyether oils and greases to prevent their degradation in the presence of metals, and the corrosion of the same metals, such as, e.g., Al, Ti, V, or their alloys, when operating in oxidizing and high-temperature environments.
摘要:
Fluoropolyethers having functional groups, consisting of randomly distributed sequences of perfluoropolyoxyalkylene units selected from: ##STR1## and included in one of the following formulas: ##STR2## where X is F or CF.sub.3 T, T', T"=a perfluoroalkyl group containing from 1 to 3 carbon atoms and one or two atoms of Cl, Br or I;R, R'=halogen atoms;Y=a functional group;o, q=numbers, zero included, such that o+q=1-20;n=a number ranging from 1 to 15;m/n=a number ranging from 0.01 to 0.5;p=a number ranging from 1 to 20;s/p=a number ranging from 0.5 to 2; andz/o+p=a number ranging from 0.01 to 0.05.
摘要翻译:具有官能团的含氟聚醚,由选自以下的全氟聚氧化烯单元的随机分布序列组成:图像(I)T'O(CF 2 CF 2 O)p(CF 2 O)s CR R'Y(II)(III)其中 X是F或CF 3 T,T',T“=含有1至3个碳原子和1或2个Cl,Br或I原子的全氟烷基; R,R'=卤素原子; Y =官能团; o,q =数字,包括零,使得o + q = 1-20; n = 1到15之间的数字; m / n = 0.01〜0.5的数; p = 1到20之间的数字; s / p =从0.5到2的数字; z + o + p = 0.01〜0.05的数。
摘要:
Polishes for metal surfaces, based on dispersions of waxes, fluorinated polymers and perfluoropolyoxyalkylene oils acquire high gloss characteristics combined with improved water-repellency and resistance to soiling of 0.1-5% by weight of at least a cationic emulsifier comprised in the general formula(I) R-L-Q.sup.+ X.sup.-where:R=a chain of perfluoropolyoxyalkylene units;L=a divalent organic group;Q=a polar group;X=a halogen, or a group of formulaCH.sub.3 -Phenylene-SO.sub.3.sup.-R"SO.sub.3.sup.-R"=F-(CF.sub.2).sub.m -;t=1 or 2;m=1-4.The polished containing the emulsifiers of formula (I) as well as the compounds comprised in said formula are claimed as new products.
摘要翻译:基于蜡,氟化聚合物和全氟聚氧化烯油的分散体,金属表面的抛光剂获得高光泽特性,结合改善的防水性和耐污染性至少为通式(I)所包含的至少一种阳离子乳化剂0.1-5重量% )RL-Q + X-其中:R =全氟聚氧化烯单元链; L =二价有机基团; Q =极性基团; X =卤素或式为CH 3 - 亚苯基-SO 3 -R'SO 3 -R“= F-(CF 2)m - 基团; t = 1或2; m = 1-4。 含有式(I)的乳化剂的抛光剂以及所述式中包含的化合物被称为新产品。
摘要:
Perfluoropolyethers having fluorinated epoxy groups positioned along their perfluoropolyether chain, and free from peroxidic oxygen, are obtained by means of a low-temperature oxidation process, in the liquid phase, with molecular oxygen and in the presence of U.V. light, of a mixture of a perfluorinated monoolefin and a perfluorinated coniugated diene, and of the subsequent photochemical decomposition of the peroxy groups contained in the photoxidation product, carried out by treating the peroxy-groups-containing product with U.V. light at a temperature comprised within the range of from 0.degree. C. to 160.degree. C. Derivatives of said epoxy containing perfluoropolyethers in which the epoxy groups have been turned into functional groups.
摘要:
An antirust additive for lubricants based on perfluoropolyethers, comprising one of the fluoropolyether compounds having functionalized end groups selected from --CN, --CH.sub.2 NR.sub.1 R.sub.2 and ##STR1## and in particular a combination of these with small amounts of a fluoropolyether with acid end groups.
摘要翻译:一种用于基于全氟聚醚的润滑剂的防锈添加剂,其包含具有选自-CN,-CH 2 NR 1 R 2和的官能化端基的氟聚醚化合物之一,特别是这些与少量具有酸端基的含氟聚醚的组合。
摘要:
New lubricating greases, the oily component of which is perfluoropolyether or fluoropolyether derivative of formula R--O--Q--CFX--(Y).sub.n --Z, having a number average molecular weight ranging from 1,500 to 10,000.whereinR is perfluoroalkyl radical R.sub.F or Z(Y).sub.n)--CFX;Q is perfluoroalkylpolyether or fluoroalkylpolyether chain;X is F or CF.sub.3 ;Y is a linking divalent radical;n is zero or 1; andZ is a radical selected from --CH.sub.2 OH, --CH.sub.2 OR.sup.1, --COOR.sup.2, --CONR.sup.3 R.sup.4 etc. . . . or from particular radicals containing heteroatoms or particular aromatic radicals.
摘要:
Fluorinated polymers having improved mechanical properties and an improved surface appearance, characterized in that they comprise a reinforcing material based on glass, asbestos and silicates in general or carbon, in the form of fibres or granules, or polyamidic fibres, such material being superficially treated with fluoropolyethers having an average molecular weight from 1,000 to 10,000 and containing functional end groups capable of forming bonds of various nature with the reinforcing material.
摘要:
Vulcanizable compositions of fluoroelastomers based on vinylidene fluoride with one or more monomers containing an ethylenic unsaturation and at least one fluorine atom, which utilize as a cross-linking agent a dihydroxypolyfluoroether having a molecular weight of from 360 to 2000.