公开(公告)号：US09573123B2

公开(公告)日：2017-02-21

申请号：US14910319

申请日：2014-08-15

Applicant: Haldor Topsøe A/S

Inventor： Martin Spangsberg Holm ,  Irantzu Sadaba Zubiri ,  Søren Tolborg ,  Christian Mårup Osmundsen ,  Esben Taarning

IPC: C07C69/66 ,  B01J29/70 ,  C07C67/00 ,  B01J29/08

CPC classification number: B01J29/7057 ,  B01J29/088 ,  B01J29/7049 ,  B01J37/04 ,  B01J37/08 ,  B01J37/10 ,  B01J2229/16 ,  C07C67/00 ,  Y02P20/582 ,  C07C69/68

Abstract: A process for the preparation of lactic acid and 2-hydroxy-3-butenoic acid or esters thereof from a sugar in the presence of a metallo-silicate material, a metal ion and a solvent, wherein the metal ion is selected from one or more of the group consisting of potassium ions, sodium ions, lithium ions, rubidium ions and caesium ions.

Abstract translation: 一种在金属硅酸盐材料，金属离子和溶剂的存在下从糖制备乳酸和2-羟基-3-丁烯酸或其酯的方法，其中金属离子选自一种或多种 由钾离子，钠离子，锂离子，铷离子和铯离子组成的组。

公开(公告)号：US09328048B2

公开(公告)日：2016-05-03

申请号：US14769488

申请日：2014-02-25

Applicant: Haldor Topsøe A/S

Inventor： Esben Taarning ,  Martin Spangsberg Holm ,  Christian Mårup Osmundsen

IPC: C07C45/89 ,  C07C45/87

CPC classification number: C07C45/87 ,  C07C49/88 ,  C07C49/90

Abstract: A Process for preparing ketene in the presence of a fluidized bed material with a surface area of up to about 600 m2/g. The process is further defined as a process for preparing ketene from a sugar or glycolaldehyde feedstock.

Abstract translation: 在流化床材料存在下制备乙烯酮的方法，流化床材料的表面积高达约600m2 / g。 该方法进一步定义为从糖或乙二醇原料制备乙烯酮的方法。

公开(公告)号：US20160002137A1

公开(公告)日：2016-01-07

申请号：US14769161

申请日：2014-02-25

Applicant: HALDOR TOPSØE A/S

Inventor： Esben Taarning ,  Martin Spangsberg Holm

IPC: C07C45/85 ,  A23L1/272 ,  C07H3/02 ,  C07C29/143 ,  C07C209/24 ,  C07C67/42

CPC classification number: C07C45/85 ,  A23L5/41 ,  A23V2002/00 ,  C07C29/143 ,  C07C67/42 ,  C07C209/24 ,  C07H3/02 ,  Y02P20/127 ,  C07C47/19

Abstract: A process for reducing the percentage by weight of formaldehyde present in a composition comprising glycolaldehyde, wherein formaldehyde is transformed into one or more formaldehyde acetal(s) and removed from the reactive distillation reaction solution by reactive distillation in the presence of at least one alcohol and a catalyst.

Abstract translation: 一种降低存在于包含乙二醇的组合物中的甲醛的重量百分比的方法，其中甲醛被转化成一个或多个甲醛缩醛，并通过反应蒸馏在至少一种醇存在下从反应蒸馏反应溶液中除去， 催化剂

公开(公告)号：US11780798B2

公开(公告)日：2023-10-10

申请号：US16461989

申请日：2017-11-22

Applicant: HALDOR TOPSØE A/S

Inventor： Christian Mårup Osmundsen ,  Esben Taarning

IPC: C07C51/235 ,  B01J23/44 ,  B01J23/52 ,  C07C45/60 ,  C07C51/285 ,  C07C59/06 ,  C07C27/00

CPC classification number: C07C51/235 ,  B01J23/44 ,  B01J23/52 ,  C07C27/00 ,  C07C45/60 ,  C07C51/285 ,  C07C59/06 ,  C07C45/60 ,  C07C47/19 ,  C07C51/235 ,  C07C59/06

Abstract: A method and a system for producing glycolic acid and/or glycolate from sustainable resources. A method for catalytic production of glycolic acid and/or glycolate including the step of: oxidation of a starting material including between 0.1-100 wt/wt % glycolaldehyde at a temperature of between −10° C. and 100° C. with an oxidant in the presence of a metal-based catalyst including a catalytically active metal, which is selected from the group of palladium and platinum; or mixtures thereof.

公开(公告)号：US11603362B2

公开(公告)日：2023-03-14

申请号：US17287138

申请日：2019-11-29

Applicant: HALDOR TOPSØE A/S

Inventor： Amanda Birgitte Sølvhøj ,  Rik De Clercq ,  Esben Taarning

IPC: C07D319/12

Abstract: According to the present invention a process is provided for producing glycolide which comprises contacting glycolaldehyde dimer with an oxidizing agent to produce a glycolide product. Preferably, the process is carried out in an aprotic environment, such as in a reaction mixture comprising the glycolaldehyde dimer, the oxidizing agent, the glycolide product and an aprotic solvent.

公开(公告)号：US11370750B2

公开(公告)日：2022-06-28

申请号：US16965421

申请日：2019-05-13

Applicant: Haldor Topsøe A/S

Inventor： Amanda Birgitte Sølvhøj ,  Esben Taarning

IPC: C07C319/20 ,  C07C319/18

Abstract: The following invention regards a process of demethylating a methyl ester of methionine or its hydroxy analog and producing methane thiol as a side-product. The methionine and its hydroxy analog are suitable as an animal feed additive and as a food additive. The methane thiol may be consumed in a hydrothiolation step such as in a step of preparing the methyl ester of methionine or its hydroxy analog from methyl vinyl glycolate.

公开(公告)号：US20190119187A1

公开(公告)日：2019-04-25

申请号：US16094684

申请日：2017-06-15

Applicant: HALDOR TOPSØE A/S

Inventor： Morten Boberg Larsen ,  Christian Mårup Osmundsen ,  Esben Taarning

IPC: C07C45/60 ,  C07C27/04 ,  B01J6/00 ,  B01J8/00 ,  B01J8/18

CPC classification number: C07C45/60 ,  B01J6/008 ,  B01J8/003 ,  B01J8/0055 ,  B01J8/0065 ,  B01J8/08 ,  B01J8/1818 ,  B01J8/1836 ,  B01J8/1863 ,  B01J8/26 ,  B01J8/388 ,  B01J2208/00362 ,  B01J2208/0038 ,  B01J2208/00504 ,  B01J2208/00513 ,  B01J2208/00902 ,  B01J2208/00911 ,  C07C27/00 ,  C07C27/04 ,  C07C31/04 ,  C07C31/08 ,  C07C31/10 ,  C07C47/19

Abstract: A process for large scale and energy efficient product on of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor comprising a fluidized stream of heat carrying particles. The heat carrying particles may be separated from the fluidized stream prior to cooling the fragmentation product and may be directed to a reheater to reheat the particles and recirculate the heated particles to the fragmentation reactor.

公开(公告)号：US10100007B2

公开(公告)日：2018-10-16

申请号：US15525450

申请日：2015-11-12

Applicant: Haldor Topsøe A/S

Inventor： Irantzu Sadaba Zubiri ,  Esben Taarning

IPC: C07C319/18 ,  C07C69/732 ,  C07C69/68 ,  C07C67/47 ,  C07C67/44 ,  C07C67/475

Abstract: A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or α-hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.

公开(公告)号：US20170197893A1

公开(公告)日：2017-07-13

申请号：US15321301

申请日：2015-06-29

Applicant: HALDOR TOPSØE A/S

Inventor： Christian Mårup Osmundsen ,  Esben Taarning ,  Martin Spangsberg Holm

IPC: C07C29/141

CPC classification number: C07C29/141 ,  C07C27/00 ,  C07C29/145 ,  C07C45/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C47/19 ,  C07C47/127 ,  C07C49/185

Abstract: A process for the preparation of ethylene glycol comprising the steps of hydrogenating a composition comprising C2-oxygenate compounds in the gas phase in the presence of a catalyst.

公开(公告)号：US20170137354A1

公开(公告)日：2017-05-18

申请号：US15322680

申请日：2015-06-29

Applicant: HALDOR TOPSØE A/S

Inventor： Martin Spangsberg Holm ,  Esben Taarning

IPC: C07C29/145 ,  C07C29/76 ,  B01J6/00 ,  C07C45/52

CPC classification number: C07C29/145 ,  B01J6/008 ,  C07C27/00 ,  C07C27/04 ,  C07C29/00 ,  C07C29/141 ,  C07C29/76 ,  C07C31/20 ,  C07C45/52 ,  C07C45/60 ,  C07C47/19 ,  C07C31/202 ,  C07C31/205 ,  C07C47/127 ,  C07C49/185

Abstract: A process for the preparation of ethylene glycol comprising the steps of pyrolysing a monosaccharide and hydrogenating the product composition in the presence of a catalyst and a solvent, wherein the pressure of the hydrogenation reaction is 40 bar or greater.