摘要:
Thermoplastic molding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which comprises functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other added materials, where the total of the percentages by weight of components A) to F) is 100%.
摘要:
An elastomeric acrylate copolymer which contains, as polymerized units, comonomers having chemically reactive groups is prepared for the preparation of molding materials having good weathering resistance, improved impact strength and good flow properties. This copolymer is dissolved or swollen in monomers such as styrene and acrylonitrile, forming hard graft shells. After the addition of monomers and/or polymers having chemically reactive groups and, if required, after the addition of a chemically reactive crosslinking agent, the resulting monomer/copolymer mixture is subjected to graft polymerization, which is carried out up to a conversion of more than 15% by weight of the monomers, by thermal or free radical mass or solution polymerization. The molding materials can be used as dulling agents for polymer blends.
摘要:
In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, a compound (b) of the formula (II) ##STR2## where R.sup.3 is hydrogen or methyl, R.sup.4 is hydrogen or alkyl of 1 to 8 carbon atoms, R.sup.5 is hydrogen or methyl and R.sup.6 is hydrogen or alkyl of 1 to 10 carbon atoms, preferably hydrogen, and, if required, a first monomer (c) or a plurality thereof is polymerized with free radicals to give a rubber (B),in a second stage, the resulting rubber (B) is mixed with a second monomer (d) or with a plurality thereof, preferably dissolved or swollen therein, to form a second mixture (C), andin a third stage, the second mixture (C) formed by mixing is polymerized with free radicals to give the rubber-modified molding material (D).
摘要:
The invention relates to expandable styrene polymers for elastic polystyrene foams, comprisinga) from 75 to 98% by weight of polystyrene and/or a styrene copolymer containing at least 50% by weight of copolymerized styrene,b) from 2 to 25% by weight of at least one styrene-soluble elastomer,c) from 1 to 15% by weight, based on the sum of a) and b), of a low-boiling blowing agent, and, if desired,d) conventional additives in effective amounts,where the unfoamed beads have a structure in which the elastomer phase is dispersed in the polystyrene phase in the form of cell particles, and to foams and foam moldings produced therefrom.
摘要:
The present invention deals with low temperature impact resistant, easily flowing, thermoplastic polyurethane elastomer compositions, comprising:A) 5-95 parts by weight of at least one thermoplastic polyurethane elastomer (A) having a Shore A hardness less hah 95; andB) 95-5 parts by weight of at least one thermoplastic polyurethane elastomer (B) having a Shore A hardness greater than 98, whereby the parts by weight of (A) and (B) total 100 parts by weight; andC) 0-60 weight percent based on the weight of (A) and (B) of a reinforcing filler.The products are prepared by melting together polyurethane elastomers (A) and (B) at temperatures of from 140.degree.-250.degree. C., preferably in an extruder, and are most preferred for the preparation of ski boots and injection molded articles for motor vehicles.
摘要:
The present invention relates to transparent essentially non-cellular polyurethane casting compositions that are sterilizable with superheated steam which are prepared by reacting:(A) modified diphenylmethane diisocyanates (A) liquid at 23.degree. C. obtained by reacting(A1) 4,4'-diphenylmethane diisocyanate or(A2) 2,4'-diphenylmethane diisocyanate or(A3) a diphenylmethane diisocyanate mixture with(A4) at least one polyoxypropylene polyol and/or(A5) at least one polyoxypropylene polyoxyethylene polyol containing 1 to 80 weight percent of ethylene oxide units whereby (A4) and (A5) have a functionality of 4 to 8 and a hydroxyl number of 150 to 500 and are obtained while using sucrose and/or preferably sorbitol as initiator molecules(A6) a mixture of (A4) and/or (A5) and at least one polyoxypropylene polyol and/or polyoxyethylene polyol initiated with glycerine and/or trimethylolpropane in a NCO:OH group ratio of 2.5:1 to 15:1 with(B) at least one compound having at least reactive hydrogen atoms which preferably contains no primary, secondary or tertiary amino groups in bonded form in the presence of or absence of(C) catalysts.The present invention also relates to a process for the preparation of polyurethane casting compositions and their use for medical-technical articles.
摘要:
Low-shrinkage nylon moldings are produced by activated alkaline lactam polymerization, preferably using the reactive injection molding technique, by a process wherein the polymerization is carried out in the presence of from 5 to 80% by weight of a polymer P which1. is completely soluble in the lactam,2. separates out in the course of polymerization at a conversion of from 1 to 50%,3. is composed of one or more blocks which are compatible with polylactam and one or more blocks which are incompatible therewith, and preferably4. possesses functional groups which are incorporated into the growing polylactam chain.
摘要:
Crystallite suspensions containing from 3 to 70 weight percent of a crystalline, ethylenically unsaturated polyester prepared through condensation polymerization, and having a molecular weight factor per double bond of 154.4 to 408, as the dispersed phase, and from 30 to 97 weight percent of a polyhydroxyl compound having a functionality of from 2 to about 8, a hydroxyl number of from 20 to 800, and a melting point of less than 30.degree. C. as the coherent phase are suitable for preparing non-cellular and cellular polyurethane- or polyurethane group-containing polyisocyanurate foams.
摘要:
Use of thermoplastic molding compositions comprising, as essential components, A) a polyester, B) from 20 to 200 mmol/kg of polyester A) of at least one compound of the general formula (I) where respectively independently at any position -A1- is —NR—, —O—, —S—, —CH=A4- where R is H or C1-6-alkyl, A4 is N or CH A2 is COOX or OX, where X is Li, Na, K, Rb, Cs, Mg/2, Ca/2, Sr/2, Ba/2, Al/3 A3 is C1-6-alkyl, C6-12-aryl, O7-13-alkaryl, C7-13-aralkyl, O—C1-6-alkyl, O—C6-12-aryl, O—C7-13-alkaryl, O—C7-13-aralkyl, COOX′, OX′, SX′, SO3X′, where X′ is H or X, S—C1-6-alkyl, S—C6-12-aryl, NR2, halogen, NO2, n is an integer from 1 to 4, and m is an integer from 0 to 4−n, where m=1, if A3=NO2, with the proviso that the number of mmol is based on the group(s) COOX and OX and SX′ where X′═X, to the extent that these are present in the compound of the general formula (I), and also moreover C) from 0 to 230% by weight of further added substances, based on the weight of component A), for producing laser-transparent moldings of any type.
摘要:
Thermoplastic molding compositions comprising A) from 40 to 96% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of a copolymer composed of B1) from 35 to 89.9% by weight of ethylene, B2) from 10 to 60% by weight of 1-octene or 1-butene or propylene or a mixture of these, and B3) from 0.05 to 5% by weight of functional monomers, where the functional monomers have been selected from the group of the carboxylic acid groups, carboxylic anhydride groups, carboxylic ester groups, carboxamide groups, carboximide groups, amino groups, hydroxy groups, epoxy groups, urethane groups, or oxazoline groups, or a mixture of these, C) from 1 to 50% by weight of fibrous or particulate fillers, or a mixture of these, D) from 0.1 to 10% by weight of D1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, part 2), or D2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, E) from 0 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of further additives, where the total of the percentages by weight of components A) to F) is 100%.