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11.发明授权Solid golf balls reinforced with anhydrous metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids 失效（ALPHA），（BETA） - 乙烯基不饱和羧酸的非金属金属盐固体高岭石
公开(公告)号：US5143957A
公开(公告)日：1992-09-01
申请号：US647080
申请日：1991-01-29
CPC分类号： C08K5/098 , A63B37/0051 , A63B37/0062 , A63B37/0073 , A63B37/0084 , A63B37/0003 , Y10S524/908
摘要： Solid golf balls comprise a vulcanizable rubber and a reinforcing filler comprising an essentially anhydrous metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid. Golf balls containing such reinforcing fillers have improved physical properties over rubber compounds containing conventional metal carboxylic acid salts. Additionally, the rubber compounds have improved processability and shorter curing time.
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公开(公告)号：US4814214A
公开(公告)日：1989-03-21
申请号：US30078
申请日：1987-03-26
CPC分类号： B29D30/0654 , B29C43/3642 , C08L21/00 , C08L23/02 , C08L83/04 , B29D2030/0655 , B29K2883/00 , B29L2030/00 , C08G77/20 , C08G77/22 , C08G77/24 , C08G77/28 , C08G77/70 , C08L11/00 , Y10T428/1386 , Y10T428/31663 , Y10T428/31667
摘要： A curing bladder containing (A) organic rubber which is surface treated with a curable silicon composition containing (B) polyorganosiloxane, which comprises at least two monovalent substituted or unsubstituted hydrocarbon groups having five or more carbon atoms and a C.dbd.C double bond connected to the silicon atom through at least one carbon atom, and having a degree of polymerization greater than 20.
摘要翻译： 一种含有（A）有机橡胶的固化底漆，其用含有（B）聚有机硅氧烷的可固化硅组合物进行表面处理，该组合物包含至少两个具有五个或更多个碳原子的一价取代或未取代的烃基和C = C双键连接到 硅原子通过至少一个碳原子，并具有大于20的聚合度。
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公开(公告)号：US4546127A
公开(公告)日：1985-10-08
申请号：US640365
申请日：1984-08-13
CPC分类号： A43B13/187 , A43B13/04 , A43B13/12 , C08L25/10
摘要： A soft, low-resilience, cured rubber composition is prepared by mixing(a) 100 parts by weight of a polymeric material comprising a styrene-butadiene copolymer or styrene-butadiene copolymer mixture having a styrene content of 53 to 75% by weight, and 0 to 40% by weight of the polymeric material of another rubber ingredient,(b) 30 to 300 parts by weight of a filler, and(c) 5 to 100 parts by weight of a plasticizer, adding effective amounts of a vulcanizing agent and a vulcanizing accelerator to the mixture, and then heat curing the mixture. A similar composition further containing a foaming agent may be heat cured into a low-resilience rubber foam. Rubber and foamed rubber compositions have improved vibration-attenuating and shock-absorbing properties.
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公开(公告)号：US5272203A
公开(公告)日：1993-12-21
申请号：US586065
申请日：1990-09-21
CPC分类号： C08F236/10 , B60C1/0016 , C08K3/04 , C08K5/01 , C08L9/06
摘要： High-performance tires comprising treads made of elastomer compositions comprising (A) ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000; (B) extender oil; and (C) carbon black are described. The ultra high molecular weight copolymer compositions which are also characterized as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R.sup.o M and a 1,3-conjugated diene wherein R.sup.o is a hydrocarbyl group, M is an alkali metal, the mole ratio of R.sup.o M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1.
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公开(公告)号：US5260370A
公开(公告)日：1993-11-09
申请号：US586064
申请日：1990-09-21
CPC分类号： C08F236/10 , C08K5/01 , C08L9/06
摘要： Elastomer compositions comprising (A) ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000 and (B) oil are described. The ultra high molecular weight copolymer compositions which are also characterized as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R.sup.o M and a 1,3-conjugated diene wherein R.sup.o is a hydrocarby group, M is an alkali metal, the mole ratio of R.sup.o M to 1-alkyne is about 3:1 and th mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1. The oil extended elastomer compositions of the present invention preferably contain large amounts of oil such as 80 parts or higher per 100 parts of copolymer.
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16.发明授权Method for preparing ultra high molecular weight copolymers of conjugated dienes and aromatic vinyl compounds 失效制备超高分子量共轭二烯和芳香族乙烯基化合物的方法
公开(公告)号：US5147951A
公开(公告)日：1992-09-15
申请号：US586058
申请日：1990-09-21
CPC分类号： C08F236/10 , C08L9/06
摘要： An ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000 are described. The ultra high molecular weight copolymer compositions which are also characterized as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R.degree.M and 1,3-conjugated diene wherein R.degree. is a hydrocarbyl group, M is an alkali metal, the mole ratio of R.degree.M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1.
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17.发明授权Solid golf balls reinforced with metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids via solution masterbatch 失效用α，β-烯属不饱和羧酸的金属盐通过溶液母料增强的固体高尔夫球
公开(公告)号：US5093402A
公开(公告)日：1992-03-03
申请号：US647079
申请日：1991-01-29
CPC分类号： C08K5/098 , A63B37/0003 , A63B37/0084 , A63B45/00 , Y10S524/908
摘要： Solid golf balls are produced by the method comprising the steps of preparing a polymer cement in a suitable organic solvent, forming a suspension of the metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in a suitable aliphatic hydrocarbon solvent miscible with the organic solvent, mixing the polymer cement and the suspension together, removing the solvents to provide the metal salt uniformly dispersed within the polymer, and thereafter manufacturing a solid golf ball therefrom. Solid golf balls comprise a vulcanizable rubber and from about 5 to 100 parts by weight of a reinforcing filler comprising a metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, per 100 parts of the vulcanizable rubber. When the metal salts are incorporated via solution masterbatching, the resulting golf balls have improved physical properties.
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公开(公告)号：US4714734A
公开(公告)日：1987-12-22
申请号：US832776
申请日：1986-02-25
申请人： Takatsugu Hashimoto , Akihiro Maehara , Seisuke Tomita , Yuichi Funahashi , Junichiro Watanabe , Kazuo Sugiura , Hironori Matsumoto
发明人： Takatsugu Hashimoto , Akihiro Maehara , Seisuke Tomita , Yuichi Funahashi , Junichiro Watanabe , Kazuo Sugiura , Hironori Matsumoto
IPC分类号： C08K3/04
CPC分类号： C08K3/04
摘要： Rubber compounds comprising a specific type of polyorganosiloxane of the following formula ##STR1## in which R and R' independently represent a hydrocarbon substituent and n is an integer of not smaller than 3 provided that at least 6 mole % of the substituents R and R' consists of a hydrocarbon group having Small's molecular attraction constant not smaller than 350. Carbon black is added to the polyorganosiloxane whereby various physical properties are improved including breaking strength, water and hot water resistances. The rubber compound may further comprise at least one organic rubber other than the above polyorganosiloxane.
摘要翻译： 包含特定类型的下式“IMAGE”的聚有机硅氧烷的橡胶化合物，其中R和R'独立地表示烃取代基，n是不小于3的整数，条件是至少6摩尔％的取代基R和R' 由具有小于350的小分子吸引常数的烃基组成。将炭黑加入到聚有机硅氧烷中，由此改善了各种物理性能，包括断裂强度，水和耐热水性。 橡胶化合物可以进一步包含除上述聚有机硅氧烷之外的至少一种有机橡胶。
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公开(公告)号：US4710541A
公开(公告)日：1987-12-01
申请号：US790228
申请日：1985-10-22
CPC分类号： B29D30/0654 , B29C43/3642 , C08L21/00 , C08L23/02 , C08L83/04 , B29D2030/0655 , B29K2883/00 , B29L2030/00 , C08G77/20 , C08G77/22 , C08G77/24 , C08G77/28 , C08G77/70 , C08L11/00 , Y10T428/1386 , Y10T428/31663 , Y10T428/31667
摘要： An improved process for molding and vulcanizing rubber products using a curing bladder, characterized in that the bladder is one which is made of a rubber compound containing (A) organic rubber and (B) polyorganosiloxane, the ratio of (A)/(B) being 95/5 to 5/95, or the bladder is one which is produced by surface treating (A) organic rubber with a silicone composition containing (A) organic rubber and (B) polyorganosiloxane, said polyorganosiloxane comprising at least two monovalent substituted or unsubstituted hydrocarbon groups having five or more carbon atoms and a C.dbd.C double bond connected to the silicon atom through at least one carbon atom, and having a degree of polymerization greater than 20.
摘要翻译： 一种改进的使用固化囊成型和硫化橡胶制品的方法，其特征在于，囊是由含有（A）有机橡胶和（B）聚有机硅氧烷的橡胶化合物制成的，其中（A）/（B） 为95/5至5/95，或者膀胱是通过用含有（A）有机橡胶和（B）聚有机硅氧烷的硅氧烷组合物表面处理（A）有机橡胶而制备的，所述聚有机硅氧烷包含至少两个一价取代或 具有5个或更多个碳原子的未取代烃基和通过至少一个碳原子与硅原子连接并且聚合度大于20的C = C双键。
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公开(公告)号：US5998513A
公开(公告)日：1999-12-07
申请号：US252213
申请日：1999-02-18
申请人： Takatsugu Hashimoto
发明人： Takatsugu Hashimoto
摘要： A rubber composition is a mixture of 100 parts by weight of at least one rubber component selected from the group consisting of a natural rubber and a synthetic rubber and 1 to 120 parts by weight of a softening agent containing 0.1 to 4% by weight of asphaltene. The rubber composition simultaneously has a high high-loss property, a high fracture property and a good workability.
摘要翻译： 橡胶组合物是100重量份的选自天然橡胶和合成橡胶的至少一种橡胶组分和1至120重量份含有0.1至4重量％沥青质的软化剂的混合物 。 橡胶组合物同时具有高的高损耗性，高断裂性和良好的加工性。
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